{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>因其超高的储氢量和较好的动力学性能,成为了最具潜力的储氢材料之一.从合成方法、放氢特性、晶体结构和反应机制等方面,综述了<span style=\"color:red\">金属</span><span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>及其衍生物的研究进展.","authors":[{"authorName":"王杨","id":"502b7269-474e-4f91-b08e-b6da82cbf499","originalAuthorName":"王杨"},{"authorName":"王强","id":"ce11cd7c-b7c5-4c5a-9fa1-10046e3e15dd","originalAuthorName":"王强"}],"doi":"10.11896/j.issn.1005-023X.2015.019.012","fpage":"67","id":"96ee19d4-4440-4046-9b88-9dd85a544508","issue":"19","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"48e784f1-c298-4793-8b2b-68bae9bf6930","keyword":"<span style=\"color:red\">金属</span><span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>","originalKeyword":"金属氨硼烷"},{"id":"16bda501-c82e-4da3-b30d-75a639776b00","keyword":"衍生物","originalKeyword":"衍生物"},{"id":"e2e306a8-c1ac-4fbc-99f7-df749d452359","keyword":"储氢材料","originalKeyword":"储氢材料"},{"id":"3598bcd1-e9ab-4594-91c9-f277d6c4c281","keyword":"合成方法","originalKeyword":"合成方法"},{"id":"0941d5ea-1b51-4897-bd18-bbc7f2c4c991","keyword":"晶体结构","originalKeyword":"晶体结构"}],"language":"zh","publisherId":"cldb201519012","title":"<span style=\"color:red\">金属</span><span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>及其衍生物高容量储氢材料研究进展","volume":"29","year":"2015"},{"abstractinfo":"采用第一性原理平面波赝势方法研究了两种<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>结构(Pmn21及P42cm)的晶格参数、电子结构以及动力学性质。结果表明, Pmn21结构的能量低于P42cm结构, 与实验观测结果相符, 即低温相为Pmn21结构而室温相为P42cm结构。Pmn21到P42cm相变所引起的结构变化主要体现为<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>分子间双氢键键长显著增加, 而分子内部化学键键长变化不大。根据电子态密度分析了<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>的成键状态。<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>室温相的XRD图谱和FTIR图谱的理论预测结果与实验结果符合得较好。","authors":[{"authorName":"刘超仁胡青苗王平","id":"a88711f4-586e-4bc1-b8c6-90537939384d","originalAuthorName":"刘超仁胡青苗王平"}],"categoryName":"|","doi":"","fpage":"13","id":"85df2e91-bbda-4cc7-8a11-7eef3ec603d7","issue":"1","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"3cdda44f-08b3-41c6-8919-59ff500ec335","keyword":"材料科学基础学科 ","originalKeyword":"材料科学基础学科 "},{"id":"e85a8feb-fa19-4c81-8ece-ce5d9d7129b9","keyword":"&nbsp; ammonia borane ","originalKeyword":"&nbsp; ammonia borane "},{"id":"f2bf17ce-4677-4fc5-882b-0aab2b306242","keyword":" &nbsp;first&ndash;principles calculation ","originalKeyword":" &nbsp;first&ndash;principles calculation "},{"id":"64239d54-310d-475c-8d29-c8844a748c3f","keyword":" crystal structure, hydrogen storage material","originalKeyword":" crystal structure, hydrogen storage material"},{"id":"222bbcad-db73-44c3-8a34-3b2faee60e5f","keyword":"null","originalKeyword":"null"}],"language":"zh","publisherId":"1005-3093_2011_1_7","title":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>低温和室温结构的第一性原理计算","volume":"25","year":"2011"},{"abstractinfo":"采用第-性原理平面波赝暖势方法研究了两种<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>结构(Pmn21及P42cm)的晶格参数、电子结构以及动力学性质.结果表明,Pmn21结构的能量低于P42cm结构,与实验观测结果相符,即低温相为Pmn21结构而室温相为P42cm结构.Pmn21到P42cm相变所引起的结构变化主要体现为<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>分子间双氢键键长显著增加,而分子内部化学键键长变化不大.根据电子态密度分析了<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>的成键状态.