{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"合成了不同摩尔比的甲基苯甲酰甲基亚砜<span style=\"color:red\">高氯酸</span>铕、铥异核配合物和<span style=\"color:red\">高氯酸</span>铕、镨异核配合物(<span style=\"color:red\">Eu</span>1-xREx)(ClO4)<span style=\"color:red\">3</span>·L5·C2H5OH(RE=<span style=\"color:red\">Tm</span>、Pr,x=0.000～0.200,L=C6H5COCH2SOCH<span style=\"color:red\">3</span>).红外光谱及摩尔电导表明,配体通过亚砜基上的氧原子与<span style=\"color:red\">稀土</span>离子配位,羰基氧不参与配位,三个ClO4-有两个在内界参与了配位,而另一个在外界不参与配位.荧光光谱表明,当<span style=\"color:red\">Tm3</span>+和Pr<span style=\"color:red\">3</span>+的掺入量分别在0.001mol～0.01mol和0.001mol～0.100mol之间时,对<span style=\"color:red\">Eu3</span>+的荧光产生敏化作用,且<span style=\"color:red\">Tm3</span>+和Pr<span style=\"color:red\">3</span>+的掺入量都为0.001mol时,敏化强度最大,分别可使<span style=\"color:red\">Eu3</span>+荧光强度增加109%和137%.","authors":[{"authorName":"陈丽娟","id":"2806dfef-7142-4960-8851-c295fe8e8c2a","originalAuthorName":"陈丽娟"},{"authorName":"李文先","id":"ae7aaec9-fa51-4701-85f0-e962c9cf8640","originalAuthorName":"李文先"},{"authorName":"王宏胜","id":"02bf684a-86af-4343-8d6a-0355adf38122","originalAuthorName":"王宏胜"},{"authorName":"其其格","id":"a0103b4a-5dff-4d7b-9c0c-ff98e32fc49a","originalAuthorName":"其其格"},{"authorName":"王春莲","id":"95eaee6d-b099-47b3-8c04-14db0ed5c340","originalAuthorName":"王春莲"}],"doi":"10.3969/j.issn.1004-0277.2008.02.004","fpage":"15","id":"7d629d6e-85c2-4100-8b03-cfe0037ddba0","issue":"2","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"6e5f234d-685e-40d8-9a5d-9d38ad32b66f","keyword":"甲基苯甲酰甲基亚砜","originalKeyword":"甲基苯甲酰甲基亚砜"},{"id":"068f2913-c818-43e2-aa24-09756c1da91c","keyword":"荧光增强效应","originalKeyword":"荧光增强效应"},{"id":"12d66ea7-32bd-4e72-8c52-2454769c542b","keyword":"<span style=\"color:red\">高氯酸</span>(<span style=\"color:red\">Eu3</span>+,<span style=\"color:red\">Tm3</span>+)(<span style=\"color:red\">Eu3</span>+,Pr<span style=\"color:red\">3</span>+)异核配合物","originalKeyword":"高氯酸(Eu3+,Tm3+)(Eu3+,Pr3+)异核配合物"}],"language":"zh","publisherId":"xitu200802004","title":"在甲基苯甲酰甲基亚砜<span style=\"color:red\">高氯酸</span>体系中<span style=\"color:red\">Tm3</span>+、Pr<span style=\"color:red\">3</span>+对<span style=\"color:red\">Eu3</span>+的荧光增强效应","volume":"29","year":"2008"},{"abstractinfo":"合成并表征了六种不同掺杂比例<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>铕掺铥与对甲苯基苯乙烯基亚砜的固态配合物.经元素分析确定了配合物的组成为:(EuxTm1-x) (ClO4)<span style=\"color:red\">3</span>*L7(x=1.000,0.999,0.995,0.990,0.950,0.900; L= C6H5CH=CHSOC6H4CH<span style=\"color:red\">3</span>).配合物的红外光谱表明,配体通过亚砜基氧原子与<span style=\"color:red\">稀土</span>离子配位,烯键未参与配位.在丙酮溶液中测定的摩尔电导率表明,配合物为1∶2型电解质,三个 ClO4-无机抗衡阴离子,其中一个在内界,两个在外界.配合物的荧光发射光谱中出现了比磁偶极跃迁(5D0→7F1)强的电偶极跃迁(5D0→7F2),表明配合物不存在反演中心.