{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在NaOH溶液中,<span style=\"color:red\">苯</span>唑西林(OXA)能与某些碱性<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料如甲基紫(MV)、乙基紫(EV)和孔雀石绿(MG)结合,使体系的共振瑞利散射(RRS)急剧增强并产生新的RRS光谱,最大共振光散射峰分别位于333nm(MV体系),342nm(EV体系)和343nm(MG体系),<span style=\"color:red\">苯</span>唑西林的质量浓度在0.080～0.60mg/L(MV体系),0.040～0.40mg/L (EV体系和MG体系)时与散射强度呈良好的线性关系,检出限(3σ)分别为0.064mg/L(MV体系)、0.024mg/L(EV体系)和0.013 mg/L(MG体系),其中以孔雀石绿体系最灵敏,以其为例考察了共存物质的影响.结果表明,方法具有较高的选择性,用于人血清、人尿及市售药物中<span style=\"color:red\">苯</span>唑西林的测定,结果满意.","authors":[{"authorName":"江虹","id":"8054ff21-7de8-4b98-868d-9eee715d4cc7","originalAuthorName":"江虹"},{"authorName":"庞向东","id":"5e9a4f06-4acf-4be9-90b2-af9f232382c8","originalAuthorName":"庞向东"},{"authorName":"焦凤","id":"7984c072-fb0c-41e5-92de-bca914ea3af1","originalAuthorName":"焦凤"},{"authorName":"蹇飞","id":"6bfcb251-99ff-4c06-96f4-c6e865ef94fa","originalAuthorName":"蹇飞"}],"doi":"10.3724/SP.J.1095.2011.00328","fpage":"355","id":"06e981e2-1ee2-4626-aa4c-e1fdf1d278be","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"2c381298-0f5d-48f1-ac19-229cfa2ec262","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>","originalKeyword":"三苯甲烷"},{"id":"85762be3-928f-414e-a3b6-da690f494e30","keyword":"<span style=\"color:red\">苯</span>唑西林","originalKeyword":"苯唑西林"},{"id":"642387b5-8765-43b1-afaf-bcba7a6dc869","keyword":"共振散射","originalKeyword":"共振散射"}],"language":"zh","publisherId":"yyhx201103020","title":"某些碱性<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料共振瑞利散射法测<span style=\"color:red\">苯</span>唑西林","volume":"28","year":"2011"},{"abstractinfo":"<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>类染料是目前痕量分析中一类重要的有机试剂.本文评述了20世纪后10多年间,<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>类染料在光度法、催化光度法和电分析法等方面在我国的应用现状及发展趋势,引文125篇.","authors":[{"authorName":"冯尚彩","id":"3e3dd649-7b84-4995-ae4f-fb95448df92d","originalAuthorName":"冯尚彩"},{"authorName":"杨秀英","id":"54a09cb3-2adf-43bf-a8b5-029bb1b265c1","originalAuthorName":"杨秀英"}],"doi":"10.3969/j.issn.1000-7571.2002.01.009","fpage":"24","id":"6be0bad3-37fe-49ae-9027-222eea874366","issue":"1","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"d8b85c0d-28c0-4c06-8751-cbb843c886e5","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>类染料","originalKeyword":"三苯甲烷类染料"},{"id":"0b3d1fd8-e91f-4b4e-9acb-d55c70b47c1d","keyword":"光度法","originalKeyword":"光度法"},{"id":"ab981c39-985f-4b5c-87d1-50fa5ea1f270","keyword":"电分析法","originalKeyword":"电分析法"},{"id":"3666743a-fec7-4a1f-9701-fc57d7cad9b7","keyword":"进展","originalKeyword":"进展"}],"language":"zh","publisherId":"yjfx200201009","title":"<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料在我国光度分析和电化学分析中的应用进展","volume":"22","year":"2002"},{"abstractinfo":"以4-正辛烷氧基二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>(ODBM)为配体,邻菲啰啉为第二配体与铕配位,合成了一种新的铕-长链烷氧基β二酮-邻菲啰啉<span style=\"color:red\">三</span>元配合物.