{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"讨论了新奇的环状<span style=\"color:red\">亚砜</span>衍生物α-<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>DTMSO的合成及其萃金机理,<span style=\"color:red\">四</span><span style=\"color:red\">氢</span>塞吩<span style=\"color:red\">亚砜</span>TMSO与NaH作用生成中间体后用溴代<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>处理生成DTMSO.萃取反应为放热反应,反应热为-15.3kJ@mol-1.DTMSO在低酸度盐酸溶液中以中性溶剂化机理萃金,萃合物组成为(HAuCl4).3DTMSO,DTMSO通过氧与金配位;高酸度条件下,以离子缔合机理萃金,DTMSO和AuCl4-发生内配位转变.","authors":[{"authorName":"吴松平","id":"100e0b95-33ec-4650-9cea-69fb66295f72","originalAuthorName":"吴松平"},{"authorName":"古国榜","id":"0d6207fc-b88a-4cf2-bc53-2d43a128d1e9","originalAuthorName":"古国榜"},{"authorName":"曹珍年","id":"3009ba2c-57b1-4a48-b266-53018acd209b","originalAuthorName":"曹珍年"},{"authorName":"朱萍","id":"d1bd1967-500a-46d8-ac3a-acf6ba893f3b","originalAuthorName":"朱萍"}],"doi":"","fpage":"144","id":"1907d745-402b-4a54-8f4c-56b23c0a587b","issue":"2","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"91099afb-0a60-4512-a635-ee192d0ef5d3","keyword":"α-<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>","originalKeyword":"α-十二烷-四氢噻吩亚砜"},{"id":"a2b8e52f-5b79-41fa-aacd-bbd4593feba6","keyword":"萃取","originalKeyword":"萃取"},{"id":"992f6d66-67e7-40c2-a4d5-403a5860bbec","keyword":"金","originalKeyword":"金"}],"language":"zh","publisherId":"xyjsclygc200302016","title":"环状<span style=\"color:red\">亚砜</span>衍生物α-<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>的合成及其萃金机理研究","volume":"32","year":"2003"},{"abstractinfo":"本文讨论了环状<span style=\"color:red\">亚砜</span>衍生物α-<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>(DTMSO)的萃钯机理,DTMSO在盐酸溶液中、低酸度条件下,同时存在中性溶剂络合萃取机理和离子缔合萃取机理.<span style=\"color:red\">亚砜</span>通过硫和氧原子与钯配合;在高酸度条件下,<span style=\"color:red\">亚砜</span>以离子缔合萃取机理萃钯,萃合物发生<span style=\"color:red\">亚砜</span>对Pdl2-4的内配位转变.","authors":[{"authorName":"吴松平","id":"a00ee367-28a5-4859-b7f8-174f97c0d37a","originalAuthorName":"吴松平"},{"authorName":"古国榜","id":"53ca4a21-f074-459d-a435-74a2ffb656c6","originalAuthorName":"古国榜"}],"doi":"10.3969/j.issn.1004-0676.2002.02.004","fpage":"16","id":"806d72a9-912c-4749-bf07-22115adcd583","issue":"2","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"a115bf52-f122-4fa5-abbe-e501986d152c","keyword":"α-<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>","originalKeyword":"α-十二烷-四氢噻吩亚砜"},{"id":"bf647a44-dd3b-4f23-9f5b-0780acd5d65b","keyword":"萃取","originalKeyword":"萃取"},{"id":"65671b96-115a-4ce1-a01f-9006d5fb9d01","keyword":"钯","originalKeyword":"钯"}],"language":"zh","publisherId":"gjs200202004","title":"DTMSO的萃钯机理研究","volume":"23","year":"2002"},{"abstractinfo":"采用多种理论研究方法对2-丁基-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>(BTHTO)及其钯配合物进行几何优化,发现BHandH/6-31G*法所得构型最优,从理论上研究BTHTO与钯(II)的配合模式及其分子稳定性的关系.