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Research on a New Process of Preparation for Nano-SiO2 with High Activity and Mesopores

Ruijing ZHANG , Ke YANG , Tianying XIONG

材料科学技术(英文)

Nano-SiO2 with high activity and mesopores was prepared through sol-gel synthesis followed by low-temperature heat treatment and ball milling firstly in our experiments. TEM was performed to measure particle sizes. Nitrogen adsorption experiments were carried out to estimate specific surface area, p...

关键词: Heat treatment , null , null , null

增强LPG催化裂化催化剂ZSM-5稳定性的新方法:脱铝和负载硅

Leyla Vafi , Ramin Karimzadeh

催化学报 doi:10.1016/S1872-2067(15)61062-2

以碳纳米管为模板合成的带有介孔和微孔的ZSM-5分子筛具有不同的复合结构。用三氯乙酸(TCA)可选择性地将中孔的铝脱除。基于TCA分子大小,它可能只扩散到中孔中,因而使得微孔部分不脱铝。从分子筛结构中脱除铝原子导致催化剂中出现中空的空间。若将硅原子填充到空位中,那么介孔部分的结构会变得与硅酸盐类似,...

关键词: 介孔 , 碳纳米管 , ZSM-5分子筛 , 脱铝 , 三氯乙酸

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