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金属缓蚀剂Langmuir-Blodgett膜及缓蚀机理的研究

邢巍 , 郭渡 , 单义斌 , 陆天虹 , 席时权

中国腐蚀与防护学报

应用Langmuir-Blodgett(LB)技术研究了硬脂酸和十六烷基三甲基溴化胶等金属缓蚀剂在碳钢电极上的取向。单分子膜覆盖层数及分子结构对其缓蚀作用的影响.在实验技术上实现了对缓蚀剂表面膜在分子规模上的控制,文中讨论了这两种缓蚀剂的缓蚀机理.

关键词: Langmuir-Blodgett膜 , Corrosion inhibitor , Stearic acid , Quaternary ammonium salt

用EQCM研究中性介质中铁缓蚀剂的成膜动力学

戴忠旭 , 甘复兴 , 汪的华 , 姚禄安

中国腐蚀与防护学报

用电化学石英晶体微天平(EQCM)研究了中性Na_2SO_4溶液中钝化型缓蚀剂NaNO_2和沉淀型缓蚀剂Na_2SiO_3在铁上的成膜行为。根据EQCM原理和条件,推导了求解真实成膜质量变化的近似公式,获得了缓蚀剂成膜的等温动力学曲线。发现含钝化型缓蚀剂NaNO_2体系中铁表面膜的生长呈抛物线规律,而在含沉淀型缓蚀剂Na_2SiO_3体系中则为直线规律;水溶液中金属表面成膜具有与金属高温氧化成膜类似的动力学规律。

关键词: 电化学石英晶体微天平 , Armco-iron , Corrosion inhibitor , Filming kinetics

N-烷基月桂酰胺对硫酸溶液中碳钢的缓蚀行为

曾凌三 , 梁本熹 , 张跃龙 , 唐辉尧

中国腐蚀与防护学报

采用电化学和失重法研究N-烷基月桂酰胺(NALA)对硫酸溶液中碳钢腐蚀的缓蚀行为和吸附规律。实验表明,其缓蚀性能优良,主要属以阻滞阳极过程为主的缓蚀剂,吸附过程为放热反应,属化学吸附,在不同吸附阶段分别遵循Temkin和Frumkin吸附等温式。

关键词: 表面活性剂 , Corrosion inhibitor , Lauryl amide

Eclipta Alba as Corrosion Pickling Inhibitor on Mild Steel in Hydrochloric Acid

M. Shyamala

材料科学技术(英文)

Due to ease of application, cost effectiveness and environmentally safe, in this study, the corrosion inhibition effect of aqueous extract of Eclipta alba in 1 N hydrochloric acid has been investigated by weight loss, potentiodynamic polarization and impedance methods and the extracts of Eclipta alba were found to be effective corrosion pickling inhibitor. The effect of immersion time and temperature revealed that the extracts of Eclipta alba with an optimum concentration of 8.0% v/v showed maximum inhibition efficiency of 99.6% at 3 h immersion time and 30°C. Arrhenius plots for mild steel immersed in 1 N HCl solution in the absence and presence of optimum concentration (8.0% in v/v) of Eclipta alba extract showed the effect of temperature. Polarization studies indicate that this plant extract acts as a mixed type inhibitor. The adsorption of
Eclipta alba follows Langmuir adsorption isotherm. The inhibition action may be due to the presence of the Wedelactone and also the alkaloid Ecliptine present in the leaves of Eclipta alba.

关键词: Eclipta alba , null , null , null

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