结果表明Pd-O配位的A模式能量最高,Pd-S配位的B模式能量最低最稳定,而混合配位的C模式能量稍高于B.环状<span style=\"color:red\">亚砜</span>中的氧原子处于分子的外侧,所受位阻较小,配位速度较快;硫原子受环状结构和侧链影响,位阻较大,配位速度较慢.在萃取过程中,萃合物以硫氧混合配位的C模式形成,随时间的增加,氧配位转化为硫配位即B模式,能量达到最低值,为热力学的稳定状态.","authors":[{"authorName":"徐志广","id":"2b141b75-45ef-439c-8ff3-e6229fe7f29c","originalAuthorName":"徐志广"},{"authorName":"古国榜","id":"a9e55c6c-41d3-415a-9732-d3b6a0aa349e","originalAuthorName":"古国榜"},{"authorName":"刘海洋","id":"154e9110-6644-4857-a956-2652a07c2481","originalAuthorName":"刘海洋"},{"authorName":"吴松平","id":"37c9c5ec-76e6-4e81-aa94-69ad3729dd0e","originalAuthorName":"吴松平"}],"doi":"10.3969/j.issn.1004-0676.2007.01.003","fpage":"9","id":"b3ec1d65-8b5d-4903-a3f5-3b2275658126","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"855c0a7d-fae5-4b2c-9d60-462e327ad831","keyword":"配位化学","originalKeyword":"配位化学"},{"id":"1c1a2020-4564-41c3-9426-d943450f687e","keyword":"钯","originalKeyword":"钯"},{"id":"681fcb47-fa36-4c53-8436-695e458b8335","keyword":"理论研究","originalKeyword":"理论研究"},{"id":"a3727a88-131c-476c-a42a-c23d7606326c","keyword":"2-丁基-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>","originalKeyword":"2-丁基-四氢噻吩亚砜"},{"id":"ae320930-24d4-4384-9173-65eae6a711fe","keyword":"配位","originalKeyword":"配位"}],"language":"zh","publisherId":"gjs200701003","title":"2-丁基-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>及其钯配合物异构体的理论研究","volume":"28","year":"2007"},{"abstractinfo":"为了更好地认识加氢脱硫和催化加氢反应中的载体影响和助剂效应,在同样的催化剂制备方法及反应条件下,研究了<span style=\"color:red\">噻吩</span>加氢脱硫(HDS)和<span style=\"color:red\">四</span><span style=\"color:red\">氢</span>萘催化加氢(HYD)反应. 结果表明,对于无助剂的Mo和W催化剂,载体对催化活性的影响顺序为TiO2-Al2O3＞ZrO2＞Al2O3. 助剂的添加改变了催化剂活性顺序. Ni助剂催化剂的活性明显高于Co助剂催化剂. ZrO2担载的添加Ni的Mo和W催化剂分别获得了最佳的HDS和HYD活性. 然而,添加Pt的Mo和W催化剂其HDS和HYD活性仅是Pt与Mo(W)二者的加和,Pt与Mo(W)之间没有协同效应. 先将担载的Mo和W预硫化再将助剂引入体系的催化剂制备方法可以避免Ni和Co过早硫化形成类硫化镍(或硫化钴)物相,与采用螯合物分子方法制备的催化剂间有一定的相似性.","authors":[{"authorName":"季亚英","id":"c6cc7859-4130-4cf2-a673-8ddd49dcd306","originalAuthorName":"季亚英"},{"authorName":"","id":"e4da9d2a-ff5f-4a72-a775-0e265821d4b2","originalAuthorName":""},{"authorName":"","id":"ea657cf7-f7be-4217-b222-514f1abaecf7","originalAuthorName":""},{"authorName":"李文钊","id":"6704ae63-2c24-434c-a1f8-6cd248398921","originalAuthorName":"李文钊"},{"authorName":"徐恒泳","id":"eb39aa6c-925c-4685-9bbb-2d64f22da3e6","originalAuthorName":"徐恒泳"}],"doi":"","fpage":"32","id":"c7fe2faa-8a66-407a-831f-5f752e14956d","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"cc200b2d-1d60-4785-a901-2b74be74c404","keyword":"<span style=\"color:red\">噻吩</span>","originalKeyword":"噻吩"},{"id":"c9823da6-c4e2-488f-bb55-dd6370d1853c","keyword":"加氢脱硫","originalKeyword":"加氢脱硫"},{"id":"58123b5a-d185-4c3f-bb79-e96704317d14","keyword":"<span