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多元离子淹没轰击处理的奥氏体不锈钢的耐蚀性研究

熊玲胡永俊蒙继龙吴大庆

腐蚀学报(英文)

采用金相、扫描电镜、电化学工作站等分析手段研究了在普通离子氮化炉引入铬、镍离子源,对奥氏体不锈钢进行铬、镍、氮多元离子淹没轰击处理后材料的表面形貌、成分和耐蚀性能等。结果表明:经铬、镍、氮多元离子淹没轰击处理后的奥氏体不锈钢表面形成强化层,表面硬度Hv达到12.7 GPa;该强化层的铬、氮的含量很高,主要由CrN和Fe4N相组成;其耐腐蚀性能与普通离子氮化相比得到明显改善.

关键词: 奥氏体不锈钢 , ion nitriding , ionic bombardment , corrosion resistance

离子渗氮层的氮浓度分布函数及计算机仿真

夏立芳 , 阎牧夫

金属学报

本文研究了在不同离子渗氮条件下,纯Fe,45,40Cr,42C1Mo和38CrMoAl钢等五种材料离子渗氮层长大动力学的数学模式,在此基础上,利用仿型积分法,推导出离子渗氮层的氮浓度分布函数: C_ε=C_(min)~ε+P_4/ξ_(10)(ξ_1-x)+P_5/ξ_(10)~2(ξ_1-x)~2, C_γ′=C_(min)~γ′+P_1/ξ_(21)(ξ_2-x)+P_2/ξ_(21)~2(ξ_2-x)~2, C_α=C_(min)~α+C_(33)/ξ_(33)~3(ξ_3-x)~3利用上面数学模式,进行计算机仿真,与实验结果符合良好.

关键词: 计算机仿真 , ion nitriding , nitrogen concentration profile

MICROSTRUCTURE ANALYSIS OF AN ION-NITRIDING LAER ON A NO.45 STEEL

X.L. Xu , L. Wang , Z. W. Yu and Z.K. Hei(Institute of Metal and Technology , Dalian Maritime University , Dalian 116024 , China)

金属学报(英文版)

The cross-sectional microstructure of an ion-nitrided layer on a No.45 steel was studied by transmission electron microscopy (TEM). The results show that the columnar crystals constitute the compound layer. Most of them have the microstructure of alternating ε-Fe2-3N and γ-Fe4N and others are single ε-Fe2-3N phase. There are abnormal strip ferrites between the columnar crystals. The transition layer mainly consists of spherical γ-Fe4N and cementite (Fe3C) particles in the pearlite are dissolved in this layer. In diffusion layer, besides the equilibrium phase γ-Fe4N, there are α -Fe16N2 and the satellite spots around main spots of α-Fe16N2 demonstrate its modulation structure. A metastable ordered cluster zone of the nitropen atoms was found in the division layer.

关键词: ion nitriding , null , null

钛合金表面氮化技术研究进展

刘鹏 , 刘晓鹤

材料开发与应用

本文概述了近年来为了提高钛及钛合金表面耐磨性在钛合金表面制备氮化钛膜层而采用的表面处理技术.从气体氮化、液体氮化以及离子氮化三方面讨论了每种工艺方法所获表面改性层的结构和性能特征及其适应范围.

关键词: 钛合金 , 氮化钛 , 气体氮化 , 液体氮化 , 离子氮化

离子渗氮温度对W9Mo3Cr4V钢渗层组织及性能的影响

潘明明 , 王守晶 , 刘爽

材料保护

目前,国内外对搅拌头材料W9Mo3Cr4V钢离子渗氮表面改性研究不多.采用金相分析、显微硬度测量、X射线衍射仪(XRD)等研究了离子渗氮温度对W9Mo3Cr4V钢搅拌头显微组织和性能的影响,从而得出制备高硬度耐磨氮化层搅拌头的合适的离子渗氮温度.结果表明:经离子渗氮的W9Mo3Cr4V钢搅拌头表层获得了主要由ε相(Fe3N)和y’相(Fe4N)组成的均匀渗氮层,且随着从表面到基体距离的增加,渗氮层的硬度呈现平缓的硬度梯度分布;480~560℃范围内,随离子渗氮温度升高,渗氮层厚度不断增加,渗氮层硬度也不断提高;ε相(Fe3N)衍射峰随离子渗氮温度升高而逐渐降低,γ’相(Fe4N)衍射峰则呈逐渐升高的趋势.渗氮层厚度ζ与渗氮温度T的关系满足ζ=3.85×108e-9141/T·τ.

关键词: 离子渗氮 , W9Mo3Cr4V钢 , 渗氮温度 , 显微组织 , 性能

0.3C-Cr-W渗氮轴承钢的微动摩擦磨损性能

赖大春 , 杨卯生 , 冷崇燕 , 李林涛

钢铁研究学报 doi:10.13228/j.boyuan.issn1001-0963.20150362

利用SRV-4高温摩擦磨损试验机对0.3C-Cr-W高性能渗氮轴承钢进行了微动磨损试验,分别改变载荷和频率,研究了表面离子渗氮对摩擦磨损性能的影响.结果表明:试验钢表面渗氮后渗层厚度为238.45 μm,其中白亮的化合物层厚度为9μm,主要为γ'-Fe4N和VN两种相;渗氮后试样表面的白亮化合物层具有减小摩擦因数和提高耐磨性的作用;渗氮前后试验钢的磨损机制相同,前期以粘着磨损为主,以磨粒磨损为辅;磨损后期转变为以磨粒磨损为主,以粘着磨损为辅;渗氮前试验钢的磨损体积是渗氮后的3倍以上,表面离子渗氮后试验钢的抗微动磨损性能有明显的提高.

关键词: 微动磨损 , 离子渗氮 , 摩擦因数 , 粘着磨损 , 磨粒磨损

MATHEMATICAL MODELS OF NITROGEN CONCENTRATION PROFILE OF ION NITRIDED LAYERS AND COMPUTER SIMULATION

XIA Lifang YAN Mufu Harbin Institute of Technology , Harbin , China Laboratory of Metal Materials and Heat treatment , Harbin Institute of Technology , Harbin , China

金属学报(英文版)

The mathematical models of the kinetics of the layer growth at different ion nitriding condi- tions of armco iron.steels 45,40Cr,42CrMo and 38CrMoAl have been established.Based on these models the expression of nitrogen concentration profile of ion nitrided layers have been deduced with profile simulating method.They are C_=C_(min)~+(P_4)/(ξ_1-x)+(P_5)/(ξ_(10)~2)(ξ_1-x)~2 C_(γ′)=C_(min)~(γ′)+(P_1)/(ξ_(21))(ξ_2-x)+(P_2)/(ξ_(21)~2)(ξ_2-x)~2 C_α=C_(min)~α+(C_(33))/(C_(33))/(ξ_(32))(ξ_3-x)~3 Using these models,the kinetics of layer growth and the nitrogen concentration profile of ion nitrided layers were sinulated on Apple-Ⅱ computer.Results show that the simulated curves coincide quite well with the experimental data.

关键词: computer simulation , null , null

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