{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"分别采用柠檬酸钠、苹果酸、乳酸和丁二酸作配位剂,在30CrMnSi合金钢上化学镀镍-磷合金.考察了配位剂种类及用量对沉积速率及所得镀层耐蚀性的影响.发现以苹果酸或丁二酸作配位剂时沉积速率较快,使用柠檬酸钠或苹果酸时所得镀层的耐蚀性较好.在此基础上选取苹果酸和柠檬酸钠进行复配,研究了二者含量对沉积速率以及镀层耐蚀性的影响,并确定最佳用量为:苹果酸12g/L,柠檬酸钠16 g/L.此时沉积速率达22.54 μm/h,所得镀层在3.5% NaC1溶液和5%(体积分数)H2SO4溶液中的腐蚀速率分别为0.019 g/(m2·h)和0.014 g/(m2·h).通过扫描电镜、能谱仪和X射线衍射仪表征了镀层形貌和结构.结果表明,镀层均匀致密,磷含量为10.26%(质量分数),属于高磷镀层,呈典型的非晶态结构.","authors":[{"authorName":"汪健健","id":"252e33de-828e-4de4-8a4d-cb52ae0c1362","originalAuthorName":"汪健健"},{"authorName":"李思燃","id":"de8d10a3-b312-4109-806f-0985b7f3e0b1","originalAuthorName":"李思燃"},{"authorName":"苏勋家","id":"a349fe80-5f0a-47e5-b328-a244394db44d","originalAuthorName":"苏勋家"},{"authorName":"毕松","id":"0a26ee90-68fa-4bdc-be89-245ca1210830","originalAuthorName":"毕松"},{"authorName":"侯根良","id":"f9ac1177-4347-479c-91b7-672afe6f6c73","originalAuthorName":"侯根良"},{"authorName":"吕湘毅","id":"19dde5ec-ce20-4aaa-b568-da0bc3075cae","originalAuthorName":"吕湘毅"}],"doi":"","fpage":"834","id":"9e5de075-8f69-49bf-995a-dd6e8971c116","issue":"16","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"bfd89a40-bc42-41da-92bc-929a6aebb447","keyword":"合金钢","originalKeyword":"合金钢"},{"id":"a18004bd-c578-4559-b3b7-8cebc1ed6375","keyword":"镍-磷合金","originalKeyword":"镍-磷合金"},{"id":"19cc9edb-4947-4232-b184-1e0c64554b3e","keyword":"化学镀","originalKeyword":"化学镀"},{"id":"bd86c3be-d652-4b08-ad30-66c83e8bcefe","keyword":"配位剂","originalKeyword":"配位剂"},{"id":"6d4384ff-2a89-4df9-8c99-8fea096cc45a","keyword":"沉积速率","originalKeyword":"沉积速率"},{"id":"1a9d0ebc-cbcc-401f-a9a1-16f0ffa9406f","keyword":"微观结构","originalKeyword":"微观结构"},{"id":"27946597-0a9e-490d-a5d9-8c4eed612580","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"ddyts201616002","title":"配位剂对30CrMnSi合金钢化学镀镍磷合金的影响","volume":"35","year":"2016"},{"abstractinfo":"采用反相高效液相色谱法对克拉霉素合成工艺中关键中间E2',4″-双(三甲基硅)-红霉素A-9-(1-异丙氧环己基)肟、Z-2′,4″-双(三甲基硅)-红霉素A-9-(1-异丙氧环己基)肟和E-2′,4″-双(三甲基硅)-6-甲基红霉素A-9-(1-异丙氧环己基)肟、Z-2′,4″-双(三甲基硅)- 6-甲基红霉素A-9-(1-异丙氧环己基)肟及其相关的6种工艺杂质进行了分离、定性和定量分析。色谱柱为DIKMA公司的Inertsil ODS-3(150 mm×4.6 mm I.d., 5 μm);流动相为乙腈-水(体积比为95∶5),流速1.5 mL/min;检测波长UV 205 nm;柱温40 ℃。