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On the Thermodynamic Aspect of Interaction Between Dislocations and Highly Mobile Interstitial Solute: With Special Focus on Recent Progress in Pd-H System: A Review

Sheng Li , Yu-Zeng Chen , Yu-Ke Cao , Feng Liu

金属学报(英文版) doi:10.1007/s40195-016-0367-4

It is well known that, in kinetics, the interaction between dislocations and interstitial solute normally exerts strong solute drag effect on dislocations, leading to strong solution hardening of the metals. However, due to the low mobility of interstitial solute in many metals, thermodynamic aspect of the interaction between dislocations and interstitial solute is often unobservable and omitted. It will be shown in this article by reviewing the H-induced behaviors in metal-H systems, especially the recent progress in Pd-H system that, when the interstitial solute atoms are highly mobile and able to collect in the vicinity of mobile dislocations easily, the scenario will be remarkably different. The interaction between dislocations and these highly mobile interstitial solute atoms, in thermodynamics, will reduce the line energy of dislocations and will facilitate the generation of dislocations, leading to an increase in dislocation density and an enhanced strain hardening of metals upon plastic deformation.

关键词: Plastic , deformation , Dislocation , Interstitial , solute , Strengthening , mechanism , Thermodynamics

Induced Plasticity of a Brittle (La, Ce)-Based Bulk Metallic Glass by Surface Corrosion

Ji-Juan Liu , Ran Li , Lian-Xiang Fang , Ju Wang , Tao Zhang

金属学报(英文版) doi:10.1007/s40195-016-0368-3

Unexpected facture without any room-temperature plasticity severely limits potential structural applications of bulk metallic glasses (BMGs), especially La-, Mg- and Fe-based ones. In this study, a simple free corrosion method was provided to improve the plasticity of a brittle (La, Ce)-based BMG by the introduction of high-density corrosion defects on the surface. The influences of immersing time in 0.1 mol/L H2SO4 aqueous solution on the surface morphology and mechanical properties of the BMG were evaluated. With increasing immersing time from 5 to 30 min, the degree of surface corrosion increased obviously, and the distribution of corrosion defects became more homogenous. In the samples, the yielding phenomenon and certain plasticity appeared up to 0.3% after the surface treatment. The yielding and plasticity can be attributed to easier nucleation of shear bands on the defect surface rather than on the glabrous surface. The results provided a novel method to improve the plasticity of BMGs.

关键词: Metallic , glasses , Corrosion , plastic , deformation , mechanism , Rapid , solidification , Microstructure

Interfacial Structures Governed Plastic Deformation Behaviors in Metallic Multilayers

Ming-Zhen Wei , Zhen-Hua Cao , Xiang-Kang Meng

金属学报(英文版) doi:10.1007/s40195-016-0377-2

In this work, we have investigated the mechanical properties of Cu/Ta, Ag/Cu and Ag/Nb multilayers with different heterogeneous interfaces. The results suggest that when individual layer thickness (h) is larger than 5-10 nm, the hardness/strength of three different multilayer systems has the similar length scale effect with decreasing layer thickness, while when h ≤ 5 nm, the three multilayer systems show remarkably different plastic deformation behaviors. The strength curves exhibit the variation trends of unchanging, softening and increasing corresponding to Cu/Ta, Ag/Cu and Ag/Nb multilayers, respectively. The microstructure analysis shows that three kinds of multilayers have totally different interfacial structures, which lead to the different strengthening or softening mechanisms.

关键词: Metallic , multilayers , Plastic , deformation , Interfacial , structures , Strengthening , mechanism

AM60镁合金化学抛光的工艺及机理研究

宋晓敏余刚何晓梅胡波年陈云张俊易海波

腐蚀学报(英文)

  用在磷酸、丙二醇和水组成的抛光液中的失重率和磷化膜的盐水腐蚀实验以及电化学方法,研究了抛光工艺对AM60镁合金抛光效果、磷化膜耐蚀性的影响及AM60镁合金在磷酸系抛光液中的抛光机理.结果表明,用磷酸体积分数为60%~70%的抛光液,在温度40~50下抛光3~5 min,得到了较好的抛光效果,同时提高了磷化膜的耐蚀性.