掺杂配合物的荧光光谱表明,将千分之一的铥掺入后,铕离子的发光增强增加到111%.","authors":[{"authorName":"郑玉山","id":"79d70ca0-f3cd-42f9-8daa-0eff2e466278","originalAuthorName":"郑玉山"},{"authorName":"李文先","id":"45d1ac22-2954-46b4-993d-405a0f3189de","originalAuthorName":"李文先"},{"authorName":"陈丽娟","id":"50644035-c2ed-49f4-bfe8-9d0b5b0ad735","originalAuthorName":"陈丽娟"}],"doi":"10.3969/j.issn.1004-0277.2008.05.006","fpage":"20","id":"b9ff0b0f-9a8b-4071-ba9f-493689f3852f","issue":"5","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"ff8ac8fe-e8d8-45b8-9c7e-2d9905bca950","keyword":"对甲苯基苯乙烯基亚砜","originalKeyword":"对甲苯基苯乙烯基亚砜"},{"id":"8d7bd8e3-35ab-45df-a3c0-f770c084819f","keyword":"<span style=\"color:red\">高氯酸</span><span style=\"color:red\">稀土</span>(<span style=\"color:red\">Eu3</span>+、<span style=\"color:red\">Tm3</span>+)","originalKeyword":"高氯酸稀土(Eu3+、Tm3+)"},{"id":"710bb751-db4a-42c4-bd88-8a0b0354691b","keyword":"荧光增强效应","originalKeyword":"荧光增强效应"}],"language":"zh","publisherId":"xitu200805006","title":"对甲苯基苯乙烯基亚砜<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>盐体系中<span style=\"color:red\">Tm3</span>+→<span style=\"color:red\">Eu3</span>+的荧光增强效应","volume":"29","year":"2008"},{"abstractinfo":"合成了六种不同掺杂比例的<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>盐(铽掺铥)与甲基苯甲酰甲基亚砜的固态配合物,经元素分析、<span style=\"color:red\">稀土</span>络合滴定确定其组成为:(TbxTmy)(ClO4)<span style=\"color:red\">3</span>·L5·C2H5OH(x∶y=1.000∶0.000,0.999∶0.001,0.995∶0.005,0.990∶0.010, 0.950∶0.050,0.900∶0.100).荧光光谱测定结果表明,将铥掺入铽后,可大大提高配合物中铽离子的荧光发射强度,当x∶y=0.995∶0.005时敏化强度最大,可使配合物的荧光强度增加到147%.并且在本文所研究的掺杂比例范围内,配合物中<span style=\"color:red\">Tm3</span>+对Tb<span style=\"color:red\">3</span>+的发光一直起敏化作用.","authors":[{"authorName":"李文先","id":"a8c7909b-d6fc-42fe-832c-11d07b1e7c7e","originalAuthorName":"李文先"},{"authorName":"郑玉山","id":"5c965da5-6a87-460d-b146-403859f3fe9c","originalAuthorName":"郑玉山"},{"authorName":"其其格","id":"0a363718-6be8-4456-b8ce-e432d395d84b","originalAuthorName":"其其格"},{"authorName":"王宏胜","id":"33f88d73-e4a9-4a07-b382-891e03accba5","originalAuthorName":"王宏胜"},{"authorName":"张瑞平","id":"89653732-a00e-42d0-b980-0b07a6b07d6a","originalAuthorName":"张瑞平"},{"authorName":"秦彩花","id":"55897ab5-7919-4757-8d5e-2f09ccdd54e5","originalAuthorName":"秦彩花"}],"doi":"10.3969/j.issn.1004-0277.2006.06.003","fpage":"11","id":"902a75f6-b604-4ad4-b821-6503795734f8","issue":"6","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"5a53eff1-6fc1-4106-b1d8-c42f322e526f","keyword":"<span style=\"color:red\">高氯酸</span>铽","originalKeyword":"高氯酸铽"},{"id":"350be677-8e20-49c7-8ebd-55daa060cadb","keyword":"<span style=\"color:red\">高氯酸</span>铥","originalKeyword":"高氯酸铥"},{"id":"883cb588-f6b7-4651-994b-74fa034db5ab","keyword":"荧光增强","originalKeyword":"荧光增强"},{"id":"249b4125-ff15-4295-8c79-9c43cc56da37","keyword":"甲基苯甲酰甲基亚砜","originalKeyword":"甲基苯甲酰甲基亚砜"}],"language":"zh","publisherId":"xitu200606003","title":"<span style=\"color:red\">Tm3</span>+对甲基苯甲酰甲基亚砜<span style=\"color:red\">高氯酸</span>铽配合物的荧光增强效应","volume":"27","year":"2006"},{"abstractinfo":"应用固相反应法合成了<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>盐与邻氨基苯甲酸的配合物.