style=\"color:red\">四</span><span style=\"color:red\">氢</span>萘","originalKeyword":"四氢萘"},{"id":"691e991d-476b-487f-83b0-a9792348616b","keyword":"预硫化","originalKeyword":"预硫化"},{"id":"02283c4d-353a-49b4-a39f-9106aad0a372","keyword":"载体影响","originalKeyword":"载体影响"},{"id":"1a430d5a-3f7d-4e33-a017-13fedbb68f28","keyword":"助剂效应","originalKeyword":"助剂效应"}],"language":"zh","publisherId":"cuihuaxb200301009","title":"<span style=\"color:red\">噻吩</span>加氢脱硫和<span style=\"color:red\">四</span><span style=\"color:red\">氢</span>萘催化加氢反应中载体和助剂的影响","volume":"24","year":"2003"},{"abstractinfo":"讨论了环状<span style=\"color:red\">亚砜</span>衍生物α-<span style=\"color:red\">十二</span>烷基-<span style=\"color:red\">四</span><span style=\"color:red\">氢</span><span style=\"color:red\">噻吩</span><span style=\"color:red\">亚砜</span>(dtmso)与Au(Ⅲ)萃合物的组成和结构. 应用斜率法、饱和浓度法讨论了萃合物中<span style=\"color:red\">亚砜</span>的配位数, 得知在高酸度下介质中, <span style=\"color:red\">亚砜</span>离子缔合机理萃取金, <span style=\"color:red\">亚砜</span>的配位数为3, 形成的萃合物的组成为[H(dtmso)3 (AuCl4)]. 用紫外光谱UV、红外光谱FT-IR研究了萃合物的结构及其变化, 发现萃合物内部发生内配位转变, Au(Ⅲ)与<span style=\"color:red\">亚砜</span>基团中的氧原子产生配位键, 在萃合物中存在trans-[AuCl4(dtmso-O)2]-.","authors":[{"authorName":"刘会冲","id":"ce37f7a7-bdd9-451a-9b1a-ad4b1436e9ff","originalAuthorName":"刘会冲"},{"authorName":"吴松平","id":"7e03fe72-d0b6-4fd3-a676-97284238cb18","originalAuthorName":"吴松平"},{"authorName":"古国榜","id":"308afe15-b20b-4bfc-b1ad-66b6e7082bae","originalAuthorName":"古国榜"}],"doi":"10.3969/j.issn.0258-7076.2005.04.009","fpage":"429","id":"b1707b44-3261-412a-bf6a-3bae19dd4a2e","issue":"4","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"431ca33a-fec7-4926-902c-c394a1f0d7b2","keyword":"环状<span style=\"color:red\">亚砜</span>","originalKeyword":"环状亚砜"},{"id":"3abbe4a6-7840-40de-be63-009aacce3237","keyword":"金","originalKeyword":"金"},{"id":"76849976-25dd-4085-9437-19e842c855a9","keyword":"溶剂萃取","originalKeyword":"溶剂萃取"}],"language":"zh","publisherId":"xyjs200504009","title":"环状<span style=\"color:red\">亚砜</span>衍生物与Au(Ⅲ)萃合物的组成及结构研究","volume":"29","year":"2005"},{"abstractinfo":"利用荧光光谱法,研究了1,4,7,10-<span style=\"color:red\">四</span>氮杂环<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>合钴(Cyclen-Co(Ⅱ))配合物与牛血清白蛋白(BSA)的相互作用,用Stern-Volmer和Lineweaver-Burk方程确定了其荧光猝灭机理为静态猝灭,计算得到了在不同温度和pH值条件下以及在聚氧乙烯(23)月桂醇醚(Brij35)、十六烷基三甲基溴化铵(CTAB)、<span style=\"color:red\">十二</span>烷基硫酸钠(SDS)3种表面活性剂胶束溶液中,Cyclen-Co(Ⅱ)和BSA作用的结合点位数、结合常数和热力学参数,研究结果表明,其作用力主要为氢键和范德华力.","authors":[{"authorName":"刘凡","id":"f8df4eeb-ae46-47ca-97af-7d76fd49aadf","originalAuthorName":"刘凡"},{"authorName":"张元勤","id":"b33c7e26-3e4d-4ae3-82eb-8294a27583d8","originalAuthorName":"张元勤"},{"authorName":"张智锦","id":"b31fff88-a0cf-45ff-b374-dd49ffbc9acb","originalAuthorName":"张智锦"}],"doi":"10.3724/SP.J.1095.2013.20140","fpage":"232","id":"5d52ba71-4495-4889-a2e0-682be6cff6d4","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ce1687a7-f716-4702-a0b8-f01d6eb62b88","keyword":"<span