关键词: 镁合金 , chemical polishing , mechanism , phosphating , corrosion resistance

天然气加热炉腐蚀机理及其防护研究

张园李稳宏胡兴民李冬廖昌建李珍

腐蚀学报(英文)

    用水质分析和腐蚀产物的XRDXPSSEM分析等方法及密闭系统静态挂片实验,研究了加热炉腐蚀的主要原因和机理.结果表明,溶解氧是引起腐蚀主要因素.在此基础上,根据缓蚀机理研制了ZY-06缓蚀阻垢剂,具有很好的缓蚀、阻垢性能,能很好的抑制沉积物在金属表面的附着,同时具有很强的分散能力.

关键词: 天然气 , corrosion , mechanism , inhibitor , null

下贝氏体铁素体宽面上的台阶结构

金强 , 方鸿生 , 曹建军 , 郑燕康 , 陈秀云

金属学报

采用透射电镜技术研究高碳钢下贝氏体铁素体与母相奥氏体界面结构,发现铁素体宽面上存在可移动的生长台阶、巨型台阶以及它们的三维形态;在下贝氏体铁素体宽面上还存在结构台阶,生长台阶也可以由结构台阶演变而来,为下贝氏体的台阶生长机制提供了实验证据。

关键词: 贝氏体铁素体 , mechanism , broad face , null

流体机械的空蚀机理及其防护

朱丽娟 , 董秀琦 , 郭勇等

腐蚀学报(英文)

运用数学,从流体力学原理上分析了流体机械发生空 蚀时出现的高温、高压、高浓度化学活性物质与自然界温度、气压及机械结构的关系,并提出预防空蚀的方法.

关键词: 流体机械 , cavitation erosion , liquid , mechanism , prevention

方波脉冲电流阴极保护机理研究Ⅱ 电流参数的影响

邱于兵 , 郭稚弧 , 林汉同

中国腐蚀与防护学报

在3%NaCl、006%NaCl和自来水3种实验介质中,研究了Q 235钢的方波脉冲电流幅值(I\-A)、频率(f)和占空比(P)的变化对于阴极极化 电位(E)和极化幅度(ΔE)的影响规律.结果表明,E和ΔE随方波I\-A 、f和P的增加而变负,但当E接近或负于-100 V(SCE)时,再增加各电流参数的值, E和ΔE的负移程度都大大减小.各电流参数对ΔE的影响程度不同,并与E值 密切 相关.提出调整电流参数总的原则和方法是:在达到所要求的保护效果的前提下,尽可能采 用低P、低IA的电流参数,并优先调整f,再调整I\-A.

关键词: 电流参数 , square wave , pulsed current , cathodic protection , mechanism , null

SiCp/Al复合材料化学镀镍层耐蚀性能及机理研究

李丽波 , 安茂忠 , 武高辉

中国腐蚀与防护学报

在考察镀覆条件对镀层含磷量影响的基础上,用电化学方法评价不同含磷量镀层的耐蚀性,得到基本一致的结果:镀液温度及pH值降低,镀层磷含量升高,而镀层含磷量的提高又使镀层的耐蚀性提高.用SEM、EDAX和XRD研究了镀层的表面和断面形貌、含磷量以及相结构,探讨了碳化硅颗粒增强铝基(SiCp/Al)复合材料表面化学镀镍层耐腐蚀的机理 .结果表明,在腐蚀过程中,镀层中磷元素在表面富集形成具有良好耐蚀性的钝化膜,从而提高镀层的自钝化能力和耐蚀性.

关键词: 镍磷合金镀层 , corrosion resistance , P content , mechanism , SiCp/Al composite

铁素体/奥氏体双相钢在旋转单相流体中腐蚀的数值模拟

刘景军 , 林玉珍 , 雍兴跃

中国腐蚀与防护学报

引入现代流体力学方法,建立流体力学、传质过程、腐蚀电 化学反应的综合数学模型,对双相钢在流动35%NaCl水溶液的腐蚀过程进行了数值模拟.探 讨了近壁处流体力学参数对双相钢腐蚀过程的作用,模拟结果表明:双相钢的腐蚀主要受阳 极过程控制,其中钝化膜中的传质过程是腐蚀的主要控制步骤.计算的腐蚀速度与实测值基 本一致,验证双相钢的流体腐蚀机构.

关键词: 双相钢 , flowing 3.5%NaCl solution , numer ical simulation , mechanism

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