用红外光谱、核磁共振谱和元素分析对配体和配合物的结构进行了表征,并研究了配合物<span style=\"color:red\">三氯甲烷</span>溶液和薄膜的光致发光性能.结果表明,这种配合物的<span style=\"color:red\">三氯甲烷</span>溶液在浓度为10-2～10-4mol/L范围内浓度淬灭现象不显著,溶液和薄膜的荧光都强于铕-二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>-邻菲啰啉配合物.","authors":[{"authorName":"谭松庭","id":"62b0a6b4-c2fa-42a9-86fd-ccec8f53ee2e","originalAuthorName":"谭松庭"},{"authorName":"杨娜","id":"ac430155-e49c-4c86-b5c7-6cb8e2f2eae8","originalAuthorName":"杨娜"},{"authorName":"赵斌","id":"0b8a366f-96b7-4f54-b625-d8749b21db5e","originalAuthorName":"赵斌"},{"authorName":"肖尊宏","id":"0089a8b4-5918-4415-9417-29e95a1418b3","originalAuthorName":"肖尊宏"},{"authorName":"李松青","id":"eb723fd3-74dc-478e-befe-b667312ffe57","originalAuthorName":"李松青"}],"doi":"10.3969/j.issn.1007-2780.2002.05.005","fpage":"341","id":"3ed683a0-44ba-4128-a58b-ac7e58d369d4","issue":"5","journal":{"abbrevTitle":"YJYXS","coverImgSrc":"journal/img/cover/YJYXS.jpg","id":"72","issnPpub":"1007-2780","publisherId":"YJYXS","title":"液晶与显示   "},"keywords":[{"id":"5d2ff865-01a3-4ebf-9afb-b95b4c348566","keyword":"TN104.3","originalKeyword":"TN104.3"},{"id":"75e5f99b-0a28-44ef-bc0b-21cad21f28aa","keyword":"铕","originalKeyword":"铕"},{"id":"297915d2-9cd4-42a1-a442-f0b64f545b29","keyword":"4-正辛烷氧基二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>","originalKeyword":"4-正辛烷氧基二苯甲酰甲烷"},{"id":"83873782-26f2-408e-ab80-41173b6ede5e","keyword":"配合物","originalKeyword":"配合物"},{"id":"8cb5b787-4e64-4613-b83c-87a053a2f516","keyword":"光致发光","originalKeyword":"光致发光"}],"language":"zh","publisherId":"yjyxs200205005","title":"4-正辛烷氧基二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>-邻菲啰啉-铕<span style=\"color:red\">三</span>元配合物的合成与光致发光","volume":"17","year":"2002"},{"abstractinfo":"以盐酸苯胺为催化剂,对羟基<span style=\"color:red\">苯</span>甲醛与苯胺通过缩合反应,合成4,4'-二氨基-4\"-羟基<span style=\"color:red\">三</span>苯基<span style=\"color:red\">甲烷</span>(DAHTM)单体.DAHTM单体与均<span