{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以偶氮二异丁腈作引发剂,<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>和苯乙烯为原料,采用溶液聚合法合成了<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>/苯乙烯共聚物,分析了原料配比、不同溶剂、引发剂用量、反应时间等工艺条件对聚合反应体系的影响.采用傅立叶红外FT-IR、热失重分析法(TG)等对聚合物的结构和性质进行了表征.结果表明,随着共聚物中<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>含量的增加,共聚物的耐热性也获得提高.","authors":[{"authorName":"王国祥","id":"e2a622d2-de41-4998-8469-a57c69d57a6e","originalAuthorName":"王国祥"},{"authorName":"陈钱","id":"2960cc53-0dc1-446c-ba25-0dc4e41abfbd","originalAuthorName":"陈钱"},{"authorName":"何斌鸿","id":"37385c12-1806-4a65-84ce-a8566ae85ca7","originalAuthorName":"何斌鸿"}],"doi":"10.3969/j.issn.1009-9239.2008.05.004","fpage":"15","id":"3550d287-223e-4b8e-8e68-52b44a3a0d59","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"58def633-c7d0-4d0a-a3f9-a60305c1f4e6","keyword":"<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-(1-萘基)马来酰亚胺"},{"id":"f4f7a20f-879f-4030-acb0-a3dd6b70b999","keyword":"合成","originalKeyword":"合成"},{"id":"69dbcc81-34a8-4b98-9bbc-19e7d21ed619","keyword":"表征","originalKeyword":"表征"},{"id":"0670324f-3757-420b-b21b-280fb3e01dfd","keyword":"工艺条件","originalKeyword":"工艺条件"}],"language":"zh","publisherId":"jycltx200805004","title":"<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>/苯乙烯共聚合研究","volume":"41","year":"2008"},{"abstractinfo":"以顺丁烯二酸酐和<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span>胺为原料,冰乙酸作溶剂,醋酸酐作脱水剂,无水醋酸钠作催化剂,采用两步法合成了<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>.产物及中间产物采用熔点测定仪、傅立叶红外FT-IR、液相色谱仪等仪器进行了表征,结果表明,合成产物为目标产品.研究了原料配比、溶剂用量、脱水剂用量、催化剂用量、反应温度、反应时间等工艺条件对反应收率的影响,确定了最佳工艺条件,使<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的收率达到88%,纯度达到95.94%.","authors":[{"authorName":"王国祥","id":"523626a8-2237-4628-90aa-5754f05bf340","originalAuthorName":"王国祥"},{"authorName":"刘华伟","id":"ca6f6ba9-52b0-419c-915d-3e17519a465b","originalAuthorName":"刘华伟"}],"doi":"10.3969/j.issn.1009-9239.2007.05.004","fpage":"10","id":"c5623146-f6f8-45ba-8c2f-51a804433216","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"e4fd7c92-6040-42c0-9e62-3cbde417213c","keyword":"<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-(1-萘基)马来酰亚胺"},{"id":"e6d03d51-795c-4aeb-9e5a-f88a20826446","keyword":"合成","originalKeyword":"合成"},{"id":"375dbc06-c40e-4020-9648-394a40a52fec","keyword":"表征","originalKeyword":"表征"},{"id":"a25c6a4f-5137-4f57-89f7-0dad4735bce5","keyword":"工艺条件","originalKeyword":"工艺条件"}],"language":"zh","publisherId":"jycltx200705004","title":"<span style=\"color:red\">N-</span>(<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span><span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>合成研究","volume":"40","year":"2007"},{"abstractinfo":"合成了<span style=\"color:red\">N-</span>[4-(4-邻苯二甲腈<span style=\"color:red\">基</span>)苯氧基]<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>(<span style=\"color:red\">1</span>)和<span style=\"color:red\">N-</span>[4-(3-邻苯二甲腈<span style=\"color:red\">基</span>)苯氧基]<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>(2)两种含氰<span style=\"color:red\">基</span>的<span style=\"color:red\">N-</span>取代苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>化合物.