style=\"color:red\">四</span>氮杂环<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>合钴","originalKeyword":"四氮杂环十二烷合钴"},{"id":"3c1b7159-3312-47fc-85f1-ca15eea1f3ab","keyword":"牛血清白蛋白","originalKeyword":"牛血清白蛋白"},{"id":"bf83a43e-62d8-40ed-8fae-3f98b18206ff","keyword":"荧光光谱","originalKeyword":"荧光光谱"},{"id":"844cccd2-d069-40bd-8c1c-46b0eea4833d","keyword":"结合位点数","originalKeyword":"结合位点数"},{"id":"c20779c8-644e-4ddc-b6f8-d3a5c90f6ec6","keyword":"结合常数","originalKeyword":"结合常数"}],"language":"zh","publisherId":"yyhx201302019","title":"1,4,7,10-<span style=\"color:red\">四</span>氮杂环<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>合钴与牛血清白蛋白的相互作用","volume":"30","year":"2013"},{"abstractinfo":"利用X射线衍射、N2物理吸附与NH3-程序升温脱附等手段以及异辛烷加氢裂化探针反应研究了硅烷化处理对Pt/SAPO-11催化剂结构和酸性的影响, 并考察了催化剂对正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>临<span style=\"color:red\">氢</span>异构化反应的催化性能. 结果表明,硅烷化处理有效清除了样品外表面的酸性位,减少了发生在外表面的非选择性裂化反应. 硅烷化处理后,催化剂对单支链异构体的选择性明显提高,尤其对单支链端甲基异构体的选择性显著提高,但催化剂的总体异构化选择性有所降低. 硅烷化处理可能造成催化剂的孔口窄化,从而提高单支链异构体的选择性,但同时也导致其微孔孔道内裂化反应的增多.","authors":[{"authorName":"汪哲明","id":"f5c0ccf4-8a48-49e8-9739-226e360b8dfa","originalAuthorName":"汪哲明"},{"authorName":"田志坚","id":"ebe8a4dd-7f88-414a-8d01-a3cb4717c79a","originalAuthorName":"田志坚"},{"authorName":"滕飞","id":"8de86bef-29ed-426f-833f-f7c03bfe1bef","originalAuthorName":"滕飞"},{"authorName":"徐云鹏","id":"8c359a0b-e704-4e76-a80c-2898ee5f6fef","originalAuthorName":"徐云鹏"},{"authorName":"胡胜","id":"38dde321-8814-41f2-b119-7f02edd70ff3","originalAuthorName":"胡胜"},{"authorName":"谭明伟","id":"f1df026d-1fb1-4ced-8c95-2d903daaa38c","originalAuthorName":"谭明伟"},{"authorName":"徐竹生","id":"83745a0f-da2f-47e9-9b39-c4491d1d29ca","originalAuthorName":"徐竹生"},{"authorName":"林励吾","id":"756e616e-2687-4454-9509-9597fd828ec8","originalAuthorName":"林励吾"}],"doi":"","fpage":"819","id":"7c2ba8ca-c4fa-41bb-a5f0-7b285a91436e","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"f75c5de3-b06a-4d1d-ab29-0ff9afcbbe46","keyword":"硅烷化","originalKeyword":"硅烷化"},{"id":"53946700-d944-4c8c-8643-37dcad6e0685","keyword":"铂","originalKeyword":"铂"},{"id":"6c3b77ad-b9a3-4330-a26c-89154de0c7a9","keyword":"SAPO-11分子筛","originalKeyword":"SAPO-11分子筛"},{"id":"2fa0aaee-8d4a-4296-a812-2af2a599532b","keyword":"正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>","originalKeyword":"正十二烷"},{"id":"ae7b42cf-b55b-4226-8d08-a07dec7deda0","keyword":"临<span