style=\"color:red\">苯</span>四甲酸二酐(PMDA)聚合反应,得到含羟基的聚酰胺酸(DAHTM/PMDA-PAA)溶液,经涂膜,热亚胺化后,制成相应的聚酰亚胺薄膜,并对其表面性能进行了研究.","authors":[{"authorName":"费斐","id":"32b73969-4195-4fd0-9551-d20fc4478297","originalAuthorName":"费斐"},{"authorName":"虞鑫海","id":"06c4005b-8fbf-435e-8120-e3f61d23ef55","originalAuthorName":"虞鑫海"},{"authorName":"徐永芬","id":"04e78641-b7e0-469d-964b-c50ed7719ff9","originalAuthorName":"徐永芬"},{"authorName":"赵炯心","id":"674741e7-627b-4b1b-bb0b-5b1b72aa5fd7","originalAuthorName":"赵炯心"},{"authorName":"傅菊荪","id":"be32828a-8925-4646-b28f-b69041a6dea6","originalAuthorName":"傅菊荪"}],"doi":"10.3969/j.issn.1009-9239.2008.02.007","fpage":"22","id":"8dd9830d-8bc0-46a2-93b2-243571511878","issue":"2","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"07b25a65-2c75-4ed5-87fa-baec1e3ed0de","keyword":"4,4'-二氨基-4\"-羟基<span style=\"color:red\">三</span>苯基<span style=\"color:red\">甲烷</span>","originalKeyword":"4,4'-二氨基-4\"-羟基三苯基甲烷"},{"id":"af5697f3-3fe1-47be-bcf6-b55312d6379f","keyword":"含羟基聚酰亚胺","originalKeyword":"含羟基聚酰亚胺"},{"id":"cee40698-8691-48cd-8971-cdf39c45f35c","keyword":"合成","originalKeyword":"合成"},{"id":"a55209d8-9112-4a09-8b56-ee53a7bb2cbb","keyword":"表面性能","originalKeyword":"表面性能"}],"language":"zh","publisherId":"jycltx200802007","title":"4,4' -二氨基-4\"-羟基<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>型聚酰亚胺薄膜的制备及其表面性能研究","volume":"41","year":"2008"},{"abstractinfo":"在pH为5.0～7.6的Britton-Robinson(BR)缓冲溶液中,呋塞米(FUR)与Pd(Ⅱ)形成摩尔比1∶ 1的配合物,进一步与乙基紫(EV)、结晶紫(CV)、甲基紫(MV)、亮绿(BG)、甲基绿(MeG)等碱性<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料(BTPMD)作用形成1∶ 1的离子缔合物时,染料发生褪色反应,褪色波长分别位于595 nm(EV、CV体系)、580 nm(MV体系)、615 nm(BG体系)和630 nm(MeG体系),FUR浓度在2.0×10-7～4.0×10-6 g/mL(EV体系)、3.0×10-7～8.0×10-6 g/mL(CV体系)、4.0×10-7～4.0×10-6 g/mL(MV体系)、4.0×10-7～7.0×10-6 g/mL(BG体系)、1.2×10-6～8.0×10-6 g/mL(MeG体系)范围内与褪色波长处的吸光度变化值呈良好的线性关系,摩尔吸光系数(ε)根据染料的不同在0.57×104～3.40×104 L/(mol·cm)之间,灵敏度最高的EV体系的检出限(3σ)为6.0×10-8 g/mL,据此建立一种测定呋塞米的新分光光度法. 研究了适宜的反应条件、分析化学性质和共存物质的影响,用于尿样中呋塞米的含量测定,回收率在96.0%～106.8%之间.","authors":[{"authorName":"李翠侠","id":"cbdf4d8a-c3c5-4c81-9f21-c087dd73f95a","originalAuthorName":"李翠侠"},{"authorName":"刘绍璞","id":"14297850-aa92-444e-b15c-509da9eec8e3","originalAuthorName":"刘绍璞"},{"authorName":"刘忠芳","id":"e961c952-be09-4f53-ab47-bb6be43d750b","originalAuthorName":"刘忠芳"},{"authorName":"胡小莉","id":"500efc7d-3925-4f40-923d-e7b5e4469ac3","originalAuthorName":"胡小莉"}],"doi":"10.3724/SP.J.1095.2010.90831","fpage":"1215","id":"a6eb40f1-165b-4f71-9f3f-ae1de9e7186b","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ea37fc37-d714-4757-8c8d-99079c8efce2","keyword":"Pd(Ⅱ)","originalKeyword":"Pd(Ⅱ)"},{"id":"cd6dc6d8-6f92-4b29-8899-29513b6a92a9","keyword":"呋塞米","originalKeyword":"呋塞米"},{"id":"deff41a9-ad29-4820-b7f1-e63ea62b3bff","keyword":"<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料","originalKeyword":"三苯甲烷染料"},{"id":"c4eda97f-1877-4557-8ae5-c41f4972a9cd","keyword":"分光光度法","originalKeyword":"分光光度法"}],"language":"zh","publisherId":"yyhx201010019","title":"呋塞米-Pd(Ⅱ)-碱性<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料反应体系的吸收光谱及分析应用","volume":"27","year":"2010"},{"abstractinfo":"在不同pH值的Britton-Robinson缓冲溶液中,某些酸性<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料与盐酸吡格列酮反应,形成离子缔合物,其最大褪色波长在558～616 