用FT-IR,<span style=\"color:red\">1</span>H-NMR和EA对其结构进行了确认.利用DSC和TGA等手段,初步研究了(<span style=\"color:red\">1</span>)和(2)的热行为.DSC研究结果显示:(<span style=\"color:red\">1</span>)和(2)发生<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>双键的热自由<span style=\"color:red\">基</span>聚合反应峰比传统化合物二苯甲烷双<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>(BMI)高;TGA研究结果表明,在氮气氛下305℃前,(<span style=\"color:red\">1</span>)和(2)热失重,800℃的残炭率高于BMI,分别达到了50%和57%,证明分子结构中引入腈<span style=\"color:red\">基</span>可有效降低<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>在高温下的热分解引起的热失重,提高材料的耐热性能.","authors":[{"authorName":"韩勇","id":"91c85d28-171f-4cd5-adaa-cfc35a665deb","originalAuthorName":"韩勇"},{"authorName":"武迪蒙","id":"54a5fd0c-9ef9-41fc-afc8-66c928cfaa6f","originalAuthorName":"武迪蒙"},{"authorName":"曾科","id":"f17126e9-7f85-4c5c-9ec0-5c5db037fbea","originalAuthorName":"曾科"},{"authorName":"赵庆来","id":"79073073-76b9-4dd5-83e3-9353eb1a62b4","originalAuthorName":"赵庆来"},{"authorName":"缪培凯","id":"a9299410-ddf3-48de-9973-e8077a99eaaa","originalAuthorName":"缪培凯"},{"authorName":"唐艳","id":"82478f63-0034-43d5-87ba-e6991da2668d","originalAuthorName":"唐艳"},{"authorName":"周柯","id":"826d2442-7234-4ba4-9cef-4f0a2c94956e","originalAuthorName":"周柯"},{"authorName":"唐文睿","id":"70daf95a-61e9-41b5-92e4-6b8f5297d26e","originalAuthorName":"唐文睿"},{"authorName":"杨刚","id":"88673e00-2b26-4f2c-bd99-ff527a3a7742","originalAuthorName":"杨刚"}],"doi":"","fpage":"96","id":"ffb33600-5b54-42a3-b692-6a677fcf86d3","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"9fb6556f-b571-48d9-9dd1-16668ca63640","keyword":"氰<span style=\"color:red\">基</span>","originalKeyword":"氰基"},{"id":"18832a4d-2d39-46d4-b329-1b265dfb473b","keyword":"<span style=\"color:red\">N-</span>取代苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-取代苯基马来酰亚胺"},{"id":"5801e3e3-8004-4aba-90ae-900efbea4935","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gfzclkxygc200703024","title":"含氰<span style=\"color:red\">基</span>的<span style=\"color:red\">N-</span>取代苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的合成及性能","volume":"23","year":"2007"},{"abstractinfo":"以AIBN为引发剂在氯仿溶剂中成功地合成了耐热型聚苯乙烯-苯乙烯/<span style=\"color:red\">N-</span>(α-甲基-丁酯<span style=\"color:red\">基</span>)-<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>共聚物(St-co-BAM).