W.H. Tian
金属学报(英文版)
The microstructures of Cr modified Al3 Ti containing Al2 Ti and L10-AlTi precipitateshave been investigated in terms of transmission electron microscopy ( TEM). Fine pre-cipitation of Al2 Ti (Ga2Hf type structure) and L 1o-AlTi(Cr) occurs in L l2-Al3 Ti(Cr)by aging around 973K. The aging behavior was investigated by microhardness mea-surements. TEM observations revealed that plate-like Al2 Ti precipitates lie on { 100}planes of the L12-Al3 Ti(Cr) matrix with the c axis of the tetragonal phase perpendic-ular to the thin plate. As contrast with Al2 Ti precipitates, L1o-AlTi(Cr) precipitatesform thin plate and lie on {100} planes of L12-Al3Ti(Cr) matrix at the initial agingtime and for long time aging the habit plane of the thin plate deviated from {100}plane and finally formed a kinked plate. The coherency stresses across the precipi-tate/matrix interface are considered to be the main factor controlling the precipitatemorphology.``
关键词:
titanium aluminide
,
null
,
null
,
null
,
null
W.H. Tian
金属学报(英文版)
Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.
关键词:
NiAl intermetallics
,
null
,
null
,
null
,
null
冷文秀
,
田文怀
,
高红叶
,
成生伟
稀有金属材料与工程
研究了不同成分的Fe-Cu二元合金在过饱和固溶体状态下晶粒尺寸和硬度之间的关系,分析了Cu元素的固溶强化作用.研究了Fe-Cu二元合金的时效硬化现象和Cu元素的析出过程.结果表明Fe-Cu二元合金硬度值增加近一倍.通过透射电镜观察到随时效时间的增加,析出相的尺寸逐渐增大,形状由球形变为棒状.电子衍射花样分析得知,时效处理硬度达到最大值时对应的析出相具有B2型晶体结构,与基体之间保持平行位向关系.透射电镜观察到位错与析出相之间存在典型的引力型交互作用,由于软析出相对运动位错的钉扎效应而使Fe-Cu二元合金得到有效强化.
关键词:
析出
,
时效硬化
,
B2晶体结构
,
相变
屈华
,
刘伟东
,
刘海平
材料热处理学报
采用金相显微分析技术、布氏硬度、XRD分析、室温与高温拉伸性能测试等方法,研究了Ag对Al-5.3Cu-0.8Mg合金铸态组织与时效硬化行为的影响.研究表明:Ag对合金铸态组织有细化作用,随着Ag含量的增加,枝晶得到细化;Ag添加缩短了合金的峰时效时间,其原因在于Ag原子提高了合金析出相的形核速率,进而加速了析出相的形成;随着Ag含量的增加,合金的硬度先增加后降低,含0.8％ Ag的合金峰时效硬度最大;适量的Ag可以促进合金中Ω相的形成,过量的Ag将会抑制Ω相的形成;随着Ag含量的增加,合金的强度和热稳定性先升高后降低,当Ag含量为0.8％时,其强度和热稳定性均达到峰值;Ag提高合金强度与热稳定性的原因在于析出了热稳定性和强化作用比θ'、S'相更强的Ω相.
关键词:
Al-Cu-Mg-Ag合金
,
Ag添加
,
铸态组织
,
时效硬化
,
热稳定性
徐春杰
,
代盼
,
屠涛
,
余玲
,
张忠明
,
王锦程
材料热处理学报
采用Ar气保护制备了Mg-5Sn-1Si(质量分数,％)合金,并研究了合金的铸态组织和在480 ℃固溶处理及180 ℃和280℃不同时效热处理对合金组织中析出相演变的影响及组织与硬度的关系.结果表明,合金铸态组织由α-Mg、共晶Mg2Si、共晶Mg2Sn三相组成;经480℃固溶处理后Mg2Sn相完全固溶,粗大的Mg2Si相得到少量球化;时效处理过程中Mg2Si相得到球化.在180℃时效时,Mg2Sn无沉淀析出,硬度较低,时效保温24 h仅为24.1 HV.在280℃时效时,细小的Mg2Sn相弥散析出并使合金的硬度明显升高,时效保温18 h达到峰值硬度47.6 HV,并随时间的延长出现过时效现象.280℃时效初期,组织中形成较宽的无析出带(PFZ),随着时效时间的延长无析出带PFZ消失.
关键词:
镁合金
,
微观组织
,
固溶
,
时效硬化
,
无析出带
樊志斌
,
林小娉
,
董允
,
叶杰
,
李婵
,
李博
金属学报
doi:10.11900/0412.1961.2016.00098
在4 GPa高压下对Mg96.17Zn3.15Y0.5Zr0.18合金进行600～800℃固溶处理,之后在200℃进行等温时效处理.利用TEM,HRTEM,SEM,XRD等分析方法研究了高压固溶及随后时效处理后合金的显微组织,并测试了4 GPa高压下固溶处理后合金的时效硬化曲线.结果表明,在4 GPa高压下固溶能大幅提高Zn在Mg基体中的溶解度,Zn的溶解度由常压下400℃固溶后的2.11％(质量分数,下同)提高到4 GPa高压下700～800℃固溶后的约6.60％,获得了过饱和a-Mg固溶体.在随后的200℃温时效过程中,高压固溶合金在较短的时间内即可获得较高的近峰值硬度,4 GPa下800℃固溶的合金近峰值时效硬度高达105 HV,比400℃固溶处理合金近峰时效硬度(81 HV)提高了约30％.HRTEM观察表明,4 GPa高压下固溶合金时效沉淀析出相具有很高的析出密度,且析出相中含有粒状准晶I-Mg3Zn6Y相.
关键词:
Mg96.17Zn3.15Y0.5Zr0.18合金
,
高压固溶
,
溶解度
,
时效硬化
,
粒状准晶相