style=\"color:red\">氢</span>异构化","originalKeyword":"临氢异构化"},{"id":"d79ef8d2-a9fb-4f99-a225-3bed11e1e04f","keyword":"选择性","originalKeyword":"选择性"}],"language":"zh","publisherId":"cuihuaxb200509020","title":"硅烷化处理对Pt/SAPO-11催化正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>临<span style=\"color:red\">氢</span>异构化反应性能的影响","volume":"26","year":"2005"},{"abstractinfo":"采用常规水热合成法合成了系列MgAPO-11分子筛,考察了晶化时间、 P/Al投料比和Mg源对MgAPO-11分子筛的物相、酸性以及Pt/MgAPO-11催化正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>临<span style=\"color:red\">氢</span>异构化反应性能的影响. 分别用X射线衍射、 X射线荧光光谱和NH3程序升温脱附测定了样品的晶相、 Mg含量和酸性质. 结果表明,合成条件影响着合成产物的晶相组成、 Mg含量及酸性质,从而影响到Pt/MgAPO-11在正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>临<span style=\"color:red\">氢</span>异构化反应中的催化性能. 反应结果显示, Pt/MgAPO-11催化剂的催化活性与MgAPO-11分子筛的强酸位数目密切相关. 较短的晶化时间、合成凝胶的P/Al摩尔比为1.0以及使用Mg(NO3)2为Mg源有利于提高MgAPO-11的强酸位数目,从而提高Pt/MgAPO-11的催化活性.","authors":[{"authorName":"杨晓梅","id":"436bdf64-f3fa-4689-800f-fd73656741c1","originalAuthorName":"杨晓梅"},{"authorName":"徐竹生","id":"8ad81e5a-72d0-4782-a213-93d4b78bcad6","originalAuthorName":"徐竹生"},{"authorName":"马怀军","id":"c796cf2b-6aeb-4219-818f-d5fdb4923b3d","originalAuthorName":"马怀军"},{"authorName":"徐云鹏","id":"277e69a0-da25-4695-85e9-1d2607f31c36","originalAuthorName":"徐云鹏"},{"authorName":"田志坚","id":"9b787595-61ad-4f9c-b0b1-36f3b99f9fa4","originalAuthorName":"田志坚"},{"authorName":"林励吾","id":"c83f3396-7307-43ac-8238-f62da7e17a35","originalAuthorName":"林励吾"}],"doi":"","fpage":"1039","id":"3c07f74a-9cff-46c3-a3f3-d719438044d6","issue":"11","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"4127b012-2237-41f7-898c-7229beb1967a","keyword":"铂","originalKeyword":"铂"},{"id":"e6e05320-0c01-430c-a919-f063eb9a0e4d","keyword":"MgAPO-11","originalKeyword":"MgAPO-11"},{"id":"bac874bd-6263-4f9a-aaf1-19707f5e27c1","keyword":"负载型催化剂","originalKeyword":"负载型催化剂"},{"id":"6e8ffbea-3350-4880-9e93-7928cd475699","keyword":"正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>","originalKeyword":"正十二烷"},{"id":"20540a63-783f-4ca6-8800-f8629e605188","keyword":"临<span style=\"color:red\">氢</span>异构化","originalKeyword":"临氢异构化"},{"id":"edecbcde-f5c7-4022-ab5f-bf79b59a35ae","keyword":"晶化时间","originalKeyword":"晶化时间"},{"id":"2fc9da17-c106-4fb2-88f3-915528761e30","keyword":"磷铝比","originalKeyword":"磷铝比"},{"id":"1351b64e-f4fa-4207-93fb-b364609c9c5f","keyword":"镁源","originalKeyword":"镁源"}],"language":"zh","publisherId":"cuihuaxb200611021","title":"MgAPO-11分子筛的合成及Pt/MgAPO-11在正<span style=\"color:red\">十二</span><span style=\"color:red\">烷</span>临<span style=\"color:red\">氢</span>异构化反应中的催化性能","volume":"27","year":"2006"},{"abstractinfo":"以化学氧化法制备聚合物然后用碘进行掺杂处理使其导电,用表面电阻率、热失重分析、X射线光电子能谱研究了<span style=\"color:red\">十二</span>烷基取代聚<span style=\"color:red\">噻吩</span>在经反复加热和掺杂处理后的性能和结构变化.