Yan NIU
,
F.Gesmundo
材料科学技术（英文）
The phase diagrams of ternary systems involving two metal components and one oxidant are considered first, the limitations to their use is discussed in relation to the high temperature oxidation of binary alloys. Kinetic diagrams, which are useful to predict the conditions for the stability of the two mutually insoluble oxides as the external scale, are then calculated on the basis of thermodynamic and kinetic data concerning both the alloys and the oxides, assuming the validity of the parabolic rate law. A combination of the two types of diagrams provides a more detail information about the oxidation behavior of binary alloys. The calculation of the diffusion paths, which relate the oxidant pressure to the composition of the system in terms of the alloy components both in the alloy and in the scale during an initial stage of the reaction in the presence of the parabolic rate law, is finally developed.
关键词:
Binary alloys
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Xingqiu CHEN
,
Hailan LI
,
Xueyong DING
,
P.Rogl
,
R.Podloucky
材料科学技术（英文）
A new method of revising activity values has been derived based on the so called correction factor function for binary alloys with a large difference between two components. The correction factor is a function of physical properties formed by the difference of two components. Its absolute value increases with the enhancement of the difference in the character of components. It can be either positive or negative and the rules for selecting the sign of correction factor have been analyzed. Results are in good agreement with the experimental values.
关键词:
Correction factor function
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