对配合物进行了组成分析及热谱分析,确定了配合物组成为[RE(LH)2(L)(ClO4)2]·6H2O(RE:Nd,<span style=\"color:red\">Eu</span>,Tb; LH: C6H4(NH2)COOH;L:C6H4(NH2)COO-).通过IR光谱、紫外光谱及摩尔电导的测定推测了配位情况.溶解性实验表明配合物可溶于乙醇,但不溶于水.荧光光谱实验表明:固相反应合成Tb<span style=\"color:red\">3</span>+的<span style=\"color:red\">高氯酸</span>盐邻氨基苯甲酸的配合物具有良好的荧光性能.","authors":[{"authorName":"李文先","id":"be72bc79-7aa8-4f4f-87b6-140dcb6e5747","originalAuthorName":"李文先"},{"authorName":"田桂香","id":"d29cdf92-a7e2-4098-a7e2-ca4a8dc7108e","originalAuthorName":"田桂香"},{"authorName":"其其格","id":"3d7d1e53-382d-4fb2-967c-904d231d5269","originalAuthorName":"其其格"},{"authorName":"王宏胜","id":"8977121d-7634-4657-a2ba-018c97f26741","originalAuthorName":"王宏胜"}],"doi":"10.3969/j.issn.1004-0277.2004.02.001","fpage":"1","id":"d214c691-3afa-470b-9cd0-632d3eddfa78","issue":"2","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"750dce8a-ca34-44ee-b256-b3ad944d4420","keyword":"固相合成","originalKeyword":"固相合成"},{"id":"613e1012-75e9-4bbe-833c-63202e45a01d","keyword":"<span style=\"color:red\">高氯酸</span><span style=\"color:red\">稀土</span>","originalKeyword":"高氯酸稀土"},{"id":"68b715e0-ffe6-4b00-ad31-306616604b2b","keyword":"邻氨基苯甲酸配合物","originalKeyword":"邻氨基苯甲酸配合物"},{"id":"7ed0dcbf-27d7-406e-a8d5-750027a42fe0","keyword":"发光","originalKeyword":"发光"}],"language":"zh","publisherId":"xitu200402001","title":"<span style=\"color:red\">高氯酸</span><span style=\"color:red\">稀土</span>邻氨基苯甲酸配合物的固相合成及Tb<span style=\"color:red\">3</span>+的发光","volume":"25","year":"2004"},{"abstractinfo":"合成并表征了<span style=\"color:red\">高氯酸</span><span style=\"color:red\">稀土</span>与二苯基亚砜、苯甲酸的六种四元配合物.经元素分析、差热-热重分析,表明四元配合物组成为[REL5L′(ClO4)](ClO4)(RE=Tb,Dy,Ho,Er,<span style=\"color:red\">Tm</span>,Yb;L=C6H5SOC6H5,L′=C6H5COO-).IR、1 HNMR表明,第一配体二苯基亚砜通过一个亚砜基氧原子、第二配体苯甲酸脱质子以阴离子形式通过一个羧基氧原子单齿与<span style=\"color:red\">稀土</span>离子配位.摩尔电导率表明配合物为1:1型,两个 ClO4-无机抗衡阴离子,其中一个在内界,一个在外界;配合物的荧光光谱表明,Tb<span style=\"color:red\">3</span>+、Dy<span style=\"color:red\">3</span>+四元配合物的荧光强度分别比二苯基亚砜与<span style=\"color:red\">高氯酸</span><span style=\"color:red\">稀土</span>二元配合物的荧光强度提高226%和422%.磷光光谱表明第二配体的加入提高了配体的三重态能级与<span style=\"color:red\">稀土</span>离子激发态能级的匹配程度.