{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用水热法原位法和浸渍法分别制备了La/SBA-15和Fe/La/SBA-15两种SBA-15改性<span style=\"color:red\">催化</span>剂,两种材料保持了SBA-15材料的高度有序二维六孔结构,并在实验温度范围内具有良好的热稳定性.本文利用松木屑作为生物质原料,讨论了水蒸气流量、实验温度、SBA-15改性<span style=\"color:red\">催化</span>剂等影响因素对生物质<span style=\"color:red\">气化</span>过程的影响.一定温度下提高水蒸气流量可促进水蒸气与焦炭反应和焦油的重整反应,降低了焦油和焦炭产量从而提高了产气率;提高温度可以促进焦油的二次裂解;添加La/SBA-15、Fe/La/SBA-15两种<span style=\"color:red\">催化</span>剂可以促进焦油中难分解物质的裂解以及水与焦炭反应的发生.尤其是Fe/La/SBA-15<span style=\"color:red\">催化</span>剂,一定温度下提高了产气率的同时提高了燃气的热值.","authors":[{"authorName":"张玉黎","id":"65d4bce9-d669-4b17-9d23-f1d1eabf720a","originalAuthorName":"张玉黎"},{"authorName":"肖睿","id":"a7ae623f-68a7-41d2-b91b-1a2911d67b75","originalAuthorName":"肖睿"},{"authorName":"何光莹","id":"a5f5944e-eee0-47b2-a755-a81c289185c0","originalAuthorName":"何光莹"}],"doi":"","fpage":"173","id":"3158bfeb-5eea-4c37-abeb-eb1f694e4d60","issue":"1","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"081b1f76-dea6-4f6b-b83c-24bec82aa9a7","keyword":"生物质","originalKeyword":"生物质"},{"id":"baf81d8f-2866-45fe-b071-0bcf751300ba","keyword":"Fe/La/SBA-15","originalKeyword":"Fe/La/SBA-15"},{"id":"68d1280b-24f6-428d-9093-4c25fb74884c","keyword":"<span style=\"color:red\">催化</span><span style=\"color:red\">气化</span>","originalKeyword":"催化气化"},{"id":"c5689c2d-eeb0-4090-b6c2-b4efe91a3ad2","keyword":"高热值","originalKeyword":"高热值"}],"language":"zh","publisherId":"gcrwlxb201301043","title":"Fe/La/SBA-15对生物质<span style=\"color:red\">气化</span>影响研究","volume":"34","year":"2013"},{"abstractinfo":"通过失重法和X-ray衍射分析手段,研究了碱金属盐复合氧化物和卤盐对碳<span style=\"color:red\">气化</span>反应的影响规律.对于相同的阴离子,钾盐的<span style=\"color:red\">催化</span>性能好于钠盐,钠盐的<span style=\"color:red\">催化</span>效果又优于锂盐;对于同一种阳离子的复合氧化物的<span style=\"color:red\">催化</span>活性规律为:硝酸盐>氢氧化物>碳酸盐>硫酸盐>偏硅酸盐>磷酸盐,对于同一种阳离子的卤盐的<span style=\"color:red\">催化</span>活性规律为:氟盐>氯盐>碘盐>溴盐.提出了一种新的微观<span style=\"color:red\">催化</span>机理:碱金属盐的<span style=\"color:red\">催化</span>作用在于<span style=\"color:red\">催化</span>剂能改变C-C化学键的作用程度,从而加速反应的进行.<span style=\"color:red\">催化</span>活性与阳离子、阴离子种类以及化合物的稳定性有关,这3方面因素相互耦合,共同决定添加剂的<span style=\"color:red\">催化</span>性能.","authors":[{"authorName":"郭培民","id":"647212dd-3b20-4cb2-b97c-2947a2030dd0","originalAuthorName":"郭培民"},{"authorName":"张临峰","id":"ca4a19df-04db-46b4-84ad-095cb4a1c19b","originalAuthorName":"张临峰"},{"authorName":"赵沛","id":"b5c0fbf6-8f6a-4bc7-9abf-fd9521d218ff","originalAuthorName":"赵沛"}],"doi":"","fpage":"26","id":"48ff95cc-b498-49b6-b512-1c5b9b164e64","issue":"2","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"f8148edb-bfff-4b02-b775-872edab92775","keyword":"碳<span