{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以成本低廉的无机钛盐硫酸氧钛为钛源,首先利用低温水热同步晶化技术制备了具有可见光活性的氮掺杂纳米二氧化钛(N-TiO2)溶胶,然后采用喷涂工艺在瓷绝缘子釉面上喷涂了SiO2溶胶和N-TiO2溶胶制备了具有自清洁功能的N-TiO2/SiO2复合薄膜.所制备的自清洁绝缘子样片在可见光的照射下,8h对甲基橙的降解率达到90%.TiO2/SiO2薄膜与水的接触角光照30min后从28.2°降至7.4°,该超亲水性能可维持2~3天.上述结果表明复合薄膜具有良好的光催化和自清洁性能,有利于有效减少污闪事故的发生.","authors":[{"authorName":"刘文秀","id":"5ffecd36-d591-45a8-a342-4c77b3e1f7cc","originalAuthorName":"刘文秀"},{"authorName":"全海芹","id":"46f224f4-a71a-4720-9b60-2286d5162e26","originalAuthorName":"全海芹"},{"authorName":"刘雪梅","id":"874ac5fa-b608-4b96-992d-accedd0275ff","originalAuthorName":"刘雪梅"},{"authorName":"","id":"62d711a1-ad13-437e-8d8d-9a399bd80c98","originalAuthorName":"曾艳萍"},{"authorName":"蔡文河","id":"0f0d200f-deb8-4a3f-8857-bafdf1026c98","originalAuthorName":"蔡文河"},{"authorName":"赵卫东","id":"5fc7762c-c111-4fc3-ae02-1962c9f8bea5","originalAuthorName":"赵卫东"},{"authorName":"曹文斌","id":"7d6a6be3-2b4b-43af-99e0-bef7636537e2","originalAuthorName":"曹文斌"}],"doi":"10.3969/j.issn.1001-4381.2014.03.008","fpage":"46","id":"d1984609-212c-4ee9-b15b-c7c9cba8bc40","issue":"3","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"d7893ffa-070a-46ab-9c01-c020a28ddd73","keyword":"自清洁","originalKeyword":"自清洁"},{"id":"0f7bcda3-8856-4fe0-9341-2f5e1795ebfb","keyword":"瓷绝缘子","originalKeyword":"瓷绝缘子"},{"id":"e6b0b8cf-15f7-4c23-8870-3f5c6e5178f0","keyword":"纳米N-TiO2溶胶","originalKeyword":"纳米N-TiO2溶胶"}],"language":"zh","publisherId":"clgc201403008","title":"可见光响应自清洁瓷绝缘子的制备及性能研究","volume":"","year":"2014"},{"abstractinfo":"以活性橙溶液为模拟废水,通过H2O2/TiO2超声(US)协同作用光降解活性橙溶液,探讨了TiO2催化剂用量、H2O2用量、活性橙溶液的初始浓度、pH值、TiO2催化剂锻烧温度等对活性橙溶液降解率的影响,并比较了几种不同作用方式对活性橙溶液的降解效果.结果表明:UV/H2O2/TiO2/US协同作用降解活性橙溶液的效果最好;当活性橙溶液的初始浓度为20 mg·L-1,pH=5,TiO2用量为0.4 g·L-1,H2O2用量为0.4 ml·L-1时,降解率可达92.06%.","authors":[{"authorName":"陈芳","id":"c018b667-4b1a-4338-b385-2d4c125d64b8","originalAuthorName":"陈芳"},{"authorName":"易回阳","id":"7008f390-2bc9-4a87-b6ed-71777a8de22a","originalAuthorName":"易回阳"},{"authorName":"吴一鸣","id":"bf3d8c22-2232-46d8-8102-d586676d01f0","originalAuthorName":"吴一鸣"}],"doi":"","fpage":"230","id":"b15922b8-beeb-4a39-9990-eeb51b375572","issue":"3","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学 "},"keywords":[{"id":"88a482ad-2c4f-4805-8a02-a613239277fb","keyword":"超声波","originalKeyword":"超声波"},{"id":"dc948252-a79c-4d4a-9236-5ae4192b8f72","keyword":"TiO2","originalKeyword":"TiO2"},{"id":"d7b25bb4-ef3f-4423-a23b-6a3ab0c3ac88","keyword":"协同作用","originalKeyword":"协同作用"},{"id":"b41f2468-584b-4018-ac2c-90b0366a1c28","keyword":"活性橙","originalKeyword":"活性艳橙"},{"id":"510604c2-b4ac-4dd0-9b95-2ca3d2b4fc0b","keyword":"降解","originalKeyword":"降解"}],"language":"zh","publisherId":"ggkxyghx201003008","title":"H2O2/TiO2超声协同光降解活性橙的研究","volume":"28","year":"2010"},{"abstractinfo":"通过静态吸附实验方法,研究了有机改性凹凸棒石吸附活性蓝KN-R的动力学行为.