通过IR、TG、DTA对共聚物的表征,研究了其耐热性能;讨论了单体全程配比、温度、引发剂浓度对共聚合初始速率的影响,测得共聚合总活化能Ea＝76.2 kJ/mol,共聚合增长活化能Ep=13.4 kJ/mol,比一般的正常乙烯<span style=\"color:red\">基</span>单体Ep值小.","authors":[{"authorName":"艾娇艳","id":"5cbc1f45-587d-4d9b-9abe-39c5d87b3475","originalAuthorName":"艾娇艳"},{"authorName":"刘朋生","id":"f1c7d848-56f4-419d-a0f2-0b0ec70ec1fd","originalAuthorName":"刘朋生"},{"authorName":"周述璋","id":"50ed3260-9e67-4643-aac5-a2993297e81b","originalAuthorName":"周述璋"}],"doi":"","fpage":"196","id":"19d4e784-21f5-4b0e-9acd-71b5e00bb053","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"41089f60-90a2-4bce-8629-3710b34e78b4","keyword":"<span style=\"color:red\">N-</span>(α-甲基-丁酯<span style=\"color:red\">基</span>)-<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-(α-甲基-丁酯基)-马来酰亚胺"},{"id":"7acc52af-47fc-4204-978e-85255762c276","keyword":"耐热型聚苯乙烯","originalKeyword":"耐热型聚苯乙烯"},{"id":"8dce5c23-4f8d-4423-9bb1-5efd241789d9","keyword":"自由<span style=\"color:red\">基</span>共聚","originalKeyword":"自由基共聚"}],"language":"zh","publisherId":"gfzclkxygc200203050","title":"<span style=\"color:red\">N-</span>(α-甲基-丁酯<span style=\"color:red\">基</span>)-<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>/苯乙烯共聚合研究","volume":"18","year":"2002"},{"abstractinfo":"对<span style=\"color:red\">N-</span>(苯并环丁烯-4-<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>原有文献的合成方法进行了改进,在温和条件下使该单体产率有所提高.研究了该单体分别与苯乙烯和<span style=\"color:red\">N-</span>苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>在溶液中的二元共聚反应,对所得的共聚物进行表征,并对其热性能进行了分析.结果表明,<span style=\"color:red\">N-</span>(苯并环丁烯-4-<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的均聚物具有很高的热分解温度,初始分解温度为400℃,480℃的热失重仅为10%,将其与苯乙烯共聚可显著提高苯乙烯的耐热性,有望用于高性能复合材料的树脂基体.","authors":[{"authorName":"杨海君","id":"017ea6b9-f42e-4e7c-8487-ce727a4149fa","originalAuthorName":"杨海君"},{"authorName":"朱海亮","id":"4fd5b59e-7bd2-4325-a36c-823aba5a0051","originalAuthorName":"朱海亮"},{"authorName":"杨军校","id":"0588947b-6731-4262-baa2-a186c010cb84","originalAuthorName":"杨军校"},{"authorName":"刘才林","id":"e7fe18fa-8ae5-4d5f-b3e0-ecae569260b7","originalAuthorName":"刘才林"},{"authorName":"谢如刚","id":"2eeb74c4-9177-4a91-8761-d1950e426ba7","originalAuthorName":"谢如刚"}],"doi":"","fpage":"129","id":"44ce5016-d019-4b62-9d2a-b73a54604b0c","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"0d41f66c-f2b6-4109-ac0a-49768a9b46da","keyword":"<span style=\"color:red\">N-</span>(苯并环丁烯-4-<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-(苯并环丁烯-4-基)马来酰亚胺"},{"id":"a710e6c8-5dcc-4646-9e8b-58573fd48eef","keyword":"热稳定性","originalKeyword":"热稳定性"},{"id":"ad001257-2178-4c1c-9ce7-1c7019140620","keyword":"聚合","originalKeyword":"聚合"}],"language":"zh","publisherId":"gfzclkxygc201010034","title":"<span style=\"color:red\">N-</span>(苯并环丁烯-4-<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的制备及热稳定性","volume":"26","year":"2010"},{"abstractinfo":"以氯苯、α-氯代<span