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DEFLECTION METHOD FROM TWO SIDES OXIDATION TO STUDY EFFECT OF Y ON INTERNAL STRESS OF OXIDE SCALES

LI Tiefan , LI Meishuan Corrosion Science Laboratory , Institute of Corrosion and Protection of Metals , Academia Sinica Shenyang.China

金属学报(英文版)

Au investigation was carried ont of the effect of Y addition upon the internal stress of Al_2O_3 scale formed during oxidation of sputtering coating on Co-30Cr-6Al alloy and the growth stress of oxidized film on Fe-23Cr-5Al alloy heating up to 900℃ in air,using a specially designed deflection method from thin strip specimen with coat- ings,ion-implanted Y on one side and oxidized onto both sides.Results indicate that Y may decrease the internal stress of oxide scale on 2×10~(17) Y~+/cm~2 implanted Co- 30Cr-6Al coating,and increase one on 2×10~(16) Y~+/cm~2 implanted Fe-23Cr-5Al alloy. This seems due to whether or not Y promotes the plastic deformation of oxide scale.In addition,at initial oxidation stage,the change of growth stress of oxide scale formed on Y-implanted Co-30Cr-6Al coating may be related to the influence of Y on oxidation process of the coating.

关键词: growth stress , null , null , null

Fe-23Cr-5Al合金1000℃氧化形成的Al2O3膜生长应力研究*

李美栓 , 钱余海 , 辛丽

中国腐蚀与防护学报

采用一种测定氧化膜生长应力的双面氧化弯曲方法,测量了Fe-23Cr-5Al(Fe-22.6Cr-4.42Al-0.21Ti,wt%)合金在1000℃空气中氧化形成的Al2O3膜的平均生长应力,研究了氧化膜应力释放机制。Al2O3膜的平均生长应力随膜厚增大而减小,其大小从-1GPa数量级变化到-100MPa数量级。基体合金和Al2O3膜在1000℃时均发生蠕变。合金氧化一定时间后于真空保温退火,发现0。0.039μm厚的氧化膜应力下降速率比0.30μm厚的氧化膜快6.9-18.4倍.

关键词: 生长应力 , deflection test , greep analysis , oxidation

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