在进样量为6~60 μg时具有良好的线性关系并可以基线分离,为研究区域选择性甲基化提供了基础。","authors":[{"authorName":"梁建华","id":"c9f85b95-a11c-4bc8-9553-2e742bf591bc","originalAuthorName":"梁建华"},{"authorName":"姚国伟","id":"1cb47ee2-af72-4959-9864-394e260fbca4","originalAuthorName":"姚国伟"},{"authorName":"郑少军","id":"a3776afc-415e-4887-8bc4-9ec01b4675e8","originalAuthorName":"郑少军"}],"doi":"10.3321/j.issn:1000-8713.2004.03.012","fpage":"237","id":"a44fa278-aaa2-4a80-89ad-27c5f38f6301","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"1ba68bae-9257-4239-9ce3-d2b2c12dd3b9","keyword":"高效液相色谱法","originalKeyword":"高效液相色谱法"},{"id":"56d68e17-06b0-443f-89d7-6d1022eb617d","keyword":"克拉霉素","originalKeyword":"克拉霉素"},{"id":"629f0a90-9adc-40a1-8bd0-8217ee60a126","keyword":"肟","originalKeyword":"肟"},{"id":"a7ac3f24-a14a-45b2-9d0f-671d5f867ff5","keyword":"醚化","originalKeyword":"醚化"},{"id":"03eb4a5d-a714-4fcc-b578-4fae68cedebb","keyword":"硅烷化","originalKeyword":"硅烷化"},{"id":"31c9ed26-1b04-4d0f-b5b5-8f7159bc3fa8","keyword":"甲基化","originalKeyword":"甲基化"},{"id":"ae106e38-f5ad-427f-96f3-cda123746c6c","keyword":"异构体","originalKeyword":"异构体"},{"id":"c47539e5-ea57-426b-ad49-65b871808fb5","keyword":"区域选择性","originalKeyword":"区域选择性"}],"language":"zh","publisherId":"sp200403012","title":"反相高效液相色谱分析克拉霉素合成工艺中区域选择性甲基化的关健中间体","volume":"22","year":"2004"},{"abstractinfo":"","authors":[],"doi":"","fpage":"319","id":"88754d16-be8c-4fd1-9277-a7f03b1cc610","issue":"6","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"a57dd2aa-ab71-45c4-bafa-cba21325a5f2","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"ddyts201506006","title":"《丙烯酸涂料生产实用技术问答》(汪盛藻编著)等","volume":"","year":"2015"},{"abstractinfo":"介绍了耐高温防腐涂料研制的基本原理,选择适当的树脂、颜填料,通过控制配方PVC值、固含量、密度、黏度制得双涂层耐热防腐涂料,解决了耐热后防腐这一关健性能.","authors":[{"authorName":"秦玉猛","id":"b8b5235f-6be9-4715-8900-39ae1a639a70","originalAuthorName":"秦玉猛"}],"doi":"10.3969/j.issn.0253-4312.2007.z1.006","fpage":"37","id":"176d702f-896e-429b-8250-5436681c3d88","issue":"z1","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"24ef0b49-128e-4c23-be56-ef9b57148b8d","keyword":"耐热后防腐","originalKeyword":"耐热后防腐"},{"id":"4e509912-cef8-4222-bc8d-911ab5a2dbf6","keyword":"PVC值","originalKeyword":"PVC值"},{"id":"6897ed5b-d48f-4ed4-abb0-0a6511edebb1","keyword":"硅烷偶联剂","originalKeyword":"硅烷偶联剂"},{"id":"e04fffb7-56c0-426b-aefb-3f9167fe30b3","keyword":"纳米氧化锌","originalKeyword":"纳米氧化锌"}],"language":"zh","publisherId":"tlgy2007z1006","title":"摩托车消声器用耐高温防腐涂料的研制","volume":"37","year":"2007"},{"abstractinfo":"高速电弧喷涂技术是一种优质、高效、低成本的再制造工程关健性技术.