Guangming WU
,
Jun SHEN
,
Tianhe YANG
,
Bin ZHOU
,
Jue WANG
材料科学技术（英）
Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of ammonia and water vapor. The silica films were characterized with TEM, AFM, FTIR, spectrophotometer, ellipsometer, and abrasion test, respectively. The experimental results have shown that the films have a nanostructure with a low refractive index and can form an excellent scratch-resistant broadband anti-reflectance. The two-step catalysis noticeably strengthens the films, and the mixed gas treatment further improves mechanical strength of the silica network. Finally the strengthening mechanism has been discussed.
关键词:
Sol-gel process
,
null
,
null
,
null
S.M.Attia
,
Jue WANG
,
Guangming WU
,
Jun SHEN
,
Jianhua MA
材料科学技术（英）
Sol-gel process is one of the simplest techniques to manufacture thin films. The quality of the prepared films depends on the parameters of the sol-gel process and the used technique for deposition. A great variety of the sol-gel derived films have been prepared for different applications. We present a review on the sol-gel derived coatings. The description of the process is introduced in details. Different sol-gel deposition techniques are mentioned. The optical applications of the sol-gel derived coatings are reviewed.
关键词:
Sol-gel process
,
null
,
null
Jingxiao LIU
,
Fei SHI
,
Dazhi YANG
材料科学技术（英）
In order to improve the corrosion resistance and biocompatibility of NiTi surgical alloy, TiO2 and TiO2-SiO2 thin films were prepared by sol-gel method. The surface characteristics of the film, which include surface composition, microstructure and surface morphology, were studied by X-ray diffraction (XRD), atomic force microscopy (AFM) and X-ray photoelectron spectra (XPS), respectively. A scratching test was used to assess the interface adhesive strength between the film and substrate. The corrosion resistances of NiTi alloy coated with oxide films were studied by anodic polarization curves measurement in biological solution. Additionally, a preliminary study of the in vitro bioactivity of the films was conducted. The results indicated that TiO2 and TiO2-SiO2 (Ti/Si=4:1) films have higher electrochemical corrosion resistance and can be used as protective layers on NiTi alloy. In addition, TiO2-SiO2 composite films have better bioactivity than TiO2 film.
关键词:
TiO2
,
null
,
null
,
null
,
null
A.Sadeghzadeh Attar
,
Sh.Mirdamadi
,
F.Hajiesmaeilbaigi
,
M.Sasani Ghamsari
材料科学技术（英）
In this work, TiO2 nanorods with uniform diameter of about 100 nm and a length of several micrometers were successfully prepared by the sol-gel template method. Also the influence of molar ratios of precursor on the morphology and structure of TiO2 nanorods has been investigated. The prepared samples were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results indicated that the TiO2 nanorods were crystallized in the anatase and rutile phases, after annealing to 400–700℃ up to 2
关键词:
TiO2 nanorods
,
null
,
null
胡久彪
,
余长林
,
毕亚东
,
魏龙福
,
陈建钗
,
陈喜蓉
催化学报
doi:10.1016/S1872-2067(12)60723-2
以硝酸亚铈(Ce(NO3)3·6H2O)和正硅酸四乙酯(C8H20O4Si)为前驱体,采用溶胶-凝胶法合成了系列具有大比表面积的xCeO2-(1-x)SiO2 (x=0,0.25,0.50,0.75,1)复合氧化物载体,然后浸渍活性组分Ni制得用于甲烷部分氧化制合成气的Ni催化剂.运用N2物理吸附-脱附、X射线粉末衍射、扫描电镜、紫外-可见漫反射光谱、氢程序升温还原、氨程序升温脱附和热重等手段对所得催化剂的组织结构、还原性、表面酸性和积炭行为等进行了表征;同时考察了催化剂的组成、焙烧温度和反应时间等对催化剂在甲烷部分氧化制合成气中催化性能的影响.表征结果表明,该系列Ni/CeO2-SiO2催化剂具有大比表面积,CeO2晶粒较小,NiO的分散性好且易被还原,表面酸性弱,不容易积炭.当Ce/Si摩尔比为1∶1,活性组分Ni的质量分数为10％,焙烧温度为700℃时,所制备的Ni/CeO2-SiO2催化剂表现出较好的稳定性、最高的CH4转化率(～84％)和对产物CO及H2的选择性(＞87％).
关键词:
溶胶-凝胶法
,
铈-硅复合氧化物
,
负载型镍催化剂
,
甲烷部分氧化
,
合成气
龙东辉
,
张洁
,
杨俊和
,
胡子君
,
李同起
,
成果
,
张睿
,
凌立成
新型炭材料
以苯酚、间甲酚和糠醛为原料,在正丙醇溶剂中以盐酸为催化剂经溶胶-凝胶过程合成了醇凝胶,直接超临界正丙醇干燥得到有机气凝胶,在氮气保护下裂解制备出富含中孔的炭气凝胶.用IR、N2吸附、SEM、TEM等表征气凝胶的结构特征,考察了问甲酚苯酚摩尔比对凝胶结构的影响.结果发现:提高间甲酚的含量能够增强聚合物的交联密度,减小聚合物与溶剂的相溶性,缩短相分离时间,有利于得到较小的纳米颗粒和孔径的炭气凝胶.所制得的炭气凝胶平均中孔孔径随间甲酚含量的增加从47 nm逐渐减小至13 nm,BET比表面积和中孔孔容在m-C/P=0.33时达到最大值.
关键词:
炭气凝胶
,
溶胶-凝胶法
,
超临界干燥
,
密度
,
孔隙
