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Hardness-Lattice Parameter Correlation for Aged Al-Zn-Mg Alloys

P. Fernandez G. Gonzalez I. Alfonso I.A. Figueroa

材料科学技术(英文)

Two ternary Al-2.2Zn-0.95Mg and Al-5.5Zn-2.1Mg (in wt pct) alloys, with Zn:Mg ratios close to 2.5 were produced by conventional ingot casting metallurgy. The ingots were solution heat treated at 500°C for 0.5 h and aged at 180°C for times between 0.5 and 80 h. The structural characterization was carried out by X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED) and Vickers microhardness measurements (HV). The study was focused on the investigation of the precipitates formation and the relationship between hardness and lattice parameter for α-Al. The results showed that there was an inverse correlation for all the experimental conditions, and the aged peaks coincided with lattice parameter minima. Significant precipitates formation only occurred for the alloy containing 5.5 wt pct Zn and 2.1 wt pct Mg, provoking an important strengthening and variations in the lattice parameter, however, this was not observed for the alloy containing 2.2 wt pct Zn and 0.95 wt pct Mg. A plausible explanation of the increment of hardness values could be the presence of a well distributed μ phase (MgZn2). At initial stages of the precipitation process, μ' was the most abundant precipitate while the phase τ was observed at overaged conditions. These results showed that the aging response of the conventionally cast Al-Zn-Mg alloys could be obtained using the lattice parameter of the α-Al matrix, even for alloy systems with low precipitates formation.

关键词: Aluminum alloy , X-ray diffraction , Precipitation , Lattice parameter , Hardness

铝合金稀土硝酸盐磷化的电化学行为

张圣麟李朝阳陈华辉荆树科陈燕燕

中国腐蚀与防护学报

采用电化学测试和扫描电镜等方法研究了硝酸铈对6061 铝合金磷化过程及磷化膜形貌的影响。结果表明,硝酸铈的加入改变了铝合金基体与磷化液之间液固界面间的初始电位;硝酸铈吸附在铝合金表面上形成凝胶,成为磷酸盐晶体形成的良好晶核,磷化晶粒细化,生成较为致密的磷化膜,膜的耐蚀性得到提高。硝酸铈使铝合金达到最高电位的时间缩短,阴极极化电流密度增大,磷化速度加快。硝酸铈在整个铝合金磷化过程中起到了成核和促进的作用。在本实验条件下,最佳硝酸盐含量为20 mg/L~40 mg/L。

关键词: 稀土硝酸盐(REN) , Phosphate coating , Aluminum alloy , Nucleation agent

铝合金高压铸造过程铸件与铸型间的界面热交换系数的研究

郭志鹏 , 熊守美 , 曹尚铉 , 崔正吉

金属学报

通过采集高压铸造过程中铸型内部温度的变化曲线,采用热传导反算法, 求解了以铝合金ADC12Z为铸件材料的铸件-铸型界面换热系数并且分析了该界面换热系数随着铸件厚度的变化而呈现出的变化规律。计算以及分析结果表明:压铸过程中铸件-铸型以及空气-铸型间的界面换热系数随着压铸循环中不同阶段的进行表现出不同的变化规律。铸件的厚度对于铸件-铸型界面换热系数有着很大的影响,不仅表现在厚度的增大提高了换热系数的数值而且厚度的增大对于换热系数的变化趋势也存在的很大的影响。同时,不同厚度的铸件,其固相率和冷却速度的变化规律也存在着较大的区别。

关键词: 高压铸造 , Aluminum alloy , ADC12Z , Interfacial heat transfer coefficient

Effect of Microstructure on Thermal Expansion Coefficient of 7A09 Aluminum Alloy

Hongzhi Ji

材料科学技术(英文)

The relationship between microstructure evolution and coefficient of thermal expansion (CTE) of 7A09 aluinum alloy was investigated in this paper. Differential scanning calorimetry (DSC) was combined with transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) to investigate microstructure evolution taking place in 7A09 aluminum alloy during heating and cooling process. The corresponding CTE curves of the 7A09 alloy were recorded by thermal dilatometer. Results indicated that GPII zones and η' phase were main precipitates in the highest strength tempered (T6) 7A09 alloy. The η phase was the main participate in 7A09 alloy during the cooling process. The nonlinear dependency existed between CTE and temperature in both changing temperature processes. During the heating process, obvious additional contraction of alloy volume was directly caused by phase transition, such as dissolution of ´0 phase, transition from η' to η phase and dissolution of η phase. The additional contraction could slow down the increase of CTE greatly and be expressed in the nonlinearity of CTE curve. Volume and energy changes of alloy system influenced the variation trend of CTE directly, which was caused by the precipitation of ´ phase during the cooling process. These effects were revealed by the corresponding nonlinear change of CTE.

关键词: Aluminum alloy

Effect of surface pretreatment on adhesive properties of aluminum alloys

Jinsheng ZHANG , Xuhui ZHAO

材料科学技术(英文)

The lap-shear strength and durability of adhesive bonded Al alloy joints with different pretreatments were studied by the lap-shear test and wedge test. The results indicate that the maximum lap-shear strength and durability of the bonding joints pretreated by different processes are influenced by the grade of abrasive papers and can be obviously improved by phosphoric acid anodizing. Alkali etching can obviously improve the durability of bonding joints although it slightly influences the maximum lap-shear strength. The process which is composed of grit-finishing, acetone degreasing, alkali etching and phosphoric acid anodizing, provides a better adhesive bonding property of Al alloy.

