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Tunable Reactive Wetting of Sn on Microporous Cu Layer

Qingquan Lai

材料科学技术(英文)

Wetting of microporous Cu layer by liquid Sn resulted in contact angles from 0 to 33 deg., tunable by varying wetting temperature and porous microstructure. The wetting was dominated by the interfacial metallurgical reaction, which can lead to pore closure phenomenon, as the liquid infiltration facilitating the wetting process.

关键词: Wetting

Wetting Behaviors and Interfacial Reaction between Sn-10Sb-5Cu High Temperature Lead-free Solder and Cu Substrate

Qiulian Zeng

材料科学技术(英文)

Sn-10Sb-5Cu lead-free solder was fabricated for high temperature application in electronic package. Wetting behaviors and interfacial reaction between such a high temperature lead-free solder and Cu substrate were investigated and compared with those of 95Pb-Sn solder. The results showed that the wetting properties of Sn-10Sb-5Cu solder are superior to those of 95Pb-Sn solder in maximum wetting force, wetting time and wetting angle in the temperature range of 340{400°C. However, the surface of the Sn-10Sb-5Cu solder sample after wetting balance tests was rougher than that of 95Pb-Sn solder at the temperature lower than 360°C. In static liquid-state interfacial reaction, the types and thickness of the intermetallic compounds (IMCs) of both solders were different from each other. The wetting kinetics in the Sn-10Sb-5Cu/Cu system was more rapid than that in 95Pb-Sn /Cu system, and the higher formation rate of IMCs in the former system was considered as the reason.

关键词: Wetting , null , null , null

Nature and Growth of Interaction Layers Formed during the Reaction between Solid Ni and Liquid Al

Qiangang XU , Haifeng ZHANG , Bingzhe DING , Zhuangqi HU

材料科学技术(英文)

The nature and growth of the interaction layers between solid Nb and liquid Al has been studied by carrying out the tests on Nb(s)-Al(l) and Nb(s)-Al(l)-Ni(s) reaction couples isothermally reacted between 700°C and 900°C for different time intervals. It has been found that the interaction layer between Nb and Al contains two parts: a thin continuous layer of NbAl3 adjacent to the Nb surface and a two-phase zone constituted of NbAl3 particles dispersed in an Al matrix. Although the nature and growth of interaction layers follows the four-stage mechanism, a typical cruciform pattern does not occur in Nb(s)-Al(l) reaction couples. However, a cruciform pattern was observed in Nb(s)-Al(l)-Ni(s) reaction couples. The movement of NbAl3 particles is important to the production of cruciform pattern in the reaction couples.

关键词: Wetting , null , null

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