Z.Y. Wu
金属学报(英文版)
The Si L2,3 X-ray absorption near-edge structure (XANES) can be used to probe thelocal structure around Si and derive electronic information of the unoccupied s- andd-like partial density of states in nano-size SiO2. We present Si L2,3-edge for threedifferent size silicates acquired by total electron yield (TEY) at the photoemission sta-tion of Beijing Synchrotron Radiation Facility (BSRF). The Si L2,3-edge spectra areinterpreted based on ab initio full multiple-scattering (MS) calculation. The Si L2.3-edge of nano-size materials has XANES similar to that of a-quartz. The similaritiesbetween the Si L2.3-edge shapes attest to a common molecular-orbital picture of theirSi-O bonding and the same coordination state. However, a considerable broadeningof Si L2,3-edge XANES spectra as decrease of particle size is also an indicative ofpolyhedral distortions.
关键词:
multiple scattering calculation
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金晶
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刘宇航
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杨洪雨
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张明耀
高分子材料科学与工程
由聚乙二醇(PEG)、对苯二异氰酸酯(PPDI)、2,2-双(羟基甲基)丙酸(DMPA)和藻红B(EB)为主要原料,采用一步合成法合成了一系列带有自由羧基的荧光聚氨酯多嵌段共聚物.通过核磁共振氢谱、傅里叶变换红外光谱、凝胶渗透色谱法等测试方法表征了聚合物的结构.荧光光谱证实EB被成功地接在聚氨酯多嵌段共聚物上;动态激光光散射法测得该嵌段聚合物胶束粒径为208nm左右;透射电子显微镜表明该胶束粒子呈现出球型形态.
关键词:
纳米粒子
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聚氨酯
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荧光
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羧基
唐文勇
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陈清华
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柴伟伟
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陈子云
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张学清
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贺志强
材料热处理学报
通过建立二维数值分析模型,分析了不同进气温度及压力时,带电纳米粒子在激波和电场力耦合作用下的加速特性以及对粒子撞击基板速度的影响。结果表明：弓形激波气体压缩层是造成纳米粒子减速的主要因素,弓形激波气体压缩层越薄粒子撞击基板时速度越大;外加电场时,带电纳米粒子撞击基板的速度得到较大提升。
关键词:
冷喷涂
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电场辅助加速
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激波
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纳米粒子
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数值模拟
