WANG Yongzhong ZHU Naiping YAN Xueqin HAO Huiqing QIAO Guiwen Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
110015
,
China.
材料科学技术（英文）
The resistivity and magnetic susceptibility of the quenched samples for the Y-Ba-Cu oxides were measured at room temperature.The measurement for the temperature dependence of the amorphous Bi-Sr-Ca-Cu oxides with different heat treatment temperature was made.The resistivity and the parameters C in the formula x=X_0+C/(T-0)of the quenched samples for Y-Ba-Cu oxides decreased with lowering quench temperature,and their susceptibility did not vary monotonously with quench temperature.The tem- perature dependence of the amorphous Bi-Sr-Ca-Cu oxides gradually deviates from Curie-Weiss law with increasing heat treatment temperature.The local magnetic moments for Y-Ba-Cu and amorphous Bi-Sr-Ca-Cu oxides gradually decrease with decreasing quench tempera- ture or increasing heat treatment temperature.
关键词:
superconductivity
,
null
,
null
QIN Zuoxiang
,
ZHANG Yansheng
,
ZHU Naiping Department of Materials Engineering
,
Dalian Railway Institute
,
Dalian
,
116022
,
China.Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
110015
,
China.
材料科学技术（英文）
The oxygen relief/absorption,superconduc— tivity and structure of(Bi_(1-x)Pb_x)_2Sr_2Ca_2— Cu_3O_y compounds have been studied by TGA, electrical resistance measurement and X-ray diffraction.The amount of oxygen which can be re- leased and superconductivity of the compounds are correlative to Pb content.The release of oxygen in- creases when x less than 0.2 and decreases when x exceeds 0.2 with increasing x.The appropriate con- tent of Pb for superconductivity is in the range of 0.1
关键词:
oxygen relief/absorption
,
null
,
null
,
null
ZHANG Cheng
,
WANG Yongzhong
,
JIANG Ming
,
ZENG Dechang
,
TANG Hong
,
LI Zhongrun
,
QIAO Guiwen
,
CHUANG Yuzhi(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang
,
ChinaManuscript received on 20 April 1995)
金属学报(英文版)
Bi-2212 superconductive oxides with nanometer grains have been prepared by means of crystallization from amorphous materials.The structure and grain-size of samples were examined by.X-ray.diffraction,scanning electron microscopy.and high resolution electron microscopy.The temperature dependence of the resistivity.and a.c.susceptibility was measured by the standard four-probe method and the standard mutual-induction measurement,respectively.With the decrease of temperature,the resistivity of the Bi-2212 phase with grain size in nanometer was found to diminish to zero without sudden drop.No diamagnetic transition was detected from room temperature to 4.2 K.The formation of the nanocrystalline 2212 phase and the effect of grain size on the superconductivity were discussed.
关键词:
:Bi-2212
,
null
,
null
,
null
Zhiyong Liu
材料科学技术（英文）
Here we report the fabrication and superconductivity of the iron-based arsenic oxide SmO1-xFxFeAs compound. X-ray diffraction (XRD) results prove that the lattice parameters a and c decrease systematically with increasing x in between 0<x≤0.35, but when x>0.35 the a and c increase with the decrease of x in
the SmO1-xFxFeAs. The critical temperature (Tc) increases with increasing x in between 0.15≤x≤0.3, while x>0.3 the Tc decreases with the increase of x. It is found that at x=0.3 SmO0.7F0.3FeAs has the highest onset resistivity transition temperature of 55.5 K. The critical current density (Jc) value at 10 K for the obtained SmO0.7F0.3FeAs is 1.3×105 A/cm2 (0 T). Meanwhile one can estimates Hc2(0) from the slope of the Hc2(T) curve at T=Tc (HC2 is the upper critical field), and for the 90% normal-state resistivity (ρn) criterion (Tc=55 K), Hc2(0) is determined to be ~253 T.
关键词:
SmO1-xFxFeAs compound
F.H.Li
金属学报(英文版)
The melting temperature and critical transition temperature T, of YBa2Cu3O7-δ with deferent content additives of PbO and BaPbO3 were studied. When PbO was doped in YBa2Cu3O7-δ the melting temperature of YBa2Cu3O7-δ was reduced, however its superconductivity was weakened. From the XRD pattern of the sintered mixture of YBa2Cu3O7-δ and PbO, it was known that there was a reaction between YBa2Cu3O7-δ and PbO, and the product was BaPbO Hence different contents of BaPbO3 (10mass, 20massand 30mass) were added in YBa2Cu3O7-δ It was proved that there were no reactions between YBa2Cu3O7-δ and BaPbO3.And the superconductivity of the mixtures was much better than that of the samples with PbO additive.