铽配合物的电子顺磁共振谱在g=1.9920处出现一个单峰,表明该配合物具有成单电子,是顺磁性物质.","authors":[{"authorName":"李文先","id":"e90f1459-af7d-4a4e-88e6-c31662291b77","originalAuthorName":"李文先"},{"authorName":"秦彩花","id":"c916627a-b3f0-43d7-9277-b0b532ed3add","originalAuthorName":"秦彩花"},{"authorName":"石晓燕","id":"be6ca61e-f169-4c6c-9f79-9ebda1a820b2","originalAuthorName":"石晓燕"},{"authorName":"耿刚强","id":"44b0ba29-2293-4123-abdb-98a9d3145f6c","originalAuthorName":"耿刚强"},{"authorName":"孙晓军","id":"4737d0c6-d03f-44d6-9ef9-695736286efd","originalAuthorName":"孙晓军"},{"authorName":"孙雪莲","id":"3037c606-22ba-489c-9371-1dc1107d8731","originalAuthorName":"孙雪莲"},{"authorName":"柴文娟","id":"a6a7cd24-4a9d-417f-955d-ee812d4fc229","originalAuthorName":"柴文娟"}],"doi":"10.3969/j.issn.1004-0277.2009.04.002","fpage":"6","id":"5cf41711-bfc8-4ab7-9cd8-3364d918c35b","issue":"4","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"2c7cd578-5c87-40fc-ac1f-485f829207d1","keyword":"二苯基亚砜","originalKeyword":"二苯基亚砜"},{"id":"64858ab4-6b9c-4274-97aa-adbdfea89698","keyword":"苯甲酸","originalKeyword":"苯甲酸"},{"id":"2a825d6f-9995-40ab-8b5c-31a13cb03671","keyword":"<span style=\"color:red\">稀土</span>四元配合物","originalKeyword":"稀土四元配合物"},{"id":"a24bb25d-cec2-4a6b-b39c-0918d774516e","keyword":"发光","originalKeyword":"发光"}],"language":"zh","publisherId":"xitu200904002","title":"二苯基亚砜、苯甲酸与重<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>四元配合物的合成及Tb<span style=\"color:red\">3</span>+、Dy<span style=\"color:red\">3</span>+光致发光","volume":"30","year":"2009"},{"abstractinfo":"合成了<span style=\"color:red\">高氯酸</span>铕二苯亚砜和不同物质量比的<span style=\"color:red\">高氯酸</span>(Ⅲ)、钬(Ⅲ)二苯亚砜异核配合物(EuxHo1-x)(DPSO)7(ClO4)<span style=\"color:red\">3</span>.测定了配合物的组成、IR、粉晶荧光激发和发射光谱.荧光光谱表明:虽然Ho<span style=\"color:red\">3</span>+的发射几率较高的5S2激发态能级高于<span style=\"color:red\">Eu3</span>+,但并未对<span style=\"color:red\">Eu3</span>+的发光产生敏化作用,相反当掺入0.002mol的Ho<span style=\"color:red\">3</span>+时即对<span style=\"color:red\">Eu3</span>+的发光产生猝灭作用.另外从<span style=\"color:red\">Eu3</span>+的荧光光谱知:5D0→7F2的电偶极跃迁强度大大高于5D0→7F1的磁偶极跃迁,这表明铕(Ⅲ)在配合物晶体中处于非对称中心的位置.","authors":[{"authorName":"李文先","id":"b7cdc0e7-7540-4407-93c6-7213c1fb5691","originalAuthorName":"李文先"},{"authorName":"刘英平","id":"1eb41c92-751b-4920-b11f-5110bdc397fe","originalAuthorName":"刘英平"},{"authorName":"巴拉吉尼玛","id":"abd78aec-6bb5-45ab-93ba-396e4a3492e2","originalAuthorName":"巴拉吉尼玛"},{"authorName":"石永强","id":"5e3cb7f5-7fbe-4b52-9edd-f7caade3a4b8","originalAuthorName":"石永强"}],"doi":"10.3969/j.issn.1004-0277.2001.06.005","fpage":"16","id":"56bd6d05-f8fd-4bbb-98cd-bc9da0084273","issue":"6","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"a41095b5-65dc-4438-a051-8effd61e179a","keyword":"<span style=\"color:red\">高氯酸</span>铕","originalKeyword":"高氯酸铕"},{"id":"e143d37f-3f52-4509-8ec9-855985119b4a","keyword":"<span