<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>室温相的XRD图谱和FTIR图谱的理论预测结果与实验结果符合得较好.","authors":[{"authorName":"刘超仁","id":"b23935eb-de7a-4eef-b9a7-e74ae79ff26f","originalAuthorName":"刘超仁"},{"authorName":"胡青苗","id":"1e401ea8-109e-49ef-8c23-c4bb5d916167","originalAuthorName":"胡青苗"},{"authorName":"王平","id":"912a79b8-d059-45ed-a6ce-38214e0f621a","originalAuthorName":"王平"}],"doi":"","fpage":"13","id":"f2327c41-d7f2-4a4f-b25f-7208d0f87f92","issue":"1","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"e4d7a158-2c3f-4993-a0ca-9ae589154d88","keyword":"材料科学基础学科","originalKeyword":"材料科学基础学科"},{"id":"4a5780e6-9ccd-4a6c-bd4a-69ba151a68a1","keyword":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>","originalKeyword":"氨硼烷"},{"id":"a29dff9f-bc1d-4dba-9dd9-d5e8e5534275","keyword":"第一性原理","originalKeyword":"第一性原理"},{"id":"95b1bf42-447d-4b98-ba60-05c5c385085f","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"e118ad22-43f3-4c66-955d-bf29d55b2e80","keyword":"储氢材料","originalKeyword":"储氢材料"}],"language":"zh","publisherId":"clyjxb201101003","title":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>低温和室温结构的第一性原理计算","volume":"25","year":"2011"},{"abstractinfo":"利用石墨型氮化碳(C3N4)和<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>(NH3BH3,AB)球磨制备了AB-C3N4体系,发现C3N4的加入使AB放氢反应温度明显降低,但是副产物氨气浓度有所升高.因此,利用LiBH4改性的C3N4 (LC3N4)同AB球磨合成出了AB-LC3N4体系,并采用X射线衍射、程序升温脱附-质谱联用、热重-差热分析及核磁共振等技术考察了该体系的脱氢性能.结果表明,由于LC3N4的加入,AB的放氢反应温度明显降低,放氢反应速率加快,放氢诱导期缩短,同时抑制了副产物无机苯的生成.另外,C3N4的化学修饰也降低了AB-LC3N4放氢过程中生成氨气的浓度.动力学分析和核磁共振结果表明,AB-LC3N4分解过程依然遵循NH3BH2NH3BH4诱导的<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>自分解机理.","authors":[{"authorName":"张静","id":"5a6583ad-518c-4160-84c6-c725107b24a9","originalAuthorName":"张静"},{"authorName":"何腾","id":"470fd9f9-8807-467c-a867-23b12083bf17","originalAuthorName":"何腾"},{"authorName":"刘彬","id":"8705e1d3-fb60-4722-963c-17a70033eeae","originalAuthorName":"刘彬"},{"authorName":"柳林","id":"37e88a0b-4ee7-4d75-9416-b987c14fb0d4","originalAuthorName":"柳林"},{"authorName":"赵泽伦","id":"3f54f748-e931-4919-8ab4-cc8785ebe307","originalAuthorName":"赵泽伦"},{"authorName":"胡大强","id":"faa75ec9-45d8-4654-81bd-0a52e697466c","originalAuthorName":"胡大强"},{"authorName":"鞠晓花","id":"03b555b5-2023-4b72-920e-31aee51817dc","originalAuthorName":"鞠晓花"},{"authorName":"吴国涛","id":"2def2cd2-8c2f-4c23-ba16-f9de0077bded","originalAuthorName":"吴国涛"},{"authorName":"陈萍","id":"b783e9b7-5054-46c1-b554-b5eccd335d2d","originalAuthorName":"陈萍"}],"doi":"10.1016/S1872-2067(12)60566-X","fpage":"1303","id":"c567f296-fbe9-42d2-bd2f-30141f9abf5f","issue":"7","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"f4deac5a-baf4-48f7-972c-a2f3884e0e63","keyword":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>","originalKeyword":"氨硼烷"},{"id":"c95c7f33-83d7-4f67-b561-268dc6cd4ff5","keyword":"氮化碳","originalKeyword":"氮化碳"},{"id":"8ef382fb-e9c5-4a26-b640-8d34c9f0f086","keyword":"脱氢","originalKeyword":"脱氢"},{"id":"02b0be73-727e-4099-9139-e5373722a4d0","keyword":"硼氢化锂","originalKeyword":"硼氢化锂"}],"language":"zh","publisherId":"cuihuaxb201307004","title":"石墨型氮化碳对<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>放氢性能的影响","volume":"34","year":"2013"},{"abstractinfo":"首次通过化学还原法制备了纳米多孔Co-Ni-B/Cu-BTC复合材料,在 Co-Ni-B合金中掺入<span style=\"color:red\">金属</span>框架化合物Cu-BTC后有效地提高了复合材料的比表面积,其形貌由团聚的纳米粒子变成纳米多孔结构,复合材料的催化性能也得到显著的提高,用于催化氨<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>的水解,表现出良好的催化活性.