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蒸汽发生器的腐蚀失效分析

程芳婷

中国腐蚀与防护学报

田湾核电站蒸汽发生器在冷态和热态调试结束后发生的穿晶型应力腐蚀裂纹及点蚀,其腐蚀原因可能为运输及安装期间保养措施不当。提出对蒸汽发生器进行干保护、由设计的KOH-N2H4碱性水冲洗方案调整为NH3-N2H4碱性水、降低水中溶解氧和Cl-含量、提高溶液pH、对设备进行定期清洗、化水系统加装反渗透装置等方案,以保证蒸汽发生器的稳定运行。

关键词: 蒸汽发生器 , Stress corrosion cracking , Pit corrosion

Service Performance of Engineering Materials

Andrej Atrens

材料科学技术(英文)

Corrosion research by Atrens and co-workers has made significant contributions to the understanding of the service performance of engineering materials. This includes: (1) elucidated corrosion mechanisms of Mg alloys, stainless steels and Cu alloys, (2) developed an improved understanding of passivity in stainless steels and binary alloys such as Fe-Cr, Ni-Cr, Co-Cr, Fe-Ti, and Fe-Si, (3) developed an improved understanding of the melt spinning of Cu alloys, and (4) elucidated mechanisms of environment assisted fracture (EAF) of steels and Zr alloys. This paper summarises contributions in the following: (1) intergranular stress corrosion cracking of pipeline steels, (2) atmospheric corrosion and patination of Cu, (3) corrosion of Mg alloys, and (4) transgranular stress corrosion cracking of rock bolts.

关键词: Stress corrosion cracking , null , null

SCC Behaviour of X-70 Pipeline Steel in Near-Neutral pH Solutions

Hao GUO , Guangfu LI , Xun CAI , Jianjiang ZHOU , Wu YANG

材料科学技术(英文)

The stress corrosion cracking (SCC) behaviour of X-70 pipeline steel in near-neutral pH solutions was studied $via$ slow strain rate testing (SSRT). The results showed that the cracking mode of X-70 pipeline steel in near-neutral pH solutions was transgranular at different temperatures and applied potentials with the feature of quasi-cleavage. The pH value of the solution decreased with increasing the addition of CO¬2, which increased the susceptibility to SCC. SCC susceptibility increased as the applied potential moved towards the cathodic direction, suggesting that hydrogen induced cracking (HIC) dominated the cracking process at cathodic potentials. The slight decrease of pH values with decreasing temperature of the solution increased the susceptibility to SCC, which attributed to the change of solubility of CO¬2 in the solution at different temperatures. The propagating directions of SCC cracks were different at different potentials. At rather negative cathodic potentials, the cracks were almost perpendicular to the tensile axis, while at free corrosion potential and near anodic potentials, cracks were nearly at 45 degree, and in the range of moderate cathodic potentials both propagating directions could be observed.

关键词: Pipeline steel , null , null , null

Effect of Cyclic Loading on Cracking Behaviour of X-70 Pipeline Steel in Near-Neutral pH Solutions

Hao GUO , Guangfu LI , Xun CAI , Ruipeng YANG , Wu YANG

材料科学技术(英文)

The cracking behaviour of X-70 pipeline steel in near-neutral pH solutions was studied under different modes of cyclic loading. The crack propagation process of X-70 pipeline steel under low frequency cyclic loading condition was controlled mainly by stress corrosion cracking (SCC) mechanism. Under mixed-mode cyclic loading, both higher tensile stress and shear stress made cracks easier to propagate. Applied cathodic potentials and high content of carbon dioxide in solutions also promoted the propagation of cracks. The propagation directions of cracks were different under different cyclic loading conditions. Under mode I (pure tensile stress) cyclic loading condition, cracks were straight and perpendicular to the tensile stress axis, while under mixed-mode I/III (tensile/shear stress) cyclic loading, cracks were sinuous and did not propagate in the direction perpendicular to the main tensile stress axis. Under the mixed-mode cyclic loading, cracks were much easier to propagate, suggesting that shear stress intensified the role of tensile stress. In addition, shear stress promoted the interaction between cracks, resulting in easier coalescence of cracks.

关键词: Pipeline steel , null , null , null

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