Xifeng Lu Qilong Wang Deliang Cui
材料科学技术（英文）
g-C3N4/TiO2 composite were prepared by hydrolysis of Ti(OC4Hn 9 )4 and the precursors of g-C3N4 at room temperature and annealing in nitrogen atmosphere. X-ray diffraction results revealed that all the products were anatase structure. The chemical nature of O, N of the g-C3N4/TiO2 were identified by X-ray photoelectron spectroscopy, presenting N-Ti-O and N-Ti-N doping status of the composite. The g-C3N4/TiO2 composite showed better photocatalytic activity for the UV and visible-light degradation of Rhodamine B.
关键词:
Composite materials
,
Chemical synthesis
,
X-ray photoelectron spectroscopy (XPS)
Dangguo LI
金属学报(英文版)
The chemical composition and semi-conductive properties of passive film on nickel-based alloy (G3 alloy) in bicarbonate/carbonate buffer solution were investigated by Auger spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectra (EIS) and Mott-Schottky plot. AES and XPS results showed that the passive film appeared double-layer, in which the inner film was composed of nickel oxide, the mixed nickel-chromium-molybdenum-manganese oxides were the major component of the outer film. The electrochemical results revealed that the factors including frequency, potential, time, temperature and pH value can affect the semi-conductive property, the doping densities decreased with increasing potential and pH value, prolonging time, and decreasing temperature. According to the above results, it can be concluded that the film protection on the substrate enhanced with increasing potential and pH value, prolonging time, and decreasing temperature.
关键词:
Nickel-based alloy
,
俄歇分析
,
X-射线光电子能谱
,
电化学阻抗谱
,
Mott-Schottky曲线