style=\"color:red\">萘</span>、氯磺酸、二氯亚砜为原料,合成了4-氯-<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span>磺<span style=\"color:red\">酰</span>氯,经Frield-Craft磺<span style=\"color:red\">酰</span><span style=\"color:red\">基</span>化反应,合成了含两个<span style=\"color:red\">1</span>,4-<span style=\"color:red\">萘</span>结构的4-氯-<span style=\"color:red\">1-</span>（4′-氯-<span style=\"color:red\">1-</span><span style=\"color:red\">萘</span>磺<span style=\"color:red\">酰</span><span style=\"color:red\">基</span>）<span style=\"color:red\">萘</span>（CCNSN）。CCNSN分别与双酚A、酚酞、对苯二酚及4-（4-羟基苯基）-2,3-二氮杂<span style=\"color:red\">萘</span>-<span style=\"color:red\">1-</span>酮经溶液亲核取代逐步聚合反应,合成了4种含<span style=\"color:red\">1-</span>（<span style=\"color:red\">萘</span>-<span style=\"color:red\">1-</span>磺<span style=\"color:red\">酰</span><span style=\"color:red\">基</span>）<span style=\"color:red\">萘</span>结构的聚芳醚（Pa~Pd）。用NMR、FT-IR对单体和聚合物进行了表征,证明其结构正确;用DSC、TGA和WAXD等方法对聚合物的热性能及结晶性进行了表征,结果表明,聚合物的玻璃化转变温度在226℃~318℃之间,氮气环境下,5%热失重的起始温度均在450℃以上,说明具有良好的热稳定性;考察了聚合物的溶解性能,除Pc不溶于常见的有机溶剂外,Pa、Pb、Pd皆可溶于氯仿（CHCl3）、<span style=\"color:red\">1,1</span>,2,2-四氯乙烷（TCE）和<span style=\"color:red\">N</span>,<span style=\"color:red\">N-</span>二甲基乙酰胺（DMAC）、<span style=\"color:red\">N-</span>甲基吡咯烷酮（NMP）等非质子极性溶剂。","authors":[{"authorName":"王锦艳","id":"b1ab5710-92f2-4fc8-9837-c757a76c9746","originalAuthorName":"王锦艳"},{"authorName":"高晔","id":"270508fb-5aac-431f-af73-a6d3d940abc9","originalAuthorName":"高晔"},{"authorName":"蹇锡高","id":"9870e613-3397-41ed-8540-fdef65c16e89","originalAuthorName":"蹇锡高"}],"doi":"","fpage":"1","id":"f70c26fc-a11c-4b0f-b32a-ccee4b85b7ee","issue":"7","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"e9d142b1-51b4-432b-b9c4-e5c8feaae909","keyword":"聚芳醚砜","originalKeyword":"聚芳醚砜"},{"id":"635d58c6-1ae8-48f0-aeff-f80a8b6da4b1","keyword":"<span style=\"color:red\">1-</span>(<span style=\"color:red\">萘</span>-<span style=\"color:red\">1-</span>磺<span style=\"color:red\">酰</span><span style=\"color:red\">基</span>)<span style=\"color:red\">萘</span>","originalKeyword":"1-(萘-1-磺酰基)萘"},{"id":"e3c94f3a-69d9-4471-a421-7faca96f9a8d","keyword":"二氮杂<span style=\"color:red\">萘</span>酮","originalKeyword":"二氮杂萘酮"},{"id":"1a3b7e26-47f4-47de-a6f0-590c3588889c","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"gfzclkxygc201207001","title":"含<span style=\"color:red\">1-</span>（<span style=\"color:red\">萘</span>-<span style=\"color:red\">1-</span>磺<span style=\"color:red\">酰</span><span style=\"color:red\">基</span>）<span style=\"color:red\">萘</span>结构聚芳醚的合成及表征","volume":"28","year":"2012"},{"abstractinfo":"在微波条件下,以十二烷基硫酸钠为乳化剂,过硫酸钾为引发剂使<span style=\"color:red\">N-</span>(α-甲基-丁酯<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>微孔液聚合.