为此,综述了高速电弧喷涂层在腐蚀环境中的防护作用及其应用状况,展望了高速电弧喷涂技术在钢结构防腐蚀领域的发展趋势.","authors":[{"authorName":"楼森","id":"35ca7606-5c91-41e2-a3cf-a2b0cf329ea8","originalAuthorName":"楼森"},{"authorName":"胡永乐","id":"b205e6fb-b26a-4de2-91ab-425dac0db525","originalAuthorName":"胡永乐"},{"authorName":"强文江","id":"e5867630-260d-4ac8-a2de-ebb190ac8ba6","originalAuthorName":"强文江"},{"authorName":"芦玉峰","id":"766e37a4-dfad-4d93-8146-2f6d6c6e124f","originalAuthorName":"芦玉峰"},{"authorName":"胡新东","id":"065ab8d2-5fe0-4a1d-b9f0-37f23e9ed22f","originalAuthorName":"胡新东"},{"authorName":"范成洲","id":"77992bef-9b94-4bff-8f84-e78010baa948","originalAuthorName":"范成洲"}],"doi":"","fpage":"54","id":"e87dbf71-e7c8-49e6-b986-3a856f0e9413","issue":"3","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"6dafa875-da84-4d0a-996c-6fd89c8c832a","keyword":"高速电弧喷涂","originalKeyword":"高速电弧喷涂"},{"id":"b2593d23-75da-4588-9b43-a3810bc55a3e","keyword":"涂层","originalKeyword":"涂层"},{"id":"1c4f8d18-c099-4ef2-ada1-24ec2802358f","keyword":"腐蚀防护","originalKeyword":"腐蚀防护"},{"id":"3c866213-f8f7-4f3b-9bbb-60aa18e40270","keyword":"钢结构","originalKeyword":"钢结构"}],"language":"zh","publisherId":"clbh201103017","title":"高速电弧喷涂层在钢结构防腐蚀中的作用及应用现状","volume":"44","year":"2011"},{"abstractinfo":"采用溶胶凝胶法制备BiFeO3和Bi0.95La0.05 Fe1-xCoxO3(x=0,0.05,0.1,0.15,0.2)样品.X衍射图谱表明所有样品的主衍射峰均与纯相BiFeO3相吻合且具有良好的晶体结构,La和Co共掺杂的结果导致BiFeO3的晶胞体积增大.SEM形貌分析可知,晶粒尺寸随着掺杂量的增加而逐渐减小,晶粒由原来的10um逐渐减小到1um,且其晶粒形状有不规则状逐渐呈现四方状.Bi0.95La0.05Fe1-xCoxO3样品介电常数和介电损耗随着掺杂量的增加先增大而后减小.当f=1kHz,Bi0.95 La0.05 FeO3的介电常数是BiFeO3的5.96倍.其介电特性是由偶极子的取向极化和空间电荷限制电流两种极化机制共同作用的结果.La3+和Co3+掺杂使BiFeO3晶胞体积增大、晶格结构发生扭曲形变,导致BiFeO3的Fe-O-Fe健的健角增大,改变Fe-O健健长,进一步提高了BiFeO3样品的铁磁性.","authors":[{"authorName":"万正阳","id":"1f7da1ed-323a-482a-81fd-a58049e33105","originalAuthorName":"万正阳"},{"authorName":"孙彦胜","id":"03d29d44-ed71-4b33-8b16-1733fdf89238","originalAuthorName":"孙彦胜"},{"authorName":"陈正威","id":"bd68cea0-17af-4a46-8de6-b8d78cc77c64","originalAuthorName":"陈正威"},{"authorName":"宋桂林","id":"2efa1013-8577-4388-ac8d-8087cd52ea85","originalAuthorName":"宋桂林"}],"doi":"","fpage":"127","id":"31e7cb51-3045-4441-8bc5-23a2768c9db9","issue":"2","journal":{"abbrevTitle":"DWWLXB","coverImgSrc":"journal/img/cover/DWWLXB.jpg","id":"19","issnPpub":"1000-3258","publisherId":"DWWLXB","title":"低温物理学报 "},"keywords":[{"id":"f3db3273-d3ae-47fe-9661-e2e2a0712b65","keyword":"铁磁电材料","originalKeyword":"铁磁电材料"},{"id":"36cf0833-fc42-41c6-8b60-3811d86ef724","keyword":"介电特性","originalKeyword":"介电特性"},{"id":"2dd41e55-678e-42d2-887f-5fb7de9994d2","keyword":"磁滞回线","originalKeyword":"磁滞回线"}],"language":"zh","publisherId":"dwwlxb201602009","title":"多铁材料Bi0.95La0.05Fe1-xCoxO3的介电和铁磁特性研究","volume":"38","year":"2016"},{"abstractinfo":"砷对70/30黄铜在1NNaNO_2水溶液中应力腐蚀开裂的抑制作用罗贤竟,俞健(上海材料研究所,上海200437)发表于《中国腐蚀与防护学报》,1991;11(1):83.获中国腐蚀与防护学会第三届全国青年腐蚀科技论文讲评会优秀奖罗贤觉,84年毕业于哈尔滨船舶工程学院.现在上海材料研究所从事应力腐蚀方面的工作.砷对70/30黄铜在1NNaNO_2水溶液中应力腐蚀开裂的抑制作用@罗贤竟,俞健$上海材料研究所....","authors":[{"authorName":"罗贤竟","id":"6b39415b-ab79-405e-bcf3-cbfd530c46d9","originalAuthorName":"罗贤竟"},{"authorName":"俞健","id":"2eacdf3c-c54d-43da-af65-345fa5b5f6ce","originalAuthorName":"俞健"}],"categoryName":"|","doi":"","fpage":"115","id":"f755fa7d-ba79-4327-adb9-204429f8e5bc","issue":"1","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报(英文)"},"keywords":[],"language":"zh","publisherId":"1002-6495_1994_1_17","title":"砷对70/30黄铜在1NNaNO_2水溶液中应力腐蚀开裂的抑制作用","volume":"6","year":"1994"},{"abstractinfo":"高温杭氧化性差是限制钛合金作为高温结构材料在航空航天领域广泛应用的关健问题.从涂层体系出发,综述了国内外钛合金高温抗氧化涂层的研究进展.根据涂层的制备方法和性能,对比了各涂层的优缺点,分析了涂层研究中面临的问题,并提出了解决方法,展望了钛合金高温抗氧化涂层的发展方向.","authors":[{"authorName":"李威","id":"5a124abf-251c-4e86-88ab-4e70cbe779e2","originalAuthorName":"李威"},{"authorName":"肖来荣","id":"889164c6-b2a5-4fd3-8a88-9880a05b5041","originalAuthorName":"肖来荣"},{"authorName":"温燕宁","id":"3d260fed-f44a-43dd-b48b-20298b5b026e","originalAuthorName":"温燕宁"},{"authorName":"胡加瑞","id":"cdcbd984-8d37-4166-955a-d4b9c4d7a430","originalAuthorName":"胡加瑞"},{"authorName":"蔡圳阳","id":"1617f45e-1930-4301-bc43-285ed0dfa433","originalAuthorName":"蔡圳阳"},{"authorName":"殷傲宇","id":"f44bc67a-5198-4329-bbaa-a456e536a6d6","originalAuthorName":"殷傲宇"}],"doi":"","fpage":"123","id":"0a27f241-610e-4836-ae8e-4c11a6d8d002","issue":"1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"b07b676d-2efd-41aa-b30a-4aed465e2a42","keyword":"钛合金","originalKeyword":"钛合金"},{"id":"cb5973fd-f36b-43a6-938c-7d32e729052b","keyword":"高温抗氧化","originalKeyword":"高温抗氧化"},{"id":"4b793336-6113-4999-b3ce-77ed58e880a7","keyword":"涂层","originalKeyword":"涂层"},{"id":"39a617f4-87b0-4331-bef3-8b035d6fa323","