style=\"color:red\">气化</span>","originalKeyword":"碳气化"},{"id":"2c910346-4654-47da-bea9-33ca830054a6","keyword":"<span style=\"color:red\">催化</span>机理","originalKeyword":"催化机理"},{"id":"59f35253-4976-418e-9613-e62bc20545a9","keyword":"碱金属盐","originalKeyword":"碱金属盐"},{"id":"4135bba8-5502-4f90-ae3a-0db66ff02c04","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gt200802005","title":"碳<span style=\"color:red\">气化</span>反应的<span style=\"color:red\">催化</span>机理研究","volume":"43","year":"2008"},{"abstractinfo":"通过失重法和Xray衍射分析手段，研究了碱金属盐复合氧化物和卤盐对碳<span style=\"color:red\">气化</span>反应的影响规律。对于相同的阴离子，钾盐的<span style=\"color:red\">催化</span>性能好于钠盐，钠盐的<span style=\"color:red\">催化</span>效果又优于锂盐；对于同一种阳离子的复合氧化物的<span style=\"color:red\">催化</span>活性规律为：硝酸盐&gt;氢氧化物&gt;碳酸盐&gt;硫酸盐&gt;偏硅酸盐&gt;磷酸盐，对于同一种阳离子的卤盐的<span style=\"color:red\">催化</span>活性规律为：氟盐&gt;氯盐&gt;碘盐&gt;溴盐。提出了一种新的微观<span style=\"color:red\">催化</span>机理：碱金属盐的<span style=\"color:red\">催化</span>作用在于<span style=\"color:red\">催化</span>剂能改变CC化学键的作用程度，从而加速反应的进行。<span style=\"color:red\">催化</span>活性与阳离子、阴离子种类以及化合物的稳定性有关，这3方面因素相互耦合，共同决定添加剂的<span style=\"color:red\">催化</span>性能。","authors":[{"authorName":"郭培民","id":"7306ff5c-3c89-479a-b72e-2740319d4aeb","originalAuthorName":"郭培民"},{"authorName":"张临峰","id":"39db7001-1100-42f7-86e1-adc73e6d7f4e","originalAuthorName":"张临峰"},{"authorName":"赵沛","id":"56c124ff-1744-4d94-97d5-1df5d25cdb4c","originalAuthorName":"赵沛"}],"categoryName":"|","doi":"","fpage":"26","id":"7d174013-0feb-4a2c-880f-aeb581ff91e5","issue":"2","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"e5092350-6b32-47dc-9524-47edf57ce30b","keyword":"碳<span style=\"color:red\">气化</span>;<span style=\"color:red\">催化</span>机理;碱金属盐;热稳定性","originalKeyword":"碳气化;催化机理;碱金属盐;热稳定性"}],"language":"zh","publisherId":"0449-749X_2008_2_8","title":"碳<span style=\"color:red\">气化</span>反应的<span style=\"color:red\">催化</span>机理研究","volume":"43","year":"2008"},{"abstractinfo":"在分析比较目前国际上较好的几种超临界水生物质<span style=\"color:red\">催化</span><span style=\"color:red\">气化</span>制氢实验系统及实验方法的基础上,成功地设计研制出一套连续式超临界水湿生物质<span style=\"color:red\">催化</span><span style=\"color:red\">气化</span>制氢实验系统,简要介绍了该系统的特点及使用该系统取得的初步实验结果,并对各类实验系统存在的问题及待改进处作了分析.","authors":[{"authorName":"郝小红","id":"1b0e4025-147d-4ac8-8da3-76a3503a399d","originalAuthorName":"郝小红"},{"authorName":"郭烈锦","id":"a117dbed-f79a-42ce-9c80-6323da8d24df","originalAuthorName":"郭烈锦"}],"doi":"","fpage":"143","id":"bf654a10-e65f-4175-86e5-6b36ac7d66fb","issue":"2","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"e78e9019-7834-410e-baeb-3c5a31c0177c","keyword":"超临界水","originalKeyword":"超临界水"},{"id":"86d9753f-8de1-409a-84cb-cf6506b93577","keyword":"生物质","originalKeyword":"生物质"},{"id":"d580f079-2fa4-4d27-852b-9e9205d1a6f8","keyword":"制氢","originalKeyword":"制氢"},{"id":"0a28f3f4-61b2-4712-8aa0-1dcc01be6882","keyword":"实验系统","originalKeyword":"实验系统"}],"language":"zh","publisherId":"gcrwlxb200202003","title":"超临界水生物质<span