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Evaluation of interfacial strength by an instrumented indentation method and its application to an actual TBC vane

Yasuhiro YAMAZAKI

金属学报(英文版)

The thermal fatigue behaviour of an air plasma sprayed thermal barrier coating was investigated. And also the interfacial strengths of thermal barrier coated specimens subjected to thermal fatigue, as well as a retired TBC vane were also evaluated by means of an instrumented indentation machine. The results indicated that, (1) the TGO grew at the interface during thermal fatigue cycle as a function of the exposure time at elevated temperature; (2) the microcracks were initiated in the top coating and at the interface after thermal cycle tests; (3) the interfacial strength of TBC, which was evaluated by the indentation method, increased with the thermal cycles; (4) the interfacial strength of the retired TBC vane was almost equal with that of the as-sprayed TBC specimen.

关键词: Thermal barrier coating

Characterization of Detonation Sprayed Thermal Barrier Coatings

Fuhe YUAN , Zhiwei HUANG , Zhongguang WANG , Chao SUN , Shijie ZHU

材料科学技术(英)

Detonation spraying has advantages of strong bonding without heating substrates, high coating speed, low requirements for the quality of surface treatment of substrates and others. In the present research, yttria stabilized zirconia powders were used for detonation spraying thermal barrier coatings (TBCs) on a Ni-base superalloy with a bond coat of NiCrAlY. Thermal exposure tests were conducted at a constant temperature in air. After thermal exposure, microstructure observation, element distribution analysis and hardness measurement were carried out. The cracking behavior of the as-prepared and preoxidized TBCs specimens was investigated.

关键词: Detonation spraying , null , null , null

Influence of Annealing on the Grain Growth and Thermal Diffusivity of Nanostructured YSZ Thermal Barrier Coating

Na WANG , Chungen ZHOU , Shengkai GONG

材料科学技术(英)

The nanostructured zirconia coatings were deposited by atmospherically plasma spraying. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction were used to investigate the microstructure of the zirconia coatings. Thermal diffusivity values at normal temperatures have been evaluated by laser flash technique. Effect of annealing on the microstructure evolution of the zirconia coating has been performed. The grains and thermal diffusivity are increased with increasing annealing time and temperature. The grain growth is according to the GRIGC (the grain rotation induced grain coalescence) mechanism. The increase in thermal diffusivity is attributed to the grain growth and the decrease in porosity of nanostructured zirconia coatings.

关键词: Grain size , null , null , null

Influence of Water Vapor on the Isothermal Oxidation Behavior of Thermal Barrier Coatings

Chungen ZHOU , Jingsheng YU , Shengkai GONG , Huibin XU

材料科学技术(英)

The oxidation of specimens with thermal barrier coating (TBC) consisted of nickel-base superalloy, low-pressure plasma sprayed Ni-28Cr-6Al-0.4Y (wt pct) bond coating and electron beam physical vapor deposited 7.5 wt pct yttria stabilized zirconia (YSZ) top coating was studied at 1050℃ respectively in flows of O2, and mixture of O2 and 5%H2O under atmospheric pressure. The thermal barrier coating has relatively low oxidation rate at 1050℃ in pure O2. Oxidation rate of thermal barrier coating in the atmosphere of O2 and 5%H2O is increased The oxidation kinetics obeys almost linear law after long exposure time in the presence of 5% water vapor. Oxide formed along the interface between bond coat and top coat after oxidation at 1050℃ in pure O2 consisted of Al2O3, whereas interfacial scales formed after oxidation at 1050℃ in a mixture of O2 and 5%H2O were mainly composed of Ni(Al,Cr)2O4,NiO and Al2O3. It is suggested that the effect of water vapor on the oxidation of the NiCrAlY coating may be attributed to the increase in Ni and Cr ions transport in the oxides.

关键词: Oxidation , null , null

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