表面电阻率受温度的影响较大,在温度达到200℃以上时,该聚合物部分或全部丧失导电性.从X-射线光电子能谱可明显观察到空气中氧气参与了加热和掺杂过程并发生的物理化学反应.<span style=\"color:red\">十二</span>烷基取代聚<span style=\"color:red\">噻吩</span>掺杂后的热去掺杂过程在较低温度下(低于200℃)其导电性能可以恢复,但在高温下却不可恢复;而其结构经每一次热处理的破坏是不可逆转的,每一次加热处理都加速其老化降解.","authors":[{"authorName":"王金伟","id":"dbbfcbdf-321a-4886-92a3-21a4f593a27b","originalAuthorName":"王金伟"},{"authorName":"庞晓露","id":"6334ab5d-314f-48f7-83fc-b404a830a32e","originalAuthorName":"庞晓露"}],"doi":"10.3969/j.issn.1671-5381.2005.02.003","fpage":"8","id":"902aa6f6-bcf6-4b7b-adea-beaa14d35be3","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"dcdc9e4e-0692-492c-900b-b7e41138458c","keyword":"<span style=\"color:red\">十二</span>烷基取代聚<span style=\"color:red\">噻吩</span>","originalKeyword":"十二烷基取代聚噻吩"},{"id":"c8dd0d49-a0ab-42cd-9c3c-30f2fd695836","keyword":"掺杂和去掺杂","originalKeyword":"掺杂和去掺杂"},{"id":"91bb1e24-3b2b-45f1-9cba-1133be310c26","keyword":"表面电阻率","originalKeyword":"表面电阻率"},{"id":"21cfcb4f-9cd9-42d1-a5b3-1ad62428901e","keyword":"降解","originalKeyword":"降解"}],"language":"zh","publisherId":"hccllhyyy200502003","title":"加热处理对<span style=\"color:red\">十二</span>烷基取代聚<span style=\"color:red\">噻吩</span>导电性能及结构的影响","volume":"34","year":"2005"},{"abstractinfo":"本文介绍了高分子溶液混合与界面渗透法制备导电高分子复合材料的方法并对复合材料的结构和性能进行了表征.<span style=\"color:red\">十二</span>烷基取代聚<span style=\"color:red\">噻吩</span><span style=\"color:red\">四</span><span style=\"color:red\">氢</span>呋喃溶液与聚酰亚胺酸N-甲基吡咯<span style=\"color:red\">烷</span>酮在一定时间界面的互相渗透,<span style=\"color:red\">十二</span>烷基取代聚<span style=\"color:red\">噻吩</span>可嵌入聚酰亚胺酸层中.在溶剂挥发后,用化学或加热的方法进行酰胺化而得到稳定的导电高分子复合膜.表面电阻率、热失重及扫描电镜分析表明,与溶液混合法相比,界面渗透法制备的复合材料具有良好导电性能和稳定性.","authors":[{"authorName":"王金伟","id":"83ff96b5-1d55-4b68-8e5e-d62b9031b10a","originalAuthorName":"王金伟"},{"authorName":"杨槐","id":"bbe88fd3-4494-46dc-84c4-2a9292b7b637","originalAuthorName":"杨槐"}],"doi":"10.3969/j.issn.1673-2812.2005.04.004","fpage":"484","id":"a22d113c-0848-4319-9f54-ec3f0047ab00","issue":"4","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"2dc3f0ba-066d-4c14-90ee-d258d9102e5b","keyword":"导电复合材料","originalKeyword":"导电复合材料"},{"id":"a812b6ce-8455-4f9b-baee-2d0e4cf8797d","keyword":"溶液混合","originalKeyword":"溶液混合"},{"id":"db517550-cbe4-4d94-9cd6-05ddd2b5442d","keyword":"界面渗透","originalKeyword":"界面渗透"},{"id":"cc3e3b5e-adb5-481d-8a29-9a9c0dcbe3ce","keyword":"聚<span style=\"color:red\">噻吩</span>衍生物","originalKeyword":"聚噻吩衍生物"},{"id":"64f32e8a-2b34-404b-b87d-3b0df4bf1fe0","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"}],"language":"zh","publisherId":"clkxygc200504004","title":"溶液混合与界面渗透法制备聚<span style=\"color:red\">噻吩</span>衍生物/聚酰亚胺导电复合材料的研究","volume":"23","year":"2005"}],"totalpage":1790,"totalrecord":17896}