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"cldb201101026","title":"钛合金高温抗氧化涂层的研究进展","volume":"25","year":"2011"},{"abstractinfo":"通过对ER7车轮钢断裂韧性试验的分析总结得出:ER7车轮钢的KQ值较高时,试验结果会受到试验参数设置的影响,具有不确定性,断口上也会出现明显的塑性变形带,晶粒细化、均匀,先析出铁素体均匀分布于珠光体周围是提高车轮钢KQ值的关健.","authors":[{"authorName":"王丽英","id":"06a56c6f-ce20-4fbb-9668-d7dabbee35bc","originalAuthorName":"王丽英"},{"authorName":"李伟","id":"bf195693-886c-4261-8755-a18a744341da","originalAuthorName":"李伟"}],"doi":"","fpage":"33","id":"3437ac04-f413-454c-9141-5785c3d6f9ec","issue":"4","journal":{"abbrevTitle":"WLCS","coverImgSrc":"journal/img/cover/WLCS.jpg","id":"64","issnPpub":"1001-0777","publisherId":"WLCS","title":"物理测试"},"keywords":[{"id":"b602671a-6687-4c3a-996f-428a98e859e8","keyword":"车轮钢","originalKeyword":"车轮钢"},{"id":"7946b977-b36b-44d9-bd06-9ebc83b84a5a","keyword":"KQ值","originalKeyword":"KQ值"},{"id":"75e27b43-1a40-4bb0-8ac4-1a765bc5ba85","keyword":"断裂韧性","originalKeyword":"断裂韧性"}],"language":"zh","publisherId":"wlcs201004009","title":"ER7车轮钢的KQ值试验结果与分析","volume":"28","year":"2010"},{"abstractinfo":"2011年12月2日,中科院等离子所为国际热核聚变实验堆(ITER)计划中国制造任务的首件产品“ITER环向场(TF)超导导体”在安徽合肥举办交付启运仪式。科技部副部长曹健林、ITER国际组织总干事本岛修、中国国际核聚变能源计划执行中心副主任罗德隆等出席仪式。","authors":[],"doi":"","fpage":"60","id":"7955e888-a557-4d8d-92c1-664bd5c84573","issue":"12","journal":{"abbrevTitle":"ZGCLJZ","coverImgSrc":"journal/img/cover/中国材料进展.jpg","id":"80","issnPpub":"1674-3962","publisherId":"ZGCLJZ","title":"中国材料进展"},"keywords":[{"id":"c45ba4bd-0526-4860-8b80-8a85e6744f21","keyword":"ITER计划","originalKeyword":"ITER计划"},{"id":"9caf2b7b-22cb-466d-b967-cad6a7f48a59","keyword":"中国制造","originalKeyword":"中国制造"},{"id":"c12173a1-9bbd-4346-be1d-6f8f087353be","keyword":"国际热核聚变实验堆","originalKeyword":"国际热核聚变实验堆"},{"id":"1306cebc-b8f5-4bff-ac3a-bd8c1fed8df2","keyword":"产品","originalKeyword":"产品"},{"id":"729b7003-24bf-4b37-aa51-45cb09893f5a","keyword":"国际组织","originalKeyword":"国际组织"},{"id":"e1d62c56-708d-43db-bfec-db418d99079f","keyword":"能源计划","originalKeyword":"能源计划"},{"id":"7808faf9-3666-4f5b-b822-42e488c32328","keyword":"环向场","originalKeyword":"环向场"},{"id":"3044a28b-d378-47b1-984d-32c9ee773ca2","keyword":"等离子","originalKeyword":"等离子"}],"language":"zh","publisherId":"zgcljz201112020","title":"ITER计划中国制造任务首件产品启运","volume":"30","year":"2011"}],"totalpage":5,"totalrecord":47}