style=\"color:red\">高氯酸</span>钬","originalKeyword":"高氯酸钬"},{"id":"1fec411a-fbfc-4a9e-979e-4226e9926edd","keyword":"二苯亚砜","originalKeyword":"二苯亚砜"},{"id":"fc3bbd57-40a0-4f57-b7f1-dceef3fc5443","keyword":"发光","originalKeyword":"发光"}],"language":"zh","publisherId":"xitu200106005","title":"Ho<span style=\"color:red\">3</span>+对二苯亚砜<span style=\"color:red\">高氯酸</span>铕配合物发光的影响","volume":"22","year":"2001"},{"abstractinfo":"以硝酸镧和硝酸钴为原料, 通过硬脂酸法制备了纳米LaCoO<span style=\"color:red\">3</span>.采用红外光谱、 X射线衍射、透射电镜等测试手段对产物进行了表征, 并用热分析法考察了不同含量的纳米LaCoO<span style=\"color:red\">3</span>对<span style=\"color:red\">高氯酸</span>铵热分解的催化作用.结果表明, 在600 ℃下可获得结晶良好的钙钛矿型纳米LaCoO<span style=\"color:red\">3</span>, 粒径约40～60 nm.纳米LaCoO<span style=\"color:red\">3</span>能强烈催化<span style=\"color:red\">高氯酸</span>铵的热分解, 催化作用随着LaCoO<span style=\"color:red\">3</span>含量的增加而增强.添加5%的纳米LaCoO<span style=\"color:red\">3</span>可使<span style=\"color:red\">高氯酸</span>铵的高温分解温度下降116 ℃, 分解放热量也由2%时的1390 J·g-1增至1600 J·g-1.","authors":[{"authorName":"朱俊武","id":"52a5541d-5c7e-4121-a655-dffa0a223521","originalAuthorName":"朱俊武"},{"authorName":"王艳萍","id":"76337cf2-dc90-4629-b796-f5d607caf3c1","originalAuthorName":"王艳萍"},{"authorName":"汪信","id":"1e6cc266-a7cf-4476-9619-670a715ccb6a","originalAuthorName":"汪信"},{"authorName":"杨绪杰","id":"9cc9a28c-91bb-4963-a261-dc33878181ec","originalAuthorName":"杨绪杰"},{"authorName":"陆路德","id":"6f462059-cbd0-41ec-82c3-7d0b16195dba","originalAuthorName":"陆路德"}],"doi":"","fpage":"364","id":"8822d6b9-2ac2-41a2-aa45-50f00d029ee6","issue":"3","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"f82b836c-886a-44d9-a40a-06ebc01631c4","keyword":"LaCoO<span style=\"color:red\">3</span>","originalKeyword":"LaCoO3"},{"id":"f8cd8dda-7f33-45d0-84fa-c6df6c6a38b2","keyword":"硬脂酸法","originalKeyword":"硬脂酸法"},{"id":"7c61f2e3-9e6d-4a70-83b1-65b7e87a76df","keyword":"<span style=\"color:red\">高氯酸</span>铵","originalKeyword":"高氯酸铵"},{"id":"3247f8aa-3c9a-4e7d-a357-804bc561caae","keyword":"热分解","originalKeyword":"热分解"},{"id":"b499b1b9-b8bf-488b-b39c-fde7626d75e6","keyword":"催化性能","originalKeyword":"催化性能"},{"id":"27c19a0d-94c9-4d2d-a1e4-2ec55639c9ee","keyword":"<span style=\"color:red\">稀土</span>","originalKeyword":"稀土"}],"language":"zh","publisherId":"zgxtxb200703021","title":"纳米LaCoO<span style=\"color:red\">3</span>的制备及其对<span style=\"color:red\">高氯酸</span>铵分解的催化性能","volume":"25","year":"2007"},{"abstractinfo":"用两相体系方法制备了纳米Fe2O<span style=\"color:red\">3</span>,并用X射线衍射、红外光谱和粒度分析对其结构进行了表征. 结果表明,当有机溶胶的pH=6,油酸与Fe<span style=\"color:red\">3</span>+的摩尔比为1∶3.5时,Fe(OH)<span style=\"color:red\">3</span>在油相中的萃取率可高达90%,将有机溶胶在120 ℃回流8 h后可得到非晶态、窄粒度分布的纳米Fe2O<span style=\"color:red\">3</span>粒子,其粒径在12 nm左右. 分别采用恒容燃烧热和差热分析研究了纳米Fe2O<span style=\"color:red\">3</span>对<span style=\"color:red\">高氯酸</span>铵热分解的催化性能. 