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Process of Re-Resourcing of Converter Slag

GAO Jin-tao , LI Shi-qi , ZHANG Yan-ting , ZHANG Yan-ling , CHEN Pei-yu , SHEN Ping

钢铁研究学报(英文版)

The process of “re-resourcing of converter slag” was put forward based on the analysis of the existing steel slag treatment process. The converter slag obtained from Jinan steel plant was studied. After grinding, the slag contained 33% of iron particles, 5484% of magnetic part (wTFe=20%), and 4184% of non-magnetic part, which could be used for making cement directly. At a temperature below 1000 ℃, the non-magnetic Fe2O3 in the slag could be efficiently reduced to magnetic iron by pure H2 and CO. The slag after precise reduction had high degree of dispersion and did not get sintered, which provided an optimum condition for the separation of iron and impurities. To separate the slag and enrich the iron after reduction, the laboratory-scale device of magnetic separation was designed and made. The process of slag re-resourcing, which included magnetic sorting, precise reduction, magnetic separation, and removal of free calcium oxide (f-CaO), was proposed to obtain iron-rich magnetic materials and cement adulterant materials. Through this process, 33 kg iron particles, 150 kg iron-rich material and 700 kg cement could be obtained in each ton slag. Besides, this process to recycle converter slag had a lower energy and material consumption and no pollutant emission.

关键词: converter slag , resource recycling , precise reduction , cement

转炉钢渣的物理化学和矿物特性分析

张朝晖,焦志远,巨建涛,鲁慧慧

钢铁

为了合理回收转炉钢渣中的铁,以临钢钢渣为原料,采用光谱半定量全分析、X衍射、扫描电镜、和电子探针等方法分析试样的物理化学和矿物特性,并对原渣的粒度和金属分布进行测定。结果表明:转炉钢渣中主要物相是硅酸二钙、硅酸三钙和熟石灰,含铁物相主要有金属态(Fe)、简单化合态(Fe2O3、Fe3O4、Fe2O3·nH2O和FeCO3等)、铁酸盐(2CaO·Fe2O3等)和固溶体(MgO·2FeO),全铁品位高达23.39%,分布比较分散;钢渣比较难磨且具有选择性破碎特性。研究结果为后续钢渣加工和综合利用提供了依据。

关键词: 转炉钢渣 , physicochemical property , mineralogical property , grinding

不同处理条件下转炉渣活性的分析

钱强

钢铁

不同预处理工艺对转炉渣矿物组成的影响不同,急冷及陈化处理有利于活性矿物的生成。转炉渣中的游离钙结构致密使反应缓慢,经过消解陈化处理,生成硅钙石和Ca(OH)2固溶体,既有利于游离钙的消解,又可提高其活性。因此,将钢渣用于混合材时,需严格控制游离钙质量分数在4%~5%范围内,以实现高效利用。

关键词: 转炉渣 , mineral composition , microstructure

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