在30℃时,催化水解<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>制氢的反应速率到达2670 mL/(min.g),其水解反应的活化能为22．4 kJ/mol,与文献相比,表现出较大的优势.所制备的复合材料还具有良好的化学稳定性,表现出重要的应用前景.","authors":[{"authorName":"程军","id":"f4766b84-eccd-4465-8d1a-fc1785c97a24","originalAuthorName":"程军"},{"authorName":"邹勇进","id":"f1699966-da20-4935-ae23-b59685828806","originalAuthorName":"邹勇进"},{"authorName":"向翠丽","id":"826fc449-5d13-48d2-bc58-8ada82e8e49f","originalAuthorName":"向翠丽"},{"authorName":"郑良军","id":"96c776eb-dd49-49ec-8510-6c59e9e7bb20","originalAuthorName":"郑良军"},{"authorName":"孙立贤","id":"e7e73626-d7a7-4ca7-a046-ab9015726d6a","originalAuthorName":"孙立贤"},{"authorName":"徐芬","id":"f2aba9d0-ea1f-4885-a0e6-1c0806829035","originalAuthorName":"徐芬"},{"authorName":"刘淑生","id":"369a5d4c-0035-4342-9c38-ef566dad0d29","originalAuthorName":"刘淑生"}],"doi":"10.3969/j.issn.1001-9731.2016.06.027","fpage":"6152","id":"12cd7aa6-993b-40bd-9a52-f75f596b680f","issue":"6","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"18170f6a-3e44-4791-a733-26b6842fca0a","keyword":"Co-Ni-B/Cu-BTC","originalKeyword":"Co-Ni-B/Cu-BTC"},{"id":"417e0870-89f9-4bef-938e-046ce8ba3c5d","keyword":"催化水解","originalKeyword":"催化水解"},{"id":"5a556dee-e8ac-4405-afad-8208c490cfb4","keyword":"复合材料","originalKeyword":"复合材料"},{"id":"7bc36042-6c03-400e-9ede-d190ebf421bb","keyword":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>","originalKeyword":"氨硼烷"}],"language":"zh","publisherId":"gncl201606027","title":"纳米多孔Co-Ni-B/Cu-BTC复合材料的制备及其催化水解<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>的研究?","volume":"47","year":"2016"},{"abstractinfo":"本文介绍了含<span style=\"color:red\">氨</span>丙基聚硅氧<span style=\"color:red\">烷</span>的有效合成途径,制备了数种不同分子量、不同<span style=\"color:red\">氨</span>丙基含量的含<span style=\"color:red\">氨</span>丙基聚硅氧<span style=\"color:red\">烷</span>.通过扭辫分析法测定了系列含<span style=\"color:red\">氨</span>丙基聚硅氧<span style=\"color:red\">烷</span>在不同温度下的内耗及相对刚度,对其进行了动态力学性能分析.","authors":[{"authorName":"吴拥中","id":"10732771-559e-4549-b968-181998aadade","originalAuthorName":"吴拥中"},{"authorName":"庄宝群","id":"7b1188a3-27e5-4999-9f07-002a26175a03","originalAuthorName":"庄宝群"},{"authorName":"冯圣玉","id":"319f284a-e939-49f5-914e-88e10b468ff3","originalAuthorName":"冯圣玉"}],"doi":"10.3969/j.issn.1673-2812.2000.z1.033","fpage":"143","id":"86efe381-8e2a-4d67-bc54-9ea73df3b2c4","issue":"z1","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"eac31a6f-df81-4d9c-8a79-bb4a2cb0e952","keyword":"<span style=\"color:red\">氨</span>丙基","originalKeyword":"氨丙基"},{"id":"54df57a3-1552-4a11-bf31-926c7aa3686c","keyword":"聚硅氧<span style=\"color:red\">烷</span>","originalKeyword":"聚硅氧烷"},{"id":"76032c18-1c2a-48d0-90ed-f2d9cae7dfd5","keyword":"扭辫分析法","originalKeyword":"扭辫分析法"}],"language":"zh","publisherId":"clkxygc2000z1033","title":"含<span style=\"color:red\">氨</span>丙基聚硅氧<span style=\"color:red\">烷</span>的动态力学性能研究","volume":"18","year":"2000"},{"abstractinfo":"碳<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>是一类优异的耐高温原料,POSS是一类性能优异的耐原子氧化合物.