{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用改进的溶胶-凝胶法令TiO2在普通玻璃载玻片表面浸渍提拉成膜,再经150℃热处理15min.用阶梯厚度仪、XRD、SEM、XPS、AFM、<span style=\"color:red\">UV-vis</span>吸收光谱和降解亚甲基蓝实验对所成薄膜的厚度、晶粒大小、表面形貌、吸光性和光催化性能进行了表征.研究结果表明:薄膜为类微晶玻璃态,其纳米粒子晶型为单一锐钛矿型,粒径在10～50nm,薄膜表面均匀、致密,具有良好紫外-可见吸收性和光催化活性.","authors":[{"authorName":"李玉花","id":"72adfb40-1cd9-47d6-bf6f-a4ed70bf439f","originalAuthorName":"李玉花"},{"authorName":"肖清泉","id":"156a5f1b-66a5-430b-a8d5-629a2102231f","originalAuthorName":"肖清泉"},{"authorName":"陈朝凤","id":"4cc5967b-8f69-4149-88e9-05eac956fbbe","originalAuthorName":"陈朝凤"},{"authorName":"黄东升","id":"0f049a2f-97ea-4130-99aa-c82f6507ad2c","originalAuthorName":"黄东升"},{"authorName":"程一兵","id":"9e0e2a8d-645d-408a-b6b4-da4486c84206","originalAuthorName":"程一兵"},{"authorName":"曾人杰","id":"6aea8413-f83d-4cec-b64c-414b030fa0fa","originalAuthorName":"曾人杰"}],"doi":"","fpage":"1206","id":"ac3bf808-7a3f-4566-b40c-ef00de4b96c4","issue":"7","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"fc3be103-1fb8-4ba8-afed-48a5650aef26","keyword":"TiO2薄膜","originalKeyword":"TiO2薄膜"},{"id":"24cbd3c1-2382-419a-b275-d4089496a6ed","keyword":"低温烧结","originalKeyword":"低温烧结"},{"id":"d3e2b8ee-a364-4ea1-9895-743e749376b5","keyword":"sol-gel法","originalKeyword":"sol-gel法"},{"id":"989b1422-b1b5-43a2-a554-59c5921666dc","keyword":"<span style=\"color:red\">UV-vis</span>","originalKeyword":"UV-vis"}],"language":"zh","publisherId":"gncl200707046","title":"纳米TiO2薄膜的低温烧结制备及表征","volume":"38","year":"2007"},{"abstractinfo":"采用甲醇钠为催化剂,乙醇为溶剂,对甲基苯乙酮、三氟乙酸乙酯催化合成了中间体4,4,4-三氟-1-(4-甲苯基)-1,3-丁二酮.中间体和对肼基苯磺酰胺盐酸盐发生环合反应得到粗品塞来昔布(Celecoxib,CLX),重结晶、抽滤、干燥,得到了纯度为99.7％的CLX.以二氯甲烷为溶剂,采用溶剂蒸发法培养出化合物CLX晶体,通过单晶衍射仪、HPLC-MS、1 HNMR、FT-IR、<span style=\"color:red\">UV-vis</span>、TG-DTA对CLX进行检测和表征,揭示了CLX的微观结构和内在规律性.单晶衍射仪检测到了衍射数据、部分健长和键角数据,准确判断出CLX为单晶化合物.HPLC-MS检测到了CLX分子的质量信息,CLX在电离室中发生了脱氢反应,最大相对丰度的质荷比(m/z)为379.9381.1 HNMR检测到了CLX分子有6组峰,积分值对应不同的化学位移,推断出CLX的氢核数目为14.FT-IR揭示出CLX分子内部的各元素之间的化学键键型,CLX为含有C-F键、苯环、吡唑环、二取代苯的伯酰胺.<span style=\"color:red\">UV-vis</span>检测出了CLX在244.1nm、250.2 nm、259.7 nm有三个吸收峰,为共轭苯环π→π*电子跃迁产生的,最大吸收波长为250.2 nm,为企业CLX产品质量检测,推测CLX的结构提供了实验依据.TG-DTA检测出CLX的质量变化与热效应,CLX的DSC曲线在170.8℃、371.6℃存在二个吸热峰,分别为CLX的相变峰、分解峰.","authors":[{"authorName":"贾太轩","id":"2eba0ef1-0221-4dbc-b93b-5826aa23a421","originalAuthorName":"贾太轩"},{"authorName":"田大勇","id":"54c32895-0bf0-4c68-923b-250408e5b388","originalAuthorName":"田大勇"},{"authorName":"张智亮","id":"3b7f91dc-f1ec-42ab-8c75-26be61b4de66","originalAuthorName":"张智亮"},{"authorName":"柴志平","id":"af4cb500-fde4-4b5b-8a49-713df089ec6c","originalAuthorName":"柴志平"},{"authorName":"路春霞","id":"8d879f7d-50b1-4c32-9272-29501a8fee9e","originalAuthorName":"路春霞"},{"authorName":"李红良","id":"8fe100df-ae9e-479d-a641-c9ba51e05230","originalAuthorName":"李红良"}],"doi":"","fpage":"2160","id":"17d65b2f-4b81-464f-829c-2c2a94a8649b","issue":"8","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"86fcdc79-5e02-42d8-8ec0-6846802b7586","keyword":"塞来昔布","originalKeyword":"塞来昔布"},{"id":"21ba99f1-b071-4f56-b18c-56036bd1fbcb","keyword":"单晶化合物","originalKeyword":"单晶化合物"},{"id":"36e2fb65-554a-4b12-b929-2c3e43c04ae9","keyword":"FT-IR","originalKeyword":"FT-IR"},{"id":"e424f080-8132-4f5d-ade7-569f84384741","keyword":"<span