结果表明,在模拟固体推进剂中分别加入4.7%微米Fe2O<span style=\"color:red\">3</span>和4.7%纳米Fe2O<span style=\"color:red\">3</span>后,恒容燃烧热分别提高了2 350.84和5 095.70 J/g. 在<span style=\"color:red\">高氯酸</span>铵中加入5%微米Fe2O<span style=\"color:red\">3</span>可使<span style=\"color:red\">高氯酸</span>铵两个放热峰的出现分别提前1.10和62.25 ℃,而加入5%纳米Fe2O<span style=\"color:red\">3</span>时分别提前61.89和118.82 ℃,这说明纳米Fe2O<span style=\"color:red\">3</span>的催化活性优于微米Fe2O<span style=\"color:red\">3</span>.","authors":[{"authorName":"马振叶","id":"3797fcd5-d818-41df-81aa-a88408caa3ab","originalAuthorName":"马振叶"},{"authorName":"李凤生","id":"64012154-7bb6-48d7-a480-7e0cf0344180","originalAuthorName":"李凤生"},{"authorName":"崔平","id":"71f6358f-5969-47fd-96f1-e5d11f20dd43","originalAuthorName":"崔平"},{"authorName":"白华萍","id":"3749bec6-3430-43b8-b0c1-badb21557667","originalAuthorName":"白华萍"}],"doi":"","fpage":"795","id":"a1db53d3-82b7-4db5-85f0-7501f2248023","issue":"10","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"382eb9d4-1688-410f-a234-2e21faffa005","keyword":"两相体系","originalKeyword":"两相体系"},{"id":"a6431b0e-d22d-4514-bdcd-365c0166a175","keyword":"氧化铁","originalKeyword":"氧化铁"},{"id":"be69a796-8c19-4e9f-bb63-f469fe090e90","keyword":"纳米粒子","originalKeyword":"纳米粒子"},{"id":"0e87b5fe-cfb0-4cce-be1c-2620e4600272","keyword":"<span style=\"color:red\">高氯酸</span>铵","originalKeyword":"高氯酸铵"},{"id":"609ae1d5-9fc4-40df-bedf-e4f2bd096fa6","keyword":"热分解","originalKeyword":"热分解"}],"language":"zh","publisherId":"cuihuaxb200310017","title":"纳米Fe2O<span style=\"color:red\">3</span>的制备及其对<span style=\"color:red\">高氯酸</span>铵热分解的催化性能","volume":"24","year":"2003"},{"abstractinfo":"合成了5种甲基苯甲酰甲基亚砜与轻<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>盐配合物RE(ClO4)<span style=\"color:red\">3</span>·L5·C2H5OH(RE=La,n,Nd,Sm,<span style=\"color:red\">Eu</span>;L=C6H5COCH2SOCH<span style=\"color:red\">3</span>),经元素分析、<span style=\"color:red\">稀土</span>络合滴定、摩尔电导及热重分析确定了配合物的组成,测定了配体及配合物的的IR谱、1HNMR及铕配合物的磷光光谱、荧光激发和发射光谱,根据磷光发射光谱数据计算了配体的三重态能级值.荧光发射光谱表明,配体可有效的向<span style=\"color:red\">Eu3</span>+离子传能使其发射较强荧光.","authors":[{"authorName":"李文先","id":"5deafd2b-735f-42a8-8f6e-a5376adb3a3a","originalAuthorName":"李文先"},{"authorName":"其其格","id":"e5c3496f-8cb0-46a2-95c2-193f49c24a77","originalAuthorName":"其其格"},{"authorName":"王宏胜","id":"84c5dd67-e8e4-4505-8d14-9ad5b678633e","originalAuthorName":"王宏胜"},{"authorName":"陈丽娟","id":"e9f5fde4-c26d-4bd4-89d5-46af109cc9d1","originalAuthorName":"陈丽娟"},{"authorName":"郭磊","id":"befd17d9-3884-459c-887f-a18c29f504cb","originalAuthorName":"郭磊"}],"doi":"10.3969/j.issn.1004-0277.2007.03.007","fpage":"26","id":"a1e9146a-e07b-4e2c-9791-c9405dcdd814","issue":"3","