研究结果表明:准二级动力学模型能很好地描述活性蓝KN-R在有机改性凹凸棒石上的动力学行为,平衡吸附量q2随着KN-R初始浓度、振荡速度、温度的增加而增加.有机改性凹凸棒石吸附活性蓝KN-R主要是外表面吸附,吸附活化能为39.2 kJ/mol,说明其为物理吸附、化学吸附综合作用的过程,其速率由化学过程与外扩散共同控制.","authors":[{"authorName":"张波","id":"f9714a14-4182-4326-b828-5048e81c1590","originalAuthorName":"张波"},{"authorName":"彭书传","id":"ee74e18c-2c8d-444d-b77e-7d7cc30a323f","originalAuthorName":"彭书传"},{"authorName":"王世亮","id":"2081aac6-56de-48dc-afb0-2a3156bf3ad2","originalAuthorName":"王世亮"},{"authorName":"张泽滨","id":"93899ca6-0450-415a-ace0-d2cad41cd09c","originalAuthorName":"张泽滨"},{"authorName":"吴敏伟","id":"7bd933ae-1226-4ef6-b7a1-c107f72d1daf","originalAuthorName":"吴敏伟"}],"doi":"","fpage":"122","id":"2ad6a218-c793-44a4-af6f-213768c81239","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"14b91fae-876a-4a73-aed5-77891101763e","keyword":"有机改性","originalKeyword":"有机改性"},{"id":"1314339a-4fe8-4996-83a2-feff1221503c","keyword":"凹凸棒","originalKeyword":"凹凸棒"},{"id":"35569aab-9a77-4074-b7c3-dbfeb611ffe3","keyword":"吸附","originalKeyword":"吸附"},{"id":"acbdf65e-ed32-4155-a86c-5a7cc298153f","keyword":"活性蓝KN-R","originalKeyword":"活性艳蓝KN-R"},{"id":"6d9a6b9d-9b2e-48a1-bd3d-bd6a2a787f27","keyword":"动力学","originalKeyword":"动力学"}],"language":"zh","publisherId":"cldb201304031","title":"有机改性凹凸棒石吸附活性蓝KN-R的动力学研究","volume":"27","year":"2013"},{"abstractinfo":"采用湿相转化法制备了以活性蓝KN-R为印迹分子的醋酸纤维素(CA)-聚偏二氟乙烯(PVDF)分子印迹膜(MIM).实验结果表明在一定的制备条件下可制得具有较大吸附结合率的MIM,此时的铸膜液组成为:活性蓝KN-R质量浓度硼ω1为0.1%,共混组成比ω(CA):ω(PVDF)=9.5:0.5,聚合物质量浓度ωp,为14%,添加剂LiCl质量浓度ωa为7.5%.所制得的MIM是一种特异分子吸附膜,对印迹分子具有亲和性,其分离机理属于延迟渗透机理.在一定范围(0~0.1%)内,随着印迹分子活性蓝KN-R质量浓度增大,MIM的吸附选择性提高.由吸附焓△H0及MIM与印迹分子间结合力强弱的测定结果可知,MIM与印迹分子之间的结合作用力以疏水/范德华力与氢键作用为主.","authors":[{"authorName":"李婧娴","id":"adc39f6d-454c-4444-b471-9abaf319eb20","originalAuthorName":"李婧娴"},{"authorName":"董声雄","id":"974c9bac-83ba-4efc-8746-ddffb5b2a98e","originalAuthorName":"董声雄"},{"authorName":"苗晶","id":"40757d46-48bb-449f-a6f5-b995922abdcb","originalAuthorName":"苗晶"}],"doi":"10.3969/j.issn.1007-8924.2009.01.002","fpage":"8","id":"00fd3ec0-448e-4ff2-a4bf-8e3a505411fa","issue":"1","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"ab540a8e-4a22-4c27-9032-8794df61b554","keyword":"湿相转化法","originalKeyword":"湿相转化法"},{"id":"f919dd35-564c-46a0-8918-ae39230