style=\"color:red\">UV-vis</span>","originalKeyword":"UV-vis"},{"id":"43956eb7-a12e-46b5-9783-be3bdfbd850a","keyword":"TG-DTA","originalKeyword":"TG-DTA"}],"language":"zh","publisherId":"rgjtxb98201608032","title":"塞来昔布的合成及其光谱性质研究","volume":"45","year":"2016"},{"abstractinfo":"作为贵金属纳米材料,纳米银在许多领域的广泛应用而成为当今纳米科学最感兴趣的研究对象.简单介绍了纳米银的合成方法如光化学法、超声辅助还原法、电化学还原法、模板法、辐射还原法和生物化学法,主要讨论了化学还原法和微乳液法以及纳米银合成研究的一些进展.光谱吸收是纳米银的重要性质,<span style=\"color:red\">UV-Vis</span>特征光谱是研究纳米银的形成和纳米晶生长的重要手段,因此详细评述了纳米银的光谱特性,最后,对它们的研究发展趋势进行了展望.","authors":[{"authorName":"张万忠","id":"f966513b-512c-494b-b299-7030950f39a1","originalAuthorName":"张万忠"},{"authorName":"乔学亮","id":"fe1dc841-2adf-4ddc-8b8d-969e8fbff250","originalAuthorName":"乔学亮"},{"authorName":"陈建国","id":"60033bad-b5b6-44f8-9c8a-88be17f16ad9","originalAuthorName":"陈建国"}],"doi":"","fpage":"64","id":"c32134dd-7a60-4829-bb4f-1b613e33b673","issue":"z3","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"bf383397-349e-4585-9605-440b875483d9","keyword":"纳米银","originalKeyword":"纳米银"},{"id":"cce58307-0680-4bcc-87b7-6d0944e3edf2","keyword":"合成","originalKeyword":"合成"},{"id":"bf443b03-8340-4968-a6b1-ba8bdd0e9749","keyword":"等离子体共振","originalKeyword":"等离子体共振"},{"id":"35153993-45c1-43de-b7bb-1e790385e088","keyword":"光谱特性","originalKeyword":"光谱特性"}],"language":"zh","publisherId":"xyjsclygc2007z3016","title":"纳米银的合成及其<span style=\"color:red\">UV-Vis</span>光谱特性","volume":"36","year":"2007"},{"abstractinfo":"","authors":[{"authorName":"","id":"e071d8a6-355a-4159-9bea-133ed02acc4e","originalAuthorName":""},{"authorName":"","id":"125256d6-8106-4181-92c7-7fd986678e49","originalAuthorName":""},{"authorName":"","id":"097f66cc-1f15-41ec-8144-f0eb557541a8","originalAuthorName":""},{"authorName":"","id":"d049130e-44c1-4071-8523-096fd426e093","originalAuthorName":""}],"doi":"","fpage":"36","id":"7b4d1908-6ed3-473f-8405-4c9b6d8550cb","issue":"3","journal":{"abbrevTitle":"WHLGDXXBCLKXBYWB","coverImgSrc":"journal/img/cover/20081008102608458.jpg","id":"63","issnPpub":"1000-2413","publisherId":"WHLGDXXBCLKXBYWB","title":"武汉理工大学学报-材料科学版(英文版)"},"keywords":[{"id":"4c816cc0-b652-4d69-abad-08b252ebe5b2","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"whgydxxb-e200303010","title":"<span style=\"color:red\">UV-Vis</span> and Photoluminescent Spectra of TiO2 