Ying Zhang Jun Lin Dijiang Wen
材料科学技术（英文）
Ferrite compound Co0:6Zn0:4NixFe2-xO4 was synthesized by solid state reaction. The structure and performance of Co0:6Zn0:4NixFe2-xO4 compounds were studied by MÄossbauer spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared radiant tester. MÄossbauer spectroscopy and XPS analysis show the valence states and distribution of cations in Co0:6Zn0:4NixFe2-xO4. Zn2+ has invariably shown preference for the tetrahedral sites, and Ni2+ has the preference for the octahedral sites. The occupancy of Fe3+ linearly increases on the tetrahedral sites, and sharply decreases on the octahedral sites with increasing x, owing to its gradual replacement by Ni2+ on the octahedral sites. It indicates that due to the occupation of octahedral sites by the majority of Ni2+, Fe3+ decreasingly migrated from the octahedral sites to the tetrahedral sites and substituted Co3+ sites, which made the number of Co3+ in the tetrahedral sites decreasing. According to the measurement results of XRD and the infrared radiant tester analysis, the lattice parameter and infrared radiance have shown a nonlinear variation, exhibiting the infrared average radiance of 0.92 in the 8-14 μm waveband, and the results demonstrate that these Co-Zn-Ni spinel ferrites have potential for application in a wide range of infrared heating and drying materials.
关键词:
Infrared radiance
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