研究了引发剂浓度、单体浓度、乳化剂浓度等因素对聚合速率的影响,三条曲线的斜率分别为0.55,1.3,0.5.用PERKIN-ELMER DSC7、200 Varian核磁共振仪对聚合物进行了检测.","authors":[{"authorName":"黄梅芳","id":"b9f4fae6-1eb6-4aa4-a822-81e582828699","originalAuthorName":"黄梅芳"},{"authorName":"刘朋生","id":"46f5b7c0-ddb2-467f-b128-8f5d2dc31117","originalAuthorName":"刘朋生"}],"doi":"","fpage":"100","id":"580ca5bc-4080-4eca-9d3b-c8afd1f3c884","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"5726cb9f-3b75-4548-ac45-a07de48cad25","keyword":"<span style=\"color:red\">N-</span>(α-甲基-丁酯<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-(α-甲基-丁酯基)马来酰亚胺"},{"id":"1b4d202e-c73d-4d5f-ada9-c58572ae50cd","keyword":"微乳液聚合","originalKeyword":"微乳液聚合"},{"id":"fab681a8-463f-4a01-9bba-cb1249fbddca","keyword":"微波聚合","originalKeyword":"微波聚合"},{"id":"2fafff83-cfd0-4612-8264-b2603248395a","keyword":"热性能","originalKeyword":"热性能"},{"id":"ae9926a3-cd94-457e-bc8e-5dc8122d1092","keyword":"聚合动力学","originalKeyword":"聚合动力学"}],"language":"zh","publisherId":"gfzclkxygc200404025","title":"<span style=\"color:red\">N-</span>(α-甲基-丁酯<span style=\"color:red\">基</span>)<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>微乳液微波聚合动力学","volume":"20","year":"2004"},{"abstractinfo":"以<span style=\"color:red\">马来</span>酸酐(MA)、氨基丙酸(Aln)、直链醇为原料,选择合适的溶剂、催化剂,通过三步两釜法合成了侧链含柔性酯<span style=\"color:red\">基</span>的<span style=\"color:red\">N-</span>取代<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>单体(RAM);以自由<span style=\"color:red\">基</span>溶液聚合法进行了均聚和共聚;利用IR、TG、DTA对产物(PRAM)进行了表征;并讨论了侧链长度对均聚物溶解性能、热性能的影响,结果表明柔性链长度对溶解性、起始热分解温度影响不大,但玻璃化温度(Tg)随柔性链增长而明显下降.","authors":[{"authorName":"艾娇艳","id":"4e5ccec6-38b0-4400-a9a0-b9cc401300cd","originalAuthorName":"艾娇艳"},{"authorName":"刘朋生","id":"413dbbc3-3ffa-46a1-af23-e7d920fac435","originalAuthorName":"刘朋生"}],"doi":"","fpage":"117","id":"77fd55fd-67e5-452e-9110-74122180fa2b","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"180e02ca-05e9-4827-ae2f-cff0c9059022","keyword":"<span style=\"color:red\">N-</span>取代<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-取代马来酰亚胺"},{"id":"0ca3b833-563e-4159-871c-9dd36507277b","keyword":"柔性酯<span style=\"color:red\">基</span>","originalKeyword":"柔性酯基"},{"id":"2c8861e6-d8bf-4120-a46a-5d99778dcbb7","keyword":"溶解性","originalKeyword":"溶解性"},{"id":"315725f1-3c45-4af3-9d59-a82258b6d90d","keyword":"耐热性","originalKeyword":"耐热性"}],"language":"zh","publisherId":"gfzclkxygc200405029","title":"含柔性酯<span style=\"color:red\">基</span>的<span style=\"color:red\">N-</span>取代<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的合成及溶液聚合","volume":"20","year":"2004"},{"abstractinfo":"以顺丁烯二酸酐和苯胺为原料,用甲苯作共沸溶剂,自制固体超强酸作催化剂,加入阻聚剂,合成的<span style=\"color:red\">N-</span>苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的收率97%,纯度99%以上.