Films","volume":"18","year":"2003"},{"abstractinfo":"","authors":[{"authorName":"","id":"dfb16009-8174-4d48-97d5-4109c09669d9","originalAuthorName":""},{"authorName":"","id":"4f2d9c3f-467b-452c-b5ea-d33d53402542","originalAuthorName":""},{"authorName":"","id":"7904ffa4-d572-4639-a520-1fd5a98af75f","originalAuthorName":""},{"authorName":"","id":"5ef99100-0388-4acd-b5c0-752e780a8b48","originalAuthorName":""},{"authorName":"","id":"64e83977-56f5-4e2b-af68-53f11d61a635","originalAuthorName":""}],"doi":"10.1007/s11595-010-2210-5","fpage":"210","id":"0fe01cf2-ab66-42a9-b20e-6cff191bc278","issue":"2","journal":{"abbrevTitle":"WHLGDXXBCLKXBYWB","coverImgSrc":"journal/img/cover/20081008102608458.jpg","id":"63","issnPpub":"1000-2413","publisherId":"WHLGDXXBCLKXBYWB","title":"武汉理工大学学报-材料科学版(英文版)"},"keywords":[{"id":"dcd9d9a3-c8cd-41f2-9a1a-1538f741f9a8","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"whgydxxb-e201002008","title":"Temperature Effect on the Photocatalytic Degradation of Methyl Orange under <span style=\"color:red\">UV-vis</span> Light Irradiation","volume":"25","year":"2010"},{"abstractinfo":"","authors":[{"authorName":"吉红念","id":"add88196-a5a5-41d9-8a8d-48c31e942b07","originalAuthorName":"吉红念"},{"authorName":"黄晓华","id":"e89efcc4-fa73-4cd7-8685-3aa4833d7d10","originalAuthorName":"黄晓华"},{"authorName":"周青","id":"5514e0d8-cadd-4833-9b96-61014596d1a0","originalAuthorName":"周青"},{"authorName":"陆天虹","id":"4824f4f6-9636-4b0e-aec3-9cca492ce483","originalAuthorName":"陆天虹"}],"doi":"","fpage":"541","id":"102e6b2c-0a94-405e-818e-fbcab01f8009","issue":"5","journal":{"abbrevTitle":"XTXBYWB","coverImgSrc":"journal/img/cover/XTXBEN.jpg","id":"66","issnPpub":"1002-0721","publisherId":"XTXBYWB","title":"稀土学报(英文版)"},"keywords":[{"id":"506512a4-2df6-4a03-b343-3a7079ce823e","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"zgxtxb-e200205047","title":"<span style=\"color:red\">UV-Vis</span> Spectroscopy Study on Interaction between Microperoxidase-11 and Pr Ion Under Acid Rain Stress","volume":"20","year":"2002"},{"abstractinfo":"","authors":[{"authorName":"吉红念","id":"94de36e4-3d3d-4fbe-8451-9176fb8b0636","originalAuthorName":"吉红念"},{"authorName":"黄晓华","id":"8d9ccd16-79ac-40ec-89c8-04ac4114fd5c","originalAuthorName":"黄晓华"},{"authorName":"周青","id":"82cf68ec-2181-4e47-97be-22da2431ed0c","originalAuthorName":"周青"},{"authorName":"陆天虹","id":"2e32231a-94dc-4dc5-bf44-096859308d20","originalAuthorName":"陆天虹"}],"doi":"","fpage":"541","id":"1dad12bd-9ed4-46ff-9a0d-6b3793b0ae40","issue":"5","journal":{"abbrevTitle":"XTXBYWB","coverImgSrc":"journal/img/cover/XTXBEN.jpg","id":"66","issnPpub":"1002-0721","publisherId":"XTXBYWB","title":"稀土学报(英文版)"},"keywords":[{"id":"a3ad9c59-5a97-4276-b47d-10f0732868a9","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"zgxtxb-e200205047","title":"<span style=\"color:red\">UV-Vis</span> Spectroscopy Study on Interaction between Microperoxidase-11 and Pr Ion Under Acid Rain 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