本文利用硅氢加成的方法,将两者有机结合,合成了体型交联型和线型两种碳<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>/POSS复合材料,并对它们的耐温性能进行了热重分析.这类材料具有优异的耐高温性能,其中体型交联型碳<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>/POSS复合物在1 200℃空气氛围下不失重,到1 400℃有约5％的增重.线性碳<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>/POSS复合材料在1 000℃空气氛围下失重约为10％.该类材料有望应用于高速飞行器的涂层.","authors":[{"authorName":"张秋红","id":"9b270ad9-1de8-4108-8e63-768c22ed4246","originalAuthorName":"张秋红"},{"authorName":"黄新","id":"904dd74b-bd50-4987-96d1-41f9d265aa10","originalAuthorName":"黄新"},{"authorName":"袭锴","id":"78901075-110e-4c22-8d2f-cc0664a1b124","originalAuthorName":"袭锴"},{"authorName":"贾叙东","id":"c7531572-0259-4a0b-b4de-ab4259618a92","originalAuthorName":"贾叙东"},{"authorName":"顾兆旃","id":"0ca266ef-7f70-4800-890c-5304a63eb91b","originalAuthorName":"顾兆旃"}],"doi":"","fpage":"59","id":"bd5312cb-26a7-4859-a003-4c4972ff9724","issue":"1","journal":{"abbrevTitle":"YHCLGY","coverImgSrc":"journal/img/cover/YHCLGY.jpg","id":"77","issnPpub":"1007-2330","publisherId":"YHCLGY","title":"宇航材料工艺   "},"keywords":[{"id":"14e68c70-0584-4b4d-8105-37916042d642","keyword":"碳<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>","originalKeyword":"碳硼烷"},{"id":"71f4838f-9826-4675-b068-7f6d392c2191","keyword":"POSS","originalKeyword":"POSS"},{"id":"33fcbc7c-a7cb-4106-9069-4ec522b11ee0","keyword":"耐高温","originalKeyword":"耐高温"}],"language":"zh","publisherId":"yhclgy201301013","title":"碳<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>/POSS的制备及性能","volume":"43","year":"2013"},{"abstractinfo":"建立了一种旋光度法测定左旋N-乙基-<span style=\"color:red\">氨</span>甲基吡咯<span style=\"color:red\">烷</span>的方法,在(20±0.5)℃温度下,以无水乙醇为溶剂,用10 cm的旋光管测定左旋N-乙基-<span style=\"color:red\">氨</span>甲基吡咯<span style=\"color:red\">烷</span>在589.3 nm波长下的旋光度.左旋N-乙基-<span style=\"color:red\">氨</span>甲基吡咯<span style=\"color:red\">烷</span>质量浓度在0.02～0.05 g/mL范围内旋光度与浓度呈现良好的线性关系,回归方程为:a=-0.936 9c-0.031 1(r=1.000),平均回收率为99.84%,RSD=0.23%(n=4).方法具有准确、简便、快速、稳定、可靠的特点.可用于左旋N-乙基-<span style=\"color:red\">氨</span>甲基吡咯<span style=\"color:red\">烷</span>的含量测定.","authors":[{"authorName":"欧阳晓辉","id":"e00250f9-98ae-448c-bf85-8e1dafdf09a4","originalAuthorName":"欧阳晓辉"},{"authorName":"赵敏蔚","id":"1cae8d6b-363b-460f-ad29-46799cf7b20e","originalAuthorName":"赵敏蔚"}],"doi":"10.3969/j.issn.1000-0518.2008.12.025","fpage":"1490","id":"9e10e834-9aca-4724-897c-316c2675e57f","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"130fae56-3cd9-44a3-a5c9-2e2d1c237fa4","keyword":"旋光法","originalKeyword":"旋光法"},{"id":"be87d185-89a0-4ebc-ab9a-909110c672cf","keyword":"左旋N-乙基-<span style=\"color:red\">氨</span>甲基吡咯<span style=\"color:red\">烷</span>","originalKeyword":"左旋N-乙基-氨甲基吡咯烷"},{"id":"2751c1f8-8d2f-4960-9884-4d4fcda20f92","keyword":"含量测定","originalKeyword":"含量测定"}],"language":"zh","publisherId":"yyhx200812025","title":"旋光法测定左旋N-乙基-<span style=\"color:red\">氨</span>甲基吡咯<span style=\"color:red\">烷</span>的含量","volume":"25","year":"2008"},{"abstractinfo":"以NaBH4为还原剂合成了具有核壳结构的Cu@Co纳米颗粒,研究了其催化氨<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>水解放氢性能.