关键词:
YBa2Cu3O7-δ PbO additive
,
null
,
null
闻立时
,
钱声伟
,
胡倾宇
,
关侃
,
庄育智
金属学报
<正> Y-Ba-Cu系氧化物在液氮温区的高温超导电性被发现以来,其潜在应用价值引起了人们的极大兴趣。由于陶瓷材料所特有的高脆性使其加工性能极差,有效的成材途径成为这种氧化物超导陶瓷的实用化进程中主要研究方向之一。我们曾报道了用等离子喷涂工艺制备成YBa_2Cu_3O_(7-x)超导涂层的结果,运用此方法可以方便、灵活、有效地在多种基材上复合超导材料,得到超导电气元件。Neiser等及Cuomo等的结果也证实了
关键词:
超导
,
plasma spraying
,
microstructure
,
coating
张俊良
,
张思佳
,
翁红明
,
于晓辉
,
张巍
,
杨留响
,
刘清青
,
冯少敏
,
望贤成
,
禹日成
,
曹烈兆
,
张首晟
,
戴希
,
方忠
,
靳常青
低温物理学报
通过高压电阻测量，发现了拓扑绝缘体化合物BizTe3压力诱导的超导性，在3-6GPa的压力范围内，超导临界温度L约为3K．高压下原位同步辐射的结果证明这个超导相来源于常压相结构．通过霍尔效应的测量，发现超导的Bi2Te3样品的载流子为P型．对高压同步辐射结果Reitveld精修得到的晶格参数和原子位置，并以此进行第一性原理计算，得到的高压下的电子结构仍然保持其拓扑不平凡性．由于Bi2Te3的体超导态和Dirac型的表面态之间的近邻效应，可以出现拓扑超导性．文章也讨论了其体态为拓扑超导体的可能性．
关键词:
拓扑绝缘体
,
高压
,
超导性
,
Bi2Te3
王庆阳
,
闫果
,
刘国庆
,
焦高峰
,
熊晓梅
,
冯勇
,
张平祥
低温物理学报
采用Nb/Cu复合管作为外包套材料,通过原位法粉末装管工艺(PIT)制备了C掺杂MgB_2 /Nb/Cu线材.在高纯流动氩气保护条件下、650～950℃温度区间内烧结2h微观结构分析显示,通过该工艺制备的MgB_2/NbZr/Cu线材具有良好的晶粒连结性和较高的致密度.X射线衍射(XRD)分析表明在750℃左右可以生成纯度较高的MgB_2相,在低温和高温下烧结后均有杂相峰出现,并且高温烧结后所生成的相结构较为复杂.采用四引线法超导临界电流的测试结果表明,低温烧结后的线材具有超导电流传输性能,而当热处理温度超过750℃时,样品中的电流传输状态表现为正常电阻态.实验结果证实采用Nb作为原位法MgB_2超导线材的包套阻隔层时,成相热处理一般应该在低于750℃的温度下进行.
关键词:
二硼化镁线材
,
热处理温度
,
碳掺杂
,
超导电性
王庆阳
,
张平祥
,
闫果
,
熊晓梅
,
杨芳
,
刘国庆
,
焦高峰
,
李成山
稀有金属材料与工程
采用原位法粉末装管工艺(in-situ PIT),以Nb/Cu复合管作为包套材料制备了MgB2超导线材并且在氩气保护气氛中,不同温度条件下保温2h进行成相热处理.分别采用电阻-温度测试、磁矩转变测试、临界传输电流测试以及Nb-MgB2界面磁光研究等分析手段进行研究.结果表明:当热处理温度高于750℃时,在MgB2超导芯丝和Nb阻隔层之间形成一个扩散层,该扩散层的存在阻碍了电流的传输,从而导致在磁测法测试中可以检测到超导相存在,而在传输法测试中无法看到超导传输现象.说明采用Nb作为MgB2超导线带材的扩散阻隔层时其热处理温度不能高于750℃.
关键词:
MgB2/Nb/Cu超导线材,超导电性
,
无定形碳掺杂