style=\"color:red\">催化</span><span style=\"color:red\">气化</span>制氢实验系统与方法研究","volume":"23","year":"2002"},{"abstractinfo":"制备了Pt和Pd负载LaAl11O19整体式<span style=\"color:red\">催化</span>剂，借助XRD和BET对其进行了表征，同时考察了<span style=\"color:red\">催化</span>剂作用下模拟生物质<span style=\"color:red\">气化</span>气的燃烧特性及<span style=\"color:red\">气化</span>气中加入H2S对可燃成分<span style=\"color:red\">催化</span>燃烧的影响。结合失活样的XPS、SEM和FTIR表征结果，初步分析<span style=\"color:red\">催化</span>剂硫中毒的机理。结果表明，制得<span style=\"color:red\">催化</span>剂活性优良，明显降低了可燃成分的起燃温度，低温下Pd的活性优于Pt,Pd和Pt在抗硫中毒性上是不同的，<span style=\"color:red\">催化</span>剂失活是通过生成的表面硫酸盐覆盖活性位，失活后有一定的再生性。","authors":[{"authorName":"彭丹","id":"13e16952-2309-4652-b5c3-afff61ba3200","originalAuthorName":"彭丹"},{"authorName":"孙路石","id":"0127dd4a-b7eb-4373-bb1c-c166b45c2f2c","originalAuthorName":"孙路石"},{"authorName":"王志远","id":"6e31d5dd-94d0-49f0-810c-ea836b851f64","originalAuthorName":"王志远"},{"authorName":"向军","id":"90a9b87a-f3fb-4f53-a9a1-1fbaaf83d49a","originalAuthorName":"向军"},{"authorName":"胡松","id":"e506e72f-d873-4308-abcf-60bed61cd1ee","originalAuthorName":"胡松"},{"authorName":"苏胜","id":"75e8966f-86d8-4347-bd47-f66854dd2545","originalAuthorName":"苏胜"},{"authorName":"王鹏恒","id":"272cbf9f-74c7-4b3b-938c-6107410cbb6b","originalAuthorName":"王鹏恒"}],"doi":"","fpage":"1437","id":"b1ed692c-d30b-4a8e-b86b-6aff9377f32d","issue":"8","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报   "},"keywords":[{"id":"1f3aea44-d75f-4392-924e-f2182e9004b0","keyword":"Pt","originalKeyword":"Pt"},{"id":"4174b276-c10b-4563-9e99-035a8dca5242","keyword":"Pd","originalKeyword":"Pd"},{"id":"d7b7f172-5c70-4c11-b07b-fc5e5d3d9b31","keyword":"<span style=\"color:red\">催化</span>燃烧","originalKeyword":"催化燃烧"},{"id":"40a99c8b-cef8-4151-ad25-3a51dd9ff069","keyword":"失活","originalKeyword":"失活"},{"id":"1ff17086-6974-498f-a5fd-99b0b8fbe9dd","keyword":"硫中毒","originalKeyword":"硫中毒"}],"language":"zh","publisherId":"gcrwlxb201208040","title":"含硫生物质<span style=\"color:red\">气化</span>气<span style=\"color:red\">催化</span>燃烧性能研究","volume":"33","year":"2012"},{"abstractinfo":"改进了液相<span style=\"color:red\">气化</span>快速致密法制备C/C复合材料的技术,采用高频感应脉冲加热方式,直接对沥青浸渍碳化的预制件进行感应加热,在二茂铁的<span style=\"color:red\">催化</span>作用下以煤油作为前驱体,建立了一种制备碳/碳复合材料新的工艺方法.该工艺生成热解碳的致密化反应温度为800～1000℃,能在3h内将预制件的密度从0.3g/cm3提高到1.5～1.7g/cm3.