d5374","keyword":"活性蓝KN-R","originalKeyword":"活性艳蓝KN-R"},{"id":"034d028a-41f9-48db-b3e0-c9cfdc9d8c26","keyword":"分子印迹膜(MIM)","originalKeyword":"分子印迹膜(MIM)"},{"id":"f3c4f724-a1ba-4f6c-998c-93cc8914abec","keyword":"共混膜","originalKeyword":"共混膜"}],"language":"zh","publisherId":"mkxyjs200901002","title":"活性蓝KN-R分子印迹CA/PVDF共混膜的制备及性能表征","volume":"29","year":"2009"},{"abstractinfo":"采用溶胶-凝胶法制备了不掺杂和掺杂铝离子、镧离子以及两种离子共掺杂的ZnO,并用X射线衍射(XRD),高分辨透射电镜(HRTEM),紫外-可见(UV-Vis)吸收光谱对其进行了表征.用紫外灯作为光源,一定浓度的活性蓝X-BR溶液为光催化反应模型污染物,研究了各种离子掺杂ZnO的光催化性能,考察了掺杂量对降解率的影响.结果表明,镧离子和铝离子掺杂浓度为2 at%和3 at%的共搀杂ZnO的光催化性能最好;在室温下,加入催化剂浓度为0.1 g/L,降解时间为45 min时,对活性蓝X-BR溶液的降解率达到96.63%.","authors":[{"authorName":"周银","id":"490f2150-e783-47a1-8704-d2f879571574","originalAuthorName":"周银"},{"authorName":"王宇","id":"9889757b-2987-4b5e-83bb-e106ffd7f6a1","originalAuthorName":"王宇"},{"authorName":"卢士香","id":"8f1b321e-def4-42df-9c69-db5772180c51","originalAuthorName":"卢士香"},{"authorName":"徐文国","id":"3d5fd658-3b2e-4813-b421-3c76f27b6af4","originalAuthorName":"徐文国"},{"authorName":"苏苏","id":"a70d8526-7852-4b5e-883c-6555b9987294","originalAuthorName":"苏苏"}],"doi":"","fpage":"998","id":"6ec05008-600c-430c-90c0-d112e4b2ec7d","issue":"4","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"e960863a-1c4b-48e3-9edd-d7d235e981ea","keyword":"溶胶-凝胶","originalKeyword":"溶胶-凝胶"},{"id":"eac95f4b-6141-422d-bc5f-f6bcf0341d93","keyword":"纳米氧化锌","originalKeyword":"纳米氧化锌"},{"id":"3cc63b6d-1577-4565-bd8c-a1ef019394f0","keyword":"光催化降解","originalKeyword":"光催化降解"},{"id":"7b88e351-38b3-48ee-96b5-d6da24950946","keyword":"镧铝共掺杂","originalKeyword":"镧铝共掺杂"}],"language":"zh","publisherId":"rgjtxb98200904041","title":"La3+,Al3+共掺杂纳米ZnO光催化降解活性蓝X-BR研究","volume":"38","year":"2009"},{"abstractinfo":"按nAl2O3:nSiO2∶ nNaO∶ nH2O=1∶14∶ 6∶250的摩尔比,100℃10 h水热合成出微孔NaY分子筛,按n(SiO2)∶n(CTAB)∶n(H2O)=0.6∶1∶30的摩尔比配制成MCM48的溶胶液,再将NaY混合到MCM-48的晶化液中,110℃晶化72 h后取出漂洗烘干,再在550℃焙烧去除有机模板剂,获得NaY/MCM-48微介孔复合分子筛,采用XRD、SEM和TEM等手段对合成分子筛进行了表征.考查了分子筛的投加量、pH值、温度、吸附时间等对吸附活性兰KN-R染料废水脱色率的影响,研究了三种分子筛对活性兰的吸附等温线,吸附动力学和热力学.研究结果表明:NaY/MCM-48微介孔复合分子筛,对活性兰KN-R的吸附效果较好,当NaY/MCM-41微介孔复合分子筛的投加量为0.3 g/L、活性兰KN-R染料浓度20 mg/L,溶液pH =4、吸附时间为60 min,温度为55℃时吸附结果最好,脱色率以达到了96.6%.