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"e8ed3cd9-2773-4dbb-8658-b23b0ff48616","keyword":"轻<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>盐","originalKeyword":"轻稀土高氯酸盐"},{"id":"e61d920f-523d-414b-9f10-b2dd771880fc","keyword":"甲基苯甲酰甲基亚砜的配合物","originalKeyword":"甲基苯甲酰甲基亚砜的配合物"},{"id":"3a7e0483-51b9-4e73-99c6-d695e4853098","keyword":"合成及表征","originalKeyword":"合成及表征"}],"language":"zh","publisherId":"xitu200703007","title":"轻<span style=\"color:red\">稀土</span><span style=\"color:red\">高氯酸</span>盐甲基苯甲酰甲基亚砜配合物的合成及表征","volume":"28","year":"2007"},{"abstractinfo":"选用CoCl2·6H2O分别与NaOH, H2C2O4·2H2O, Na2CO<span style=\"color:red\">3</span>·10H2O及Na2C2O4组成四个反应体系,通过室温固相反应制备了不同平均粒径的纳米Co<span style=\"color:red\">3</span>O4, 并用X射线衍射和透射电镜对Co<span style=\"color:red\">3</span>O4的物相、形貌和粒径大小进行了表征. 结果表明, Co<span style=\"color:red\">3</span>O4的平均粒径分别为23, 30, 35和150 nm, 大小均匀,分散性好. 还用差热分析法考察了纳米Co<span style=\"color:red\">3</span>O4对<span style=\"color:red\">高氯酸</span>铵热分解的催化性能,并与微米Co<span style=\"color:red\">3</span>O4进行了比较. 结果表明,纳米Co<span style=\"color:red\">3</span>O4可使<span style=\"color:red\">高氯酸</span>铵的低温放热峰消失,高温放热峰温度降至323.5 ℃, 降低了128.5 ℃, 表观分解热增加了750 J/g, 达 1 265 J/g, 纳米Co<span style=\"color:red\">3</span>O4对<span style=\"color:red\">高氯酸</span>铵热分解的催化性能明显好于微米Co<span style=\"color:red\">3</span>O4.","authors":[{"authorName":"陈伟凡","id":"9f460810-9dd9-4a77-9926-bc5bbcf32e22","originalAuthorName":"陈伟凡"},{"authorName":"李凤生","id":"6d9aa6ab-1d35-4dac-b5a6-3898e86da475","originalAuthorName":"李凤生"},{"authorName":"刘建勋","id":"14263fa0-a18a-48b7-83af-b2ffbaf631a8","originalAuthorName":"刘建勋"},{"authorName":"宋洪昌","id":"955406d7-2054-4d7f-a208-e496e721ef27","originalAuthorName":"宋洪昌"},{"authorName":"于吉义","id":"99d21708-8e74-47e4-84a8-e3cb894e208d","originalAuthorName":"于吉义"}],"doi":"","fpage":"1073","id":"64e1c7f2-5673-4cee-8f57-2f52ba4ed341","issue":"12","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"3170d347-bc95-4a3d-a5fd-61fbe93ac616","keyword":"纳米粉体","originalKeyword":"纳米粉体"},{"id":"6a2a50f1-f6fb-4c0b-b9e3-dd6b13fff48d","keyword":"氧化钴","originalKeyword":"氧化钴"},{"id":"c9ce2fa8-ec1f-4673-9d7c-dc7bcf97dc41","keyword":"固相反应","originalKeyword":"固相反应"},{"id":"df1f17b1-191a-4d87-ab6d-e0bd2936cba8","keyword":"<span style=\"color:red\">高氯酸</span>铵","originalKeyword":"高氯酸铵"},{"id":"fe4658e3-be21-40c6-aea2-9234c5008302","keyword":"热分解","originalKeyword":"热分解"},{"id":"dd6fc5d5-3c3a-4380-a4fd-98a6b608efd7","keyword":"催化性能","originalKeyword":"催化性能"}],"language":"zh","publisherId":"cuihuaxb200512008","title":"纳米Co<span style=\"color:red\">3</span>O4的制备及其对<span style=\"color:red\">高氯酸</span>铵热分解的催化性能","volume":"26","year":"2005"}],"totalpage":6661,"totalrecord":66608}