nm区间,最大吸收波长位于426～450 nm区间,盐酸吡格列酮的浓度在3.10×10-7～1.55×10-5 mol/L不同范围内遵守比耳定律,表观摩尔吸光系数分别在1.47×104～9.50×104 L/(mol·cm)内,检测限分别在0.033 2～0.257 mg/L内,建立了测定盐酸吡格列酮的光度法. 方法有较高的灵敏度和良好的选择性,用于药品、血样、尿样中盐酸吡格列酮测定,结果满意.","authors":[{"authorName":"秦宗会","id":"d0744291-653f-46f2-bbfa-ab3bb7c4a4a0","originalAuthorName":"秦宗会"},{"authorName":"刘艳","id":"db72fd19-65e5-4722-b256-f64e19aec4ad","originalAuthorName":"刘艳"},{"authorName":"牛卫芬","id":"79f0ae9e-3149-4d2b-b5ef-4c2c75fbc8d0","originalAuthorName":"牛卫芬"},{"authorName":"赵小辉","id":"df402499-6069-493e-a691-9438a5f85624","originalAuthorName":"赵小辉"}],"doi":"10.3969/j.issn.1000-0518.2008.09.004","fpage":"1017","id":"52c0c692-bbb5-4037-a0f5-d35656b84ef9","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"709a4d0f-b5b3-48ca-8f65-27be42929e9b","keyword":"溴甲酚绿","originalKeyword":"溴甲酚绿"},{"id":"3acda56d-c01c-4add-aba4-5e055dad08f5","keyword":"氯酚红","originalKeyword":"氯酚红"},{"id":"15bd33ae-cb01-46e4-a0a6-372843f5c768","keyword":"酚红","originalKeyword":"酚红"},{"id":"799bbf8c-2d65-4ef5-b3b5-5874aeae8610","keyword":"溴甲酚紫","originalKeyword":"溴甲酚紫"},{"id":"131e2830-2884-41d6-b1aa-030283f9197c","keyword":"盐酸吡格列酮","originalKeyword":"盐酸吡格列酮"},{"id":"30a5b6e8-1e84-4b56-9273-f8b238f8c1a4","keyword":"分光光度法","originalKeyword":"分光光度法"}],"language":"zh","publisherId":"yyhx200809004","title":"某些酸性<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>染料与盐酸吡格列酮相互作用的分子光谱特点及其分析应用","volume":"25","year":"2008"},{"abstractinfo":"在硅橡胶(MVQ)和<span style=\"color:red\">三</span>元乙丙橡胶(EPDM)及其共混物中加入交联剂二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>双马来酰亚胺(BMI),研究了BMI对MVQ、EPDM及其共混物的硫化特性和力学性能的影响.EPDM的硫化活性低,正硫化时间是MVQ的3倍,共混物的共硫化性和相容性不佳.BMI能降低EPDM的活化温度,提高EPDM的硫化速度,同时减慢MVQ的硫化速度,从而使二者的硫化速度趋于接近.在MVQ/EPDM共混物中,BMI能使MVQ和EPDM在较低温度下同步反应,实现两组分的共硫化,改善MVQ与EPDM的相容性,提高了MVQ/EPDM共混物的力学性能.","authors":[{"authorName":"李远","id":"fda4425a-7c8c-4b4d-bef9-d882d29d6491","originalAuthorName":"李远"},{"authorName":"李建雄","id":"cffdeb3f-f7ea-4950-893e-74b2c0c83bc6","originalAuthorName":"李建雄"},{"authorName":"游长江","id":"3eed9682-96d9-44e9-99e5-c2cdf149a3d1","originalAuthorName":"游长江"},{"authorName":"刘安华","id":"9007fb3e-0724-49f2-972c-3fb3ea9e3c93","originalAuthorName":"刘安华"}],"doi":"","fpage":"98","id":"a4f4f058-0f89-4f4e-9257-dc44491e5ff3","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"3de049c0-f07f-4ab0-9007-68bd7f837fcf","keyword":"硅橡胶","originalKeyword":"硅橡胶"},{"id":"7c680373-3377-4b34-b5fd-03e2853e9247","keyword":"<span