通过金相显微镜观察样品在致密过程中不同反应阶段的微观结构,表明在二茂铁<span style=\"color:red\">催化</span>作用下热解碳在预制件内部多处结晶生长,从而能够降低液相<span style=\"color:red\">气化</span>致密反应的温度、提高了致密反应的速率.","authors":[{"authorName":"李劲","id":"ab213adb-0f87-487d-b102-d7b64d51c101","originalAuthorName":"李劲"},{"authorName":"陈振华","id":"1a751c6f-1492-4198-8311-ccc175daf9fd","originalAuthorName":"陈振华"}],"doi":"10.3321/j.issn:1000-324X.2005.06.029","fpage":"1450","id":"7a1c258d-1c11-4423-8719-ecb5bfadf33a","issue":"6","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"625b47a8-ed5b-42d3-bb41-8e3666fda123","keyword":"碳/碳复合材料","originalKeyword":"碳/碳复合材料"},{"id":"3843eca9-ffed-444e-9e76-04643ad75523","keyword":"化学液相<span style=\"color:red\">气化</span>","originalKeyword":"化学液相气化"},{"id":"091a03ea-a1cf-4af7-a1e6-1ad31312152a","keyword":"<span style=\"color:red\">催化</span>作用","originalKeyword":"催化作用"},{"id":"c32b56b6-01af-4835-9061-176a63c6a30c","keyword":"温度梯度","originalKeyword":"温度梯度"}],"language":"zh","publisherId":"wjclxb200506029","title":"<span style=\"color:red\">催化</span>型化学液相<span style=\"color:red\">气化</span>渗透沉积制备碳/碳复合材料工艺研究","volume":"20","year":"2005"},{"abstractinfo":"采用等体积浸渍法制备了不同助剂(Fe,Mg,Mn和Ce)修饰的镍-凹凸棒石粘土基<span style=\"color:red\">催化</span>剂(Ni/PG),并用于<span style=\"color:red\">催化</span>裂解生物质<span style=\"color:red\">气化</span>焦油反应.采用X射线衍射和透射电子显微镜对Ni/PG<span style=\"color:red\">催化</span>剂进行了表征,并用总碳分析仪测定了<span style=\"color:red\">催化</span>剂上的积炭.结果表明,助剂的种类及其含量对<span style=\"color:red\">催化</span>剂性能的影响显著,在所选用的助剂中,Fe助剂入最有利于提高Ni/PG<span style=\"color:red\">催化</span>剂上焦油的去除率和H_2的收率,且随助剂Fe含量的增加,<span style=\"color:red\">催化</span>剂活性逐渐提高.","authors":[{"authorName":"刘海波","id":"821cbd7c-c86a-4cc4-ba28-ec70dee6e8f4","originalAuthorName":"刘海波"},{"authorName":"陈天虎","id":"f4b3a901-d582-4efe-9a90-0bdb25236dcc","originalAuthorName":"陈天虎"},{"authorName":"张先龙","id":"7b59266e-f83d-4737-acca-5b98bfbf6f1b","originalAuthorName":"张先龙"},{"authorName":"李金虎","id":"1fd861f7-6eae-45c3-b052-5d28a9ceba1d","originalAuthorName":"李金虎"},{"authorName":"常冬寅","id":"53eeb1f4-deb3-455b-9f99-30e991541517","originalAuthorName":"常冬寅"},{"authorName":"宋磊","id":"edc97ee1-2bf3-4239-b971-1fd095fa8f7c","originalAuthorName":"宋磊"}],"doi":"10.1016/S1872-2067(09)60061-9","fpage":"409","id":"ed77ffca-926e-42df-918a-7959e520cf8b","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"5a4f6f59-360e-4cc7-9055-864106d9ce7a","keyword":"生物质<span style=\"color:red\">气化</span>","originalKeyword":"生物质气化"},{"id":"13658a88-a88f-45ed-a43b-db72d203d32b","keyword":"焦油","originalKeyword":"焦油"},{"id":"ba24e8a0-1dd0-4031-8cf8-f24ccb5185a3","keyword":"负载型<span