WANG He-feng
,
TANG Bin
,
LI Xiu-yan
钢铁研究学报(英文版)
N-doped TiO2 (N-TiO2) coatings were obtained by oxidation of titanium nitride coatings, which were prepared by the plasma surface alloying technique on stainless steel (SS). The microstructure of N-TiO2 coatings was characterized by X-ray diffraction (XRD), glow discharge optical emission spectrometry (GDOES), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), respectively. Ball-on-disc sliding wear was applied to test and compare the tribological behaviors of the coatings and substrate. XRD patterns showed that anatase type TiO2 existed in the coatings after oxidation. GDOES showed that the resultant coatings had a layered structure, comprising of N-TiO2 layer at the top and a diffusion-type interface. Such a hybrid coatings system showed good adhesion with the substrate. According to XPS, residual N atoms partially occupied O atom sites in the TiO2 lattice. Uniform, continuous and compact coatings were observed by SEM images of coatings after oxidation. Under a load of 7.6 N, the coefficient of friction was in the range of 0.27-0.38 for the N-TiO2/Al2O3 systems and the wear rate of the coatings was only one-fourteenth of that for untreated 316L SS. N-TiO2 coatings displayed much better wear resistance and antifriction performance than SS substrate.
关键词:
plasma surface alloying technique
,
wear resistance
,
stainless steel
,
titanium dioxide
ZHANG Jian
,
PENG Yan
,
LIU Hong-min
,
LIU Yun-fei
钢铁研究学报(英文版)
Abstract： To investigate the wear resistance of ZG42CrMo in industrial application, the wear behaviors under different normal loads, sliding speeds and ambient temperatures were simulated by an MMU-5G abrasion tester to acquire the friction coefficients and wear rates, with the morphology of worn surface observed by scanning electron microscopy (SEM) and chemical composition of worn surface and debris analyzed by X-ray energy dispersive spectroscopy (EDS). Combine with the theory of tribology, finally the regular of environmental factors′ influence on material wear behaviors is determined. The results show that the increase of load decreases wear resistance significantly, when the pressure reaches a certain extent, severe spalling occurs on the worn surface; the changes of speed result in the changes of size of abrasive debris, and then effect the wear behaviors, in the increasing process of speed, the wear rate increases firstly and then decreases; the rise of temperature causes changes in wear mechanism, bring forth oxidation film on the worn surface, which leads to significant improvement of the wear resistance of materials under high temperature compared to that under low temperature.
关键词:
Key words: ZG42CrMo
,
wear resistance
,
normal load
,
sliding speed
,
ambient temperature