style=\"color:red\">三</span>元乙丙橡胶","originalKeyword":"三元乙丙橡胶"},{"id":"bb26c51b-8366-4da8-ba4f-4abf47c08c74","keyword":"共混物","originalKeyword":"共混物"},{"id":"f02c40fc-8a76-440f-90ab-06f7919a0853","keyword":"共硫化","originalKeyword":"共硫化"},{"id":"969d9fa4-3c6c-495e-926c-7843a577703f","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"gfzclkxygc201303024","title":"二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>双马来酰亚胺对硅橡胶/<span style=\"color:red\">三</span>元乙丙橡胶共混物硫化特性和力学性能的影响","volume":"29","year":"2013"},{"abstractinfo":"在pH值为5.37～5.58的HAc-NaAc缓冲溶液中,6-苄氨基嘌呤(6-BA)能与Cu(Ⅱ)反应生成螯合物[6-BA·Cu]2+,可再与<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>类染料形成<span style=\"color:red\">三</span>元离子缔合物,其摩尔比分别为2∶1(里斯沙明绿)、3∶1(固绿)和2.5∶1(水溶性苯胺蓝).反应体系的吸收光谱发生变化,其共振瑞利散射光谱(RRS)和倍频散射(FDS)显著增强,3个体系的最大RRS峰均位于372 nm附近,6-BA浓度在一定范围内的增加与相应的RRS强度( △IRRs)、FDS( △IFDS)强度和吸光度(△A)均呈线性关系.其RRS检出限分别为5.48 μg/L(里斯沙明绿)、18.43 μg/L(固绿)和9.34 μg/L(水溶性苯胺蓝).据此建立6-BA-Cu(Ⅱ)-里斯沙明绿染料体系测定痕量6-BA的RRS法,并用于豆芽中6-BA的快速测定,结果令人满意.此外,还应用计算化学软件Gaussview3.07和Gaussian03W,采用密度泛函法,在B3 LYP/6 -31G基组水平上计算6-BA的电荷分布,并对里斯沙明绿体系的反应机理及RRS增强的主要原因进行了初步探讨.","authors":[{"authorName":"黎小艳","id":"e3650c9c-95cd-46e3-ac3e-5c4fef8e7b40","originalAuthorName":"黎小艳"},{"authorName":"杨季冬","id":"171f3e14-61ae-469a-9428-abcecb25c217","originalAuthorName":"杨季冬"}],"doi":"10.3724/SP.J.1095.2012.00305","fpage":"446","id":"fce96b27-139d-40b5-b4ce-409ca09998a8","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5926881e-19bd-4239-934e-e516eba17a81","keyword":"苄氨基嘌呤","originalKeyword":"苄氨基嘌呤"},{"id":"2e21fc44-c318-45c1-b664-1d1ca6a2b5f7","keyword":"共振瑞利散射","originalKeyword":"共振瑞利散射"},{"id":"741bb5d3-3f0d-4f6d-845e-5e4c4f16eb1d","keyword":"倍频散射","originalKeyword":"倍频散射"}],"language":"zh","publisherId":"yyhx201204014","title":"6-苄氨基腺嘌呤-Cu(Ⅱ)-<span style=\"color:red\">三</span><span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>类染料体系的吸收和共振瑞利散射光谱及其分析应用","volume":"29","year":"2012"},{"abstractinfo":"以苯甲酸甲酯和苯乙酮为原料,甲醇钠作碱,活性炭为脱色剂,二甲苯为溶剂,合成得到高纯度(99.5％)的二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>.产品结构经IR、1H NMR和13C NMR表征.