这三种分子筛可用Langmuir和Freundlich等温吸附方程描述,其中NaY,MCM-48分子筛与Freundlich等温吸附方程具有更好的相关性,而NaY/MCM--48复合分子筛与Langmuir等温吸附方程具有更好的相关性;拟二级吸附动力学反应模型与实验数据之间有更好的相关性,可以用方程lnK=-△H/RT+ lnCe来进行拟合.","authors":[{"authorName":"李聪","id":"18e0a899-6716-41af-b8d8-c5ff5deb4cbf","originalAuthorName":"李聪"},{"authorName":"成岳","id":"e7cd3727-367d-4252-9de4-9656d06f6012","originalAuthorName":"成岳"},{"authorName":"马朝云","id":"09a6b6a3-6937-4239-b563-2ed76cf9f14c","originalAuthorName":"马朝云"},{"authorName":"刘宇","id":"c5fef559-8e92-412f-b0f4-99dc3f269a96","originalAuthorName":"刘宇"}],"doi":"","fpage":"529","id":"fcd42162-ef1b-49cc-bc91-0570774256c1","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"27869a04-69bc-4d7b-b98a-ca219eee6f01","keyword":"NaY/MCM-48复合分子筛","originalKeyword":"NaY/MCM-48复合分子筛"},{"id":"72742597-8f43-4e20-b6f2-308cbd02cc00","keyword":"活性兰KN-R染料","originalKeyword":"活性艳兰KN-R染料"},{"id":"b1dcc73c-02ba-43c1-881d-3e0867e147b2","keyword":"脱色率","originalKeyword":"脱色率"},{"id":"d5f98ce5-4693-4186-b9e8-46315ec4a2fa","keyword":"吸附等温线","originalKeyword":"吸附等温线"},{"id":"8127dcbe-bc00-4859-a26c-84d967d5ac35","keyword":"动力学和热力学","originalKeyword":"动力学和热力学"}],"language":"zh","publisherId":"gsytb201602035","title":"NaY/MCM-48复合分子筛的制备及对活性兰KN-R染料的吸附性能研究","volume":"35","year":"2016"},{"abstractinfo":"","authors":[{"authorName":"李安邦","id":"ce1f96e7-c37f-4a0f-82ab-d42f3e4d3545","originalAuthorName":"李安邦"},{"authorName":"迟伟东","id":"86855a3d-18c4-40fe-a410-957c2cf7a6f0","originalAuthorName":"迟伟东"}],"doi":"10.3969/j.issn.1007-8827.2003.03.014","fpage":"239","id":"75917a9d-2ddb-42dd-bac4-859b8fea5fa5","issue":"3","journal":{"abbrevTitle":"XXTCL","coverImgSrc":"journal/img/cover/XXTCL.jpg","id":"70","issnPpub":"1007-8827","publisherId":"XXTCL","title":"新型炭材料"},"keywords":[{"id":"ef81413a-bb80-4088-864e-d24aa4cb0a3d","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"xxtcl200303014","title":"沈民教授和她的科研活动","volume":"18","year":"2003"},{"abstractinfo":"李维格先生是近代中国的政治家、实业家和教育家,倡导推进戊戌变法、创办汉冶有限公司,主持上海交通大学工作,还捐出巨额家产支持中国的高等教育事业.在冶金方面,他多次出国考察,改进炼钢设备,注重培养中国工程技术人员,创办了最早的冶金职业专门学校,并大胆改革钢铁企业用人和管理制度,是近代中国冶金业伟大的拓荒者和奠基人,为中国钢铁冶炼的近代化和民族工程技术人员的培育做出了重要贡献.","authors":[{"authorName":"王同起","id":"f18fa3d2-a890-403a-9d84-3e712418ba0f","originalAuthorName":"王同起"}],"doi":"10.3969/j.issn.1006-9356.2008.12.011","fpage":"48","id":"4633d2b0-0d88-4f96-9f06-22d53243d05e","issue":"12","journal":{"abbrevTitle":"ZGYJ","coverImgSrc":"journal/img/cover/ZGYJ.jpg","id":"87","issnPpub":"1006-9356","publisherId":"ZGYJ","title":"中国冶金"},"keywords":[{"id":"00d4ecf1-67d3-44ce-9070-1a5646ae7173","keyword":"李维格","originalKeyword":"李维格"},{"id":"31ab5e2c-cf63-496d-a84f-e2b253095d6c","keyword":"钢铁","originalKeyword":"钢铁"},{"id":"9201d38d-f8c6-4587-8614-8aae45f1bbb1","keyword":"拓荒","originalKeyword":"拓荒"}],"language":"zh","publisherId":"zgyj200812011","title":"拓荒钢铁情系中华——记近代中国钢铁工业的奠基者李维格先生","volume":"18","year":"2008"},{"abstractinfo":"采用聚丙烯强碱阴离子交换纤维对活性黄等几种活性染料进行静态吸附、动态吸附和再生实验,并与同类型树脂相比较.