结果表明,Cu和Co的比例不同,Cu@Co纳米颗粒的催化活性也不同,其中Cu0.2@Co0.8的催化活性最高,室温下最大放氢速率达1364mLmin-1 g-1,活化能为59.1 kJ mol-1.Cu0.2@Co0.8催化氨<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>水解反应对催化剂浓度是一级反应,对<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>浓度为零级反应.Cu@Co核壳结构在催化反应中比CuCo合金能够提供更多的反应活性位点,而且单质铜和钴之间存在的协同作用和电子效应在提高催化性能方面起着关键作用.","authors":[{"authorName":"王海霞","id":"983b0e0a-716e-489d-ab15-f1845b909f8f","originalAuthorName":"王海霞"},{"authorName":"周丽敏","id":"a6752ad5-1e59-48d5-93ec-5e5d43336abc","originalAuthorName":"周丽敏"},{"authorName":"陶占良","id":"3e498235-5413-4caf-a748-93202079409f","originalAuthorName":"陶占良"},{"authorName":"陈军","id":"32da011e-7bd4-4e65-a178-25e7a53edd3a","originalAuthorName":"陈军"}],"doi":"","fpage":"7","id":"5545b2fa-499c-41c9-acbc-3af121ea5e60","issue":"4","journal":{"abbrevTitle":"GNCLYQJXB","coverImgSrc":"journal/img/cover/GNCLYQJXB.jpg","id":"34","issnPpub":"1007-4252","publisherId":"GNCLYQJXB","title":"功能材料与器件学报   "},"keywords":[{"id":"dbeacb8e-600c-45bf-915e-ff22f215a24f","keyword":"核壳结构","originalKeyword":"核壳结构"},{"id":"c276a2db-13c4-4efc-9ea1-a615d0b5c971","keyword":"Cu@Co纳米颗粒","originalKeyword":"Cu@Co纳米颗粒"},{"id":"d53a4e49-7618-4f24-8fb4-c7e3868edc28","keyword":"<span style=\"color:red\">氨</span><span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>","originalKeyword":"氨硼烷"},{"id":"0e4a611e-bca0-47ab-aba7-3dc597bc3f15","keyword":"水解","originalKeyword":"水解"}],"language":"zh","publisherId":"gnclyqjxb201504002","title":"Cu@Co纳米颗粒合成及催化氨<span style=\"color:red\">硼</span><span style=\"color:red\">烷</span>水解放氢性能","volume":"21","year":"2015"},{"abstractinfo":"研究了一种新型氮化<span style=\"color:red\">硼</span>先驱体——聚<span style=\"color:red\">烷</span>胺基环<span style=\"color:red\">硼</span>氮<span style=\"color:red\">烷</span>（PPAB）在空气中的水解过程,利用FT-IR、TGA、XRD和EDX考察了水解对PPAB及其在氩气中裂解产物结构和组成的影响。结果表明PPAB在空气中极易水解,其分子结构中的B—N键易水解形成B—O键,水解程度随放置时间及温度的增加而加快。水解前后的PPAB在1000℃时的陶瓷产率分别为45.9%和56.4%。水解后的先驱体在Ar中的裂解产物中含有较多B2O3,而未水解的PPAB裂解产物中B、N原子比接近化学计量比,不含B2O3。","authors":[{"authorName":"雷永鹏","id":"393617ba-2295-458e-aa1c-df0d3b4c917d","originalAuthorName":"雷永鹏"},{"authorName":"王应德","id":"5bb966fb-9ffd-4a80-a93f-46d0a64f95c6","originalAuthorName":"王应德"},{"authorName":"薛金根","id":"5fc687fb-7703-498a-b03c-2880ceb366d0","originalAuthorName":"薛金根"},{"authorName":"宋永才","id":"5f697be6-1f39-4b89-a868-0f1402083d5b","originalAuthorName":"宋永才"}],"doi":"","fpage":"1482","id":"1fd97de5-fe11-4167-951b-67ab8c4909fa","issue":"8","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"4a761ca6-9251-4c38-986a-8f365525938e","keyword":"氮化<span style=\"color:red\">硼</span>","originalKeyword":"氮化硼"},{"id":"af4f1b72-c1fb-4a9a-9807-b62c71a2aabb","keyword":"先驱体转化法","originalKeyword":"先驱体转化法"},{"id":"7cc3c1c0-14d0-43a9-b7a1-aaf20658e113","keyword":"聚<span style=\"color:red\">硼</span>氮<span style=\"color:red\">烷</span>","originalKeyword":"聚硼氮烷"},{"id":"0d6d6f06-93e0-4d07-a18f-bf7552291f8d","keyword":"水解","originalKeyword":"水解"}],"language":"zh","publisherId":"gncl201108036","title":"水解对聚<span style=\"color:red\">烷</span>胺基环<span style=\"color:red\">硼</span>氮<span style=\"color:red\">烷</span>及其热解产物的影响","volume":"42","year":"2011"}],"totalpage":2539,"totalrecord":25383}