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反应自生成AlN传质过程的研究

王群 , 王文忠 , 高钦 , 沈玉辉 , 陈建峰

无机材料学报

根据反应自生成AIN的传质及生长特征,构造出传质模型,并建立了传质方程.分析表明:整个反应过程分AlN晶体生长并伴随Si元素富集及AlN、Sicry,晶体共生两个阶段进行;N原子的扩散传质速率是控制总反应速率的关键因素.

关键词: AlN , nitridation reaction , mass transfer , growth

EXTRACTION KINETICS OF RARE EARTH (Ⅰ) A Constant Interfacial Cell with Laminar Flow

ZHENG Zhong , LI Deqian (Changchun Institute of Applied Chemistry , Chinese Academy of Sciences , Changchun , China Manuscript received 23 January , 1995)

金属学报(英文版)

A technique was developed to study mass trans fer process and inter facial reaction in two phases system. This constant inter facial cell with a laminar flow was made into a cubic structure. The two fluids were continuously recycled and mixed. The concentration of each liquid could be monitored by two different methods. This kind of structure made both flows near the inter face flow parallel to the inter face. The inter face was smooth and steady. The mass trans fer rate could be judged by the linear velocity of the flows. The technique can be used for the analyses of the control step in both phases near the inter face in a diffusion control process. A preliminary hydrodynamics and mass trans fer study on the cell was presented, which ensures the distinguishing between a diffusion and a chemical reaction control process. A simplified mass transfer equation,N =0.5303D 1 /2* (Ci- Cb)* (V / B) 1/2, was achieved.

关键词: : constant inter face cell , null , null , null

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