Pengfei Zhang Litong Zhang Xiaowei Yin
材料科学技术（英文）
To improve the corrosion resistance of porous Si3N4 used in the high temperature environments, which contain water vapor and volatile species, porous Si3N4-Lu2Si2O7 composite ceramics were fabricated by a process of oxidation bonding and pressureless sintering in flowing N2 atmosphere at the temperatures lower than 1550°C. The pores in ceramics were formed by removing the pore-forming agent (phenolic resin). SiO2 derived by the oxidation of Si3N4 at 1250°C in air reacted with Lu2O3 at various sintering temperatures, leading to the formation of Lu2Si2O7 with excellent oxidation and corrosion resistance. The phase composition, microstructure, and mechanical properties of the porous ceramics depended on the sintering temperatures. Si3N4-Lu2Si2O7 composite ceramics with the porosity of 52% and the pore size of 0.2μm were obtained by oxidation bonding at 1250°C for 1 h and pressureless sintering at 1550°C for 2 h using 4 wt pct Lu2O3 additive.
关键词:
Porous ceramics
,
氮化硅
,
焦硅酸镥
,
无压烧结
余娟丽
,
陈磊
,
吕毅
,
赵英民
,
裴雨辰
宇航材料工艺
综述了天线罩用宽频透波材料的发展现状,分析了影响透波材料性能的因素,系统讨论了宽频透波天线罩的制备方法.研究指出介电性能是评价材料透波性能的一个重要标准,选用低介电材料和提高材料孔隙率可实现材料宽频透波,新的介质材料的开发和研究将是今后天线罩制造技术发展的一个主要发展方向.
关键词:
宽频透波
,
陶瓷材料
,
天线罩
,
多孔陶瓷
胡良发
,
汪长安
,
孙陈诚
,
鲁胜
,
胡子君
宇航材料工艺
doi:10.3969/j.issn.1007-2330.2010.02.015
以叔丁醇为溶剂,采用凝胶注模成型方法,制备出防/隔热的摩尔分数为8%Y_2O_3-ZrO_2(8YSZ)多孔陶瓷.在浆料中初始固相含量固定为10%体积分数的基础上,研究了烧结温度对8ySZ陶瓷材料的气孔率、开气孔率、孔径尺寸分布及显微结构的影响,分析了压缩强度、热导率与结构之间的关系.通过改变烧结温度,所制备的8YSZ多孔陶瓷的气孔率为65%～74%,孔隙分布均匀,平均孔径为0.68～1.82μm,压缩强度为7.92～13.15 MPa,室温热导率[最低可达0.053 W/(m·K)],比相应的致密陶瓷[～2.2 W/(m·K)]低一个数量级,且随着气孔率的增加而降低.
关键词:
凝胶注模成型
,
ZrO_2
,
多孔陶瓷
,
气孔率
,
压缩强度
,
热导率
