{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以对乙基苯酚为起始反应物,采用<span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span>基保护其酚羟基,经过α-溴代反应和β-消除反应,得目标产物<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>(PTBOCS).制备过程中,中间产物<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙</span>烷和1-溴-1-(p-<span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span>)苯基乙烷的产率分别为98％和65％,目标产物PTBOCS的产率为60％.该法反应条件相对温和,分离效率高.<span style=\"color:red\">对</span>中间产物和目标产物进行了FTIR和1H NMR表征,并确认了它们的结构.","authors":[{"authorName":"刘建国","id":"f8f5456c-d062-4041-9c69-79bba4138481","originalAuthorName":"刘建国"},{"authorName":"李平","id":"8a317128-a45f-49ae-b650-de80017b4b21","originalAuthorName":"李平"},{"authorName":"刘和平","id":"bdea84f0-7830-45a2-884c-c70c16cca618","originalAuthorName":"刘和平"},{"authorName":"李萍","id":"3d6a2b53-e197-44bc-8f1a-35c2045f8562","originalAuthorName":"李萍"},{"authorName":"郑家燊","id":"91dcc6be-8e06-46fd-a7e7-61dbfb9be188","originalAuthorName":"郑家燊"},{"authorName":"张晓红","id":"3e65dc91-c075-4046-a47b-3d23e01b771f","originalAuthorName":"张晓红"}],"doi":"10.3969/j.issn.1000-0518.2008.04.010","fpage":"424","id":"cffc3b32-0c0a-4df2-ad5f-3d21ee4e8c33","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"83fbff5f-b037-47a7-96b6-4c5a363d2cdc","keyword":"<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>","originalKeyword":"对特丁氧酰氧基苯乙烯"},{"id":"6b055b3a-2d86-4964-94c6-77b3bcc4ae7b","keyword":"α-溴代反应","originalKeyword":"α-溴代反应"},{"id":"98c48a2e-e40c-40b1-8176-f41804a04027","keyword":"β-消除反应","originalKeyword":"β-消除反应"}],"language":"zh","publisherId":"yyhx200804010","title":"<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>的制备新方法","volume":"25","year":"2008"},{"abstractinfo":"通过改进反应溶剂,用Wittig反应合成了<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>,以中性Al2O3为固定相,正己烷为流动相,采用普通液相色谱分离提纯了混合产物,改进简化了分离方法.结果表明,所得目标产物<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>纯度达99%以上,产率为60%～70%,中间产物<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span>苯甲醛可以定量合成,反应的副产物主要是三苯基氧化膦.<span style=\"color:red\">对</span>目标产物、中间产物和一些反应副产物进行了红外和核磁共振分析.","authors":[{"authorName":"刘建国","id":"5c15a577-b6f0-45cb-b35a-4b132c10802f","originalAuthorName":"刘建国"},{"authorName":"李平","id":"d4127bcc-6619-479f-89e6-f8f212d6aee6","originalAuthorName":"李平"},{"authorName":"李萍","id":"e7f45ea7-b993-4752-9d9b-8d872c7be252","originalAuthorName":"李萍"},{"authorName":"郑家燊","id":"134e70e8-77a3-41b0-9129-1f41be552640","originalAuthorName":"郑家燊"}],"doi":"10.3969/j.issn.1000-0518.2007.03.027","fpage":"361","id":"f14d63bc-ee0c-48ba-8f7a-870ea1010ffe","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"81873284-4bb8-4ce5-befb-31ff6cf8d2be","keyword":"光致抗蚀剂","originalKeyword":"光致抗蚀剂"},{"id":"3ca30e4f-f458-4b9b-9d05-06a228b41124","keyword":"聚<span style=\"color:red\">对</span>羟基<span style=\"color:red\">苯乙烯</span>","originalKeyword":"聚对羟基苯乙烯"},{"id":"eb121513-0ece-4974-81de-e7080bb5e333","keyword":"<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>","originalKeyword":"对特丁氧酰氧基苯乙烯"}],"language":"zh","publisherId":"yyhx200703027","title":"聚<span style=\"color:red\">对</span>羟基<span style=\"color:red\">苯乙烯</span>单体的中间体——<span style=\"color:red\">对</span><span style=\"color:red\">特</span><span style=\"color:red\">丁</span><span style=\"color:red\">氧</span><span style=\"color:red\">酰</span><span style=\"color:red\">氧基</span><span style=\"color:red\">苯乙烯</span>合成方法的改进","volume":"24","year":"2007"},{"abstractinfo":"添加三异<span style=\"color:red\">丁</span><span style=\"color:red\">氧基</span>钬的<span style=\"color:red\">苯乙烯</span>经本体聚合制备了掺钬聚<span style=\"color:red\">苯乙烯</span>新材料. 用FT-IR、XPS、SEM、DTA-TG和DMTA等分析技术研究了钬<span style=\"color:red\">对</span>PS性能的影响,并测定了掺杂物的冲击强度. 结果表明,掺钬聚<span style=\"color:red\">苯乙烯</span>中存在着Ho与苯环π电子之间的配位作用,掺钬聚<span style=\"color:red\">苯乙烯</span>的热稳定性随着钬含量的增加而提高,其冲击强度有明显提高,并在钬的质量分数为5.0%时达最高值,SEM和DMTA分析从微观上解释了稀土钬<span style=\"color:red\">对</span>聚<span style=\"color:red\">苯乙烯</span>的增韧机理.","authors":[{"authorName":"王文","id":"b9aba603-7abc-46de-88a0-ecfd0af1dfa8","originalAuthorName":"王文"},{"authorName":"章文贡","id":"91a824d6-f0eb-488c-a07c-36e5bb5a5a1b","originalAuthorName":"章文贡"},{"authorName":"林美娟","id":"0cf8648d-6bb7-4fda-8699-a8f6aa96d327","originalAuthorName":"林美娟"}],"doi":"10.3969/j.issn.1000-0518.2002.12.006","fpage":"1146","id":"dd6017ef-0c84-44be-a40f-66beb4a327ea","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"48d8f9b3-c35e-4024-83d6-1622e334d570","keyword":"聚<span style=\"color:red\">苯乙烯</span>","originalKeyword":"聚苯乙烯"},{"id":"c3f79476-b8ed-403f-9d44-49c1a20d280c","keyword":"掺杂","originalKeyword":"掺杂"},{"id":"7d5c51fb-1439-434c-a67f-bf47dc1d6867","keyword":"增韧性","originalKeyword":"增韧性"}],"language":"zh","publisherId":"yyhx200212006","title":"掺三异<span style=\"color:red\">丁</span><span style=\"color:red\">氧基</span>钬聚<span style=\"color:red\">苯乙烯</span>的性能","volume":"19","year":"2002"},{"abstractinfo":"以AIBN为引发剂在氯仿溶剂中成功地合成了耐热型聚<span style=\"color:red\">苯乙烯</span>-<span style=\"color:red\">苯乙烯</span>/N-(α-甲基-<span style=\"color:red\">丁</span>酯基)-马来<span style=\"color:red\">酰</span>亚胺共聚物(St-co-BAM).通过IR、TG、DTA<span style=\"color:red\">对</span>共聚物的表征,研究了其耐热性能;讨论了单体全程配比、温度、引发剂浓度<span style=\"color:red\">对</span>共聚合初始速率的影响,测得共聚合总活化能Ea＝76.2 kJ/mol