在此基础上进行中试试验,可获得相同收率纯度的产品.","authors":[{"authorName":"刘景民","id":"8b584a2c-5835-4209-a18c-7c963de56e0e","originalAuthorName":"刘景民"},{"authorName":"陈文","id":"8aa304c8-6ff5-4492-9312-29a9dd2846a6","originalAuthorName":"陈文"},{"authorName":"邵坤","id":"d87058c4-6e77-47ac-a511-43ac0357d477","originalAuthorName":"邵坤"},{"authorName":"马树林","id":"81c063a8-5b4e-4d2f-840c-050c5ccfc9af","originalAuthorName":"马树林"},{"authorName":"张军","id":"11c4928e-b959-4d65-8808-f4226a7cd700","originalAuthorName":"张军"}],"doi":"10.3969/j.issn.1009-9239.2006.05.008","fpage":"23","id":"a96e9607-1dcc-47ff-ae3a-51345236c119","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"7eb5e0fb-fe19-4f58-9e26-782d65cb34bf","keyword":"<span style=\"color:red\">N-</span>苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-苯基马来酰亚胺"},{"id":"15bc5b9c-8848-4fdd-b866-74878a00299f","keyword":"合成","originalKeyword":"合成"},{"id":"cc9d2d77-7814-4da1-99c1-c992644d96c2","keyword":"收率","originalKeyword":"收率"}],"language":"zh","publisherId":"jycltx200605008","title":"甲苯共沸法<span style=\"color:red\">N-</span>苯基<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>的合成","volume":"39","year":"2006"},{"abstractinfo":"以<span style=\"color:red\">N</span>,<span style=\"color:red\">N-</span>二甲基甲酰胺(DMF)为溶剂,醋酸酐为脱水剂,将传统三嗪氨基二苯乙烯荧光分子通过脱水闭环反应对<span style=\"color:red\">马来</span>酸酐改性,并与苯乙烯共聚合成了系列<span style=\"color:red\">N-</span>三嗪<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>聚合型荧光增白剂.采用UV、荧光发射光谱等研究了其在水和DMF中光物理特性和光化学顺反异构性能及取代<span style=\"color:red\">基</span>的影响.研究表明,共聚后反式活性荧光单体固定在大分子链上,可显著提高发色团的稳定性及荧光量子产率,降低光致异构现象.同时三嗪环上取代<span style=\"color:red\">基</span>的类型对光吸收和荧光分配并无显著影响,顺反式异构体的比例主要取决于取代<span style=\"color:red\">基</span>性质,溶剂的极性影响三嗪-二苯乙烯荧光物质光物理化学性质.","authors":[{"authorName":"刘静","id":"c6adab21-4500-4d5e-853f-0ea9b9b15dad","originalAuthorName":"刘静"},{"authorName":"张光华","id":"3404a184-9242-4d80-90e0-e6205b8b714e","originalAuthorName":"张光华"}],"doi":"","fpage":"12","id":"faeef18f-df5d-4eec-a37f-f16e520aa89e","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"426b85d9-f50b-4d93-addb-9ecb40212939","keyword":"荧光增白剂","originalKeyword":"荧光增白剂"},{"id":"11a1f40a-81bd-4337-8c38-0dcb5c4c4f98","keyword":"<span style=\"color:red\">N-</span>三嚷<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>","originalKeyword":"N-三嚷马来酰亚胺"},{"id":"c3536ef6-bf2a-44fe-b4d9-144d36949c55","keyword":"共聚型","originalKeyword":"共聚型"},{"id":"ae0acea7-3c49-4c4c-b9f1-a321090003a6","keyword":"光致异构化","originalKeyword":"光致异构化"}],"language":"zh","publisherId":"gfzclkxygc201009004","title":"<span style=\"color:red\">N-</span>三嗪<span style=\"color:red\">马来</span><span style=\"color:red\">酰</span><span style=\"color:red\">亚胺</span>聚合型荧光增白剂合成及性能","volume":"26","year":"2010"}],"totalpage":6831,"totalrecord":68302}