结果表明,强碱阴离子交换纤维对活性黄的吸附曲线符合Langmuer等温方程,吸附反应以液膜扩散为主,反应速率随温度和pH值的升高而增加,并且远大于树脂的吸附反应速率.动态吸附表明,强碱阴离子交换纤维对活性蓝、活性黄和活性艳红的吸附处理量依次增大.利用硝酸乙醇混合溶液再生,再生效率85.7%,纤维能够反复多次使用,可以作为活性染料废水的脱色剂使用.","authors":[{"authorName":"冯长根","id":"139ae5fb-07b7-41c8-b194-100aa7cb833b","originalAuthorName":"冯长根"},{"authorName":"李鑫","id":"9ab33fc1-3bb5-42a9-b36d-74354a192a49","originalAuthorName":"李鑫"},{"authorName":"庆轩","id":"a5bbd19b-5c41-4713-a4b3-007fcb51244d","originalAuthorName":"曾庆轩"},{"authorName":"周绍箕","id":"16820108-087c-4ba6-8c83-f3fd26bc8387","originalAuthorName":"周绍箕"}],"doi":"","fpage":"1568","id":"59111e29-3e2b-4eca-96aa-3c8d594c8f10","issue":"10","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"34297f00-85e5-4feb-9721-d76c6e1ebecb","keyword":"离子交换纤维","originalKeyword":"离子交换纤维"},{"id":"1c5c7c98-0195-4878-8d3e-12e94fef79ff","keyword":"活性染料","originalKeyword":"活性染料"},{"id":"6cb12977-7596-4bef-b1d4-4d871f55cb3d","keyword":"吸附","originalKeyword":"吸附"},{"id":"86001186-2607-432b-8f34-7e8fb64a3146","keyword":"脱色","originalKeyword":"脱色"}],"language":"zh","publisherId":"gncl200510027","title":"强碱阴离子交换纤维对活性染料的吸附性能研究","volume":"36","year":"2005"},{"abstractinfo":"以四丙基溴化铵(TPABr)为模板剂合成ZSM-5分子筛并采用XRD、SEM进行了表征,研究ZSM-5分子筛、铁屑和铁屑/ZSM-5分子筛对染料废水的处理效果,分别考察了染料废水浓度、pH、反应时间、ZSM-5分子筛和铁屑投加量对活性兰KN-R染料废水脱色的影响.研究结果表明:铁屑/ZSM-5分子筛联合处理染料废水的效果优于单独使用铁屑和ZSM-5分子筛;在铁屑投加量50 g/L,ZSM-5分子筛投加量为4 g/L,pH值为6,反应60 min条件下,活性兰染料废水的脱色率可达到99.05%.","authors":[{"authorName":"南小英","id":"c6b62b11-bccc-4625-a971-2609e3dc1904","originalAuthorName":"南小英"},{"authorName":"成岳","id":"8364da64-1c8c-441b-a814-327c8a809e73","originalAuthorName":"成岳"},{"authorName":"徐风琴","id":"24d8b227-2418-4401-83eb-edaeb9a4aadc","originalAuthorName":"徐风琴"}],"doi":"","fpage":"1393","id":"e428594d-22b5-4588-b5a6-08c1a6429f4c","issue":"6","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"fe10e293-cbe6-461c-87ce-d4a753d2e479","keyword":"ZSM-5分子筛","originalKeyword":"ZSM-5分子筛"},{"id":"355ac192-11ca-4ff8-b2ab-b7a45276077c","keyword":"铁屑","originalKeyword":"铁屑"},{"id":"aa7ccf12-74ae-4285-9dea-b93afde08e49","keyword":"活性兰KN-R","originalKeyword":"活性艳兰KN-R"},{"id":"02a905a2-97f8-4096-9b3b-9f936e5f7649","keyword":"染料废水","originalKeyword":"染料废水"},{"id":"bc38be4a-e353-4219-adc7-bd59abca68ef","keyword":"脱色率","originalKeyword":"脱色率"}],"language":"zh","publisherId":"gsytb201206011","title":"铁屑/ZSM-5分子筛联合处理染料废水的试验研究","volume":"31","year":"2012"}],"totalpage":14,"totalrecord":133}