style=\"color:red\">催化</span>剂","originalKeyword":"负载型催化剂"},{"id":"5347dcc6-d38e-4478-8c00-854b05fd8f80","keyword":"凹凸棒石","originalKeyword":"凹凸棒石"},{"id":"bdadec12-952f-41e3-830e-719591f78dc2","keyword":"镍","originalKeyword":"镍"},{"id":"57c09772-b708-4fa9-82de-65ff82b9add1","keyword":"助剂","originalKeyword":"助剂"},{"id":"f04c30b3-4e89-4989-abe4-52c50cc0683a","keyword":"积炭","originalKeyword":"积炭"}],"language":"zh","publisherId":"cuihuaxb201004009","title":"助剂对镍基<span style=\"color:red\">催化</span>剂<span style=\"color:red\">催化</span>裂解生物质<span style=\"color:red\">气化</span>焦油性能的影响","volume":"31","year":"2010"},{"abstractinfo":"以二茂铁为<span style=\"color:red\">催化</span>剂、有机小分子碳氢化合物为液态碳源,采用化学液相<span style=\"color:red\">气化</span>沉积工艺制备出密度为1.67 g/cm3的大尺寸C/C复合材料.分析了不同<span style=\"color:red\">催化</span>剂含量对C/C复合材料基体织构的影响,加入<span style=\"color:red\">催化</span>剂后材料的组织结构趋向于生成光滑层和各向同性热解碳,并在碳基体中伴生有碳纳米线和多壁碳纳米管的生成.当<span style=\"color:red\">催化</span>剂含量(＜1%)较低、沉积温度较高时有碳纳米线出现,且随着<span style=\"color:red\">催化</span>剂含量增加,碳纳米线直径由50～100 nm减小到20 nm,长度逐渐增加;当<span style=\"color:red\">催化</span>剂含量大于1%时,此时出现多壁碳纳米管,直径在30～100 nm之间,项部并有碳包覆金属颗粒的生成.","authors":[{"authorName":"李新涛","id":"2b41f791-a11f-498d-8219-18dc7d70ab4c","originalAuthorName":"李新涛"},{"authorName":"李克智","id":"68bf0b57-eda2-4f72-a635-6579dd7fd6dc","originalAuthorName":"李克智"},{"authorName":"李贺军","id":"e9c52971-ffd2-4699-9309-dd7021b1e585","originalAuthorName":"李贺军"},{"authorName":"魏剑","id":"b11e0d72-987a-4c68-9729-9cb2b962f027","originalAuthorName":"魏剑"},{"authorName":"廖晓玲","id":"b4c55a9f-13f5-44ec-b63a-affdd2d4f673","originalAuthorName":"廖晓玲"}],"doi":"","fpage":"530","id":"a471de0a-7f72-44ea-b141-e24f80e9ccfe","issue":"z3","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"fccff1ad-0fe9-42ab-a4f3-965c0b6b247a","keyword":"化学液相<span style=\"color:red\">气化</span>沉积","originalKeyword":"化学液相气化沉积"},{"id":"a472e0f1-7e69-4dbf-b6e7-fc49edadee9b","keyword":"炭/炭复合材料","originalKeyword":"炭/炭复合材料"},{"id":"7de9283c-a5aa-4187-ada0-b5df419df0f7","keyword":"<span style=\"color:red\">催化</span>","originalKeyword":"催化"},{"id":"f19ee83a-3a6f-4d2b-828e-aae745723ef2","keyword":"碳纳米管","originalKeyword":"碳纳米管"},{"id":"43df27a9-8107-48b3-90aa-d55c0d70398e","keyword":"碳纳米线","originalKeyword":"碳纳米线"}],"language":"zh","publisherId":"xyjsclygc2007z3127","title":"<span style=\"color:red\">催化</span>剂对化学液相<span style=\"color:red\">气化</span>沉积制备炭/炭复合材料基体织构的影响","volume":"36","year":"2007"},{"abstractinfo":"利用恒速升温热重法对低温下碳的<span style=\"color:red\">气化</span>反应进行了研究.