关键词: Aluminum alloy , alloy , adhesive , bonding , abrasive

Microstructural Evolution and Thermal Stability of Ultra-fine Grained Al-4Mg Alloy by Equal Channel Angular Pressing

Hongbin GENG , Subbong KANG , Shiyu HE

材料科学技术(英文)

Experiments were conducted to evaluate the grain refinement and thermal stability of ultra-fine grained Al-4Mg alloy introduced by equal-channel angular pressing (ECAP) at 473 K. The results show that the intensities of X-ray (111/222) and (200/400) peaks for the alloy processed by ECAP decrease significantly and the peak widths of half height become broadening compared with the corresponding value in the annealed alloy. The microstructure of 2 passes ECAPed alloy consists of both elongated and equiaxed subgrains. The residual strain in the alloy increases with increasing passes numbers, that appears as increasing dislocation density and lattice constant of matrix. An equiaxed ultra-fine grained structure of ~0.2μm is obtained in the present alloy after 8 passes. The ultra-fine grains are stable below 523 K, because the alloy retains extremely fine grain size of ~1μm after static annealing at 523 K for 1 h.

关键词: Aluminum alloy , null , null , null

Effect of Porosity and Cell Size on the Dynamic Compressive Properties of Aluminum Alloy Foams

Yi FENG , Zhengang ZHU , Shisheng HU , Yi PAN

材料科学技术(英文)

The dynamic mechanical properties of open-cell aluminum alloy foams with different relative densities and cell sizes have been investigated by compressive tests. The strain rates varied from 700 s-1 to 2600 s-1. The experimental results showed that the dynamic compressive stress-strain curves exhibited a typical three-stage behavior: elastic, plateau and densification. The dynamic compressive strength of foams is affected not only by the relative density but also by the strain rate and cell size. Aluminum alloy foams with higher relative density or smaller cell size are more sensitive to the strain rate than foams with lower relative density or larger cell size.

关键词: Aluminum alloy , null , null , null

Effect of Microstructure on Thermal Expansion Coefficient of 7A09 Aluminum Alloy

Hongzhi Ji

材料科学技术(英文)

The relationship between microstructure evolution and coefficient of thermal expansion (CTE) of 7A09 aluinum alloy was investigated in this paper. Differential scanning calorimetry (DSC) was combined with transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) to investigate microstructure evolution taking place in 7A09 aluminum alloy during heating and cooling process. The corresponding CTE curves of the 7A09 alloy were recorded by thermal dilatometer. Results indicated that GPII zones and η' phase were main precipitates in the highest strength tempered (T6) 7A09 alloy. The η phase was the main participate in 7A09 alloy during the cooling process. The nonlinear dependency existed between CTE and temperature in both changing temperature processes. During the heating process, obvious additional contraction of alloy volume was directly caused by phase transition, such as dissolution of ´0 phase, transition from η' to η phase and dissolution of η phase. The additional contraction could slow down the increase of CTE greatly and be expressed in the nonlinearity of CTE curve. Volume and energy changes of alloy system influenced the variation trend of CTE directly, which was caused by the precipitation of ´ phase during the cooling process. These effects were revealed by the corresponding nonlinear change of CTE.

关键词: Aluminum alloy

2A12铝合金表面铈盐掺杂硅烷杂化膜在3.5%NaCl溶液中耐蚀性能的电化学研究

张金涛 , 杨春勇 , 潘亮 , 李春东

金属学报

采用溶胶-凝胶法, 以γ-环氧丙氧丙基三甲氧基硅烷(γ-GPTMS)和正硅酸乙酯 (TEOS)为前驱体, 在2A12铝合金表面制备了稀土铈盐(Ce(NO3)3)掺杂的有机-无机杂化膜, 研究了铈盐掺杂浓度和涂层固化温度等工艺条件. 通过极化曲线和电化学阻抗谱(EIS), 比较了掺杂与未掺杂有机-无机硅烷杂化膜、铬酸盐转化膜和RE转化膜在3.5%NaCl (质量分数)溶液中的耐腐蚀性能. 测试结果均表明, 铈盐掺杂硅烷杂化膜的极化电阻比掺杂前增大了约13倍,并显著高于铬酸盐转化膜和RE转化膜.

关键词: 铈盐 , Organic-inorganic hybrid films , Aluminum alloy

Forming Process of Strong Anisotropic Material Based on the Hydrodynamic Deep Drawing with Radial Pressure

Lihui LANG , Joachim DANCKERT , Karl Brian NIELSEN

材料科学技术(英文)

The hydrodynamic deep drawing process enables net shape or near net shape forming of complicated sheet metal parts made from difficultly forming materials, such as aluminium or high strength steels. Based on the conventional hydrodynamic deep drawing process, a new process, hydrodynamic deep drawing process, in which radial pressure is applied to the rim of the blank, is proposed. This new process has been analysed using FEM simulations and the obtained results have been compared with the experimental results. The material used in the experiments was Al-Mg-Si alloy, and in the FEM-simulations the elastic-plastic behaviour of Al-Mg-Si alloy was modelled using Barlat's 89 yield criteria.

关键词: Hydroforming , null , null , null

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