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EFFECT OF HETEROGENEOUS DISTRIBUTION OF C AND ALLOYING ELEMENTS ON γ/α′ TRANSFORMATION IN A Fe-Mn-Cr-C ALLOY

ZHENG Yangzeng ZHANG Fucheng Yanshan University , Qinhuangdao , China

金属学报(英文版)

The heterogeneous distribution of C and metallic alloying elements as well as the phase com- position changes before and after cold deformation of an Fe-Mn-Cr-C alloy have been stu- died by the use of Mssbauer spectroscopy.The austenites without and with C and metallic alloying elements are found in the alloy in as-solid solution state.While the martensites with- out and with C and alloying elements may be induced by cold deformation.The transforma- tion from austenite to martensite in the alloy is confirmed via theoretical computation and ex- periments to be controlled by the number of covalent electron pairs forming covalent bond in austenitic crystal cell of the alloy.The formation of strong covalent bond between C and me- tallic elements can vigorously retard the γ/α' transformation.

关键词: heterogeneity , null , null , null , null

激光合金化过渡区显微结构的观察

程永兴 , 李根富 , 余少罗

金属学报

本文采用EPMA,AES和SEM技术,观察到Fe-Ni-Cr合金涂层和45号钢基体激光合金化后,其熔化区和热影响区之间的过渡区,存在明显的化学不均匀性特征,高温回火时尤为严重,以致形成过渡区一侧脱碳,而熔化区一侧增碳的现象。

关键词: 激光合金化 , heterogeneity , transition zone

合金元素及碳在Fe-Mn-Cr-C合金中的不均匀分布对γ→α′转变的影响

郑炀曾 , 张福成

金属学报

用内转换Mossbauer谱分析了Fe-Mn-Cr-C合金冷变形前后合金元素原子与碳原子的不均匀分布和相组成。发现该合金在固溶处理状态时为两类奥氏体,即无碳奥氏体和含碳奥氏体;经变形诱发出不含碳与合金元素的无碳马氏体(类α-Fe)及含碳与合金元素的合金马氏体。理论计算和试验证实:该合金中奥氏体向马氏体转变是受奥氏体晶胞内共价键中共用电子对的数目(n_A值)大小所控制。合金元素原子与碳原子之间形成结合力较强的C-M_e共价键,这对合金马氏体的形成具有强烈的阻碍作用。

关键词: 固溶体的不均匀性 , solid solution , Mossbauer spectroscopy , strain induced martensite

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