结果表明:低温条件下(＜1073 K)碳的<span style=\"color:red\">气化</span>反应符合一级反应规律;减小颗粒度可以提高碳粉的<span style=\"color:red\">气化</span>性能,特别是当颗粒度减小到一定程度(D50=4μm)时效果尤为显著;<span style=\"color:red\">催化</span>剂能够提高碳粉的<span style=\"color:red\">气化</span>性能,使其等动力学温度降低,特别是当细化和<span style=\"color:red\">催化</span>同时作用时<span style=\"color:red\">气化</span>反应效率更高;活性炭的<span style=\"color:red\">气化</span>性能优于相同粒度的石墨粉;未添加<span style=\"color:red\">催化</span>剂的碳粉具有相似的<span style=\"color:red\">气化</span>机理;Li2CO3、Na2CO3、K2CO3具有相似的<span style=\"color:red\">催化</span>机理.","authors":[{"authorName":"张殿伟","id":"0aa1926a-5e13-48c5-865f-02b11321856d","originalAuthorName":"张殿伟"},{"authorName":"郭培民","id":"28053052-0983-47a3-8ebe-6a0a2c56b0e1","originalAuthorName":"郭培民"},{"authorName":"赵沛","id":"79bab71c-8c4d-4f5e-b6fc-757fefcb7ffc","originalAuthorName":"赵沛"}],"doi":"","fpage":"13","id":"0a715762-c33e-4537-8dfd-055e84914c06","issue":"6","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"73312b6f-27d6-444f-b5bd-c65df91494cd","keyword":"<span style=\"color:red\">气化</span>反应","originalKeyword":"气化反应"},{"id":"67e52d2e-61e9-4aaf-b36e-a878941baae4","keyword":"低温","originalKeyword":"低温"},{"id":"0cbbdbb6-518e-486b-b6fc-3f5dc6081ead","keyword":"碳","originalKeyword":"碳"},{"id":"d0db7e6d-09db-42f1-88c1-b78ab017c19a","keyword":"动力学","originalKeyword":"动力学"},{"id":"d706fef2-8ca3-4472-886b-dcd0d5f8df31","keyword":"补偿效应","originalKeyword":"补偿效应"}],"language":"zh","publisherId":"gt200706003","title":"低温下碳<span style=\"color:red\">气化</span>反应的动力学研究","volume":"42","year":"2007"},{"abstractinfo":"利用恒速升温热重法对低温下碳的<span style=\"color:red\">气化</span>反应进行了研究。结果表明：低温条件下（&lt;1073 K）碳的<span style=\"color:red\">气化</span>反应符合一级反应规律；减小颗粒度可以提高碳粉的<span style=\"color:red\">气化</span>性能，特别是当颗粒度减小到一定程度(D50=4 μm)时效果尤为显著；<span style=\"color:red\">催化</span>剂能够提高碳粉的<span style=\"color:red\">气化</span>性能，使其等动力学温度降低，特别是当细化和<span style=\"color:red\">催化</span>同时作用时<span style=\"color:red\">气化</span>反应效率更高；活性炭的<span style=\"color:red\">气化</span>性能优于相同粒度的石墨粉；未添加<span style=\"color:red\">催化</span>剂的碳粉具有相似的<span style=\"color:red\">气化</span>机理；Li2CO3、Na2CO3、K2CO3具有相似的<span style=\"color:red\">催化</span>机理。","authors":[{"authorName":"张殿伟","id":"84ad54b8-8902-4ef7-b8b5-7ebc59bc0e21","originalAuthorName":"张殿伟"},{"authorName":"郭培民","id":"cd293126-925b-43e8-8bd3-0b075d4a0463","originalAuthorName":"郭培民"},{"authorName":"赵沛","id":"967765b7-070b-4e12-b1b6-77b8f068f20b","originalAuthorName":"赵沛"}],"categoryName":"|","doi":"","fpage":"13","id":"957a985a-2092-4448-8b6c-b337cbdf4659","issue":"6","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"73c9fc86-1c04-42f1-8d9c-3ad5f783f4f0","keyword":"<span style=\"color:red\">气化</span>反应;低温;碳;动力学;补偿效应","originalKeyword":"气化反应;低温;碳;动力学;补偿效应"}],"language":"zh","publisherId":"0449-749X_2007_6_2","title":"低温下碳<span style=\"color:red\">气化</span>反应的动力学研究","volume":"42","year":"2007"}],"totalpage":1341,"totalrecord":13406}