和传统文献中报道的后处理脱色方法不同,本研究在反应液中直接加入活性炭,实现反应和脱色同步,提高了产品纯度,简化了产品后处理程序.","authors":[{"authorName":"周勇","id":"1197380c-5ebb-43d8-9ea9-7fae826c10dd","originalAuthorName":"周勇"},{"authorName":"刘冰","id":"03d1b2c9-4c9d-41a0-b80f-82ad2169e595","originalAuthorName":"刘冰"},{"authorName":"李伟","id":"4646e1e0-9d64-4ac8-a6b0-cb2d9635b53b","originalAuthorName":"李伟"},{"authorName":"范钊","id":"f2538e96-c331-4c74-9e1d-591a3ae43c64","originalAuthorName":"范钊"},{"authorName":"步向义","id":"e93a3763-93cb-4884-a975-26f28a0a43ff","originalAuthorName":"步向义"}],"doi":"","fpage":"86","id":"23d0e800-5a90-4e40-810c-8aaed215ba68","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"ecb9470b-ca2e-40c4-87fe-211d65d838ad","keyword":"二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>","originalKeyword":"二苯甲酰甲烷"},{"id":"435a8be8-8183-4133-a581-be269878dd3c","keyword":"合成","originalKeyword":"合成"},{"id":"47ac00c7-54c6-46af-8658-505c96809f47","keyword":"工艺改进","originalKeyword":"工艺改进"}],"language":"zh","publisherId":"hccllhyyy201502021","title":"二<span style=\"color:red\">苯</span>甲酰<span style=\"color:red\">甲烷</span>合成工艺改进研究","volume":"44","year":"2015"},{"abstractinfo":"系统地研究了Co掺杂MCM-41用于液相催化氧化二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>的反应,并探讨了不同溶剂及溶剂用量、反应时间、反应温度、催化剂用量等对二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>氧化反应的影响;并得出较优的反应条件:m(二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>):m(催化剂)=10:1;V(二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>):V(冰醋酸)=1:10;温度为100℃,时间为10 h,二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>的转化率21%,二<span style=\"color:red\">苯</span>甲酮的选择性95.8%.","authors":[{"authorName":"常芳","id":"fa401044-1b01-482d-9715-13dfc7bb345d","originalAuthorName":"常芳"},{"authorName":"李晚谊","id":"29bf4c9e-5df2-43c1-a423-04768d4dce01","originalAuthorName":"李晚谊"},{"authorName":"杨盛春","id":"723e3458-8562-4642-a6ee-4bd8354f71c1","originalAuthorName":"杨盛春"},{"authorName":"彭丽","id":"452c2388-832d-4031-b874-1a277b84c637","originalAuthorName":"彭丽"},{"authorName":"王家强","id":"fadc6b0a-5977-45b8-a9a3-305e0c33b283","originalAuthorName":"王家强"}],"doi":"10.3969/j.issn.1000-0518.2007.07.006","fpage":"757","id":"4ba3b275-8216-4bf3-bc6e-acba08d4e129","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"c3cf86a6-991e-41b1-aa6f-4805fb9077a9","keyword":"介孔材料","originalKeyword":"介孔材料"},{"id":"304bfb0c-e898-44f5-b294-5cd583f27dfb","keyword":"催化氧化","originalKeyword":"催化氧化"},{"id":"8d0f6682-f85d-4fe7-abea-92d3b3f447c6","keyword":"二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>","originalKeyword":"二苯甲烷"},{"id":"b178e791-9277-49ca-a397-588fead10c4b","keyword":"二<span style=\"color:red\">苯</span>甲酮","originalKeyword":"二苯甲酮"}],"language":"zh","publisherId":"yyhx200707006","title":"Co-MCM-41催化氧化二<span style=\"color:red\">苯</span><span style=\"color:red\">甲烷</span>制备二<span style=\"color:red\">苯</span>甲酮的反应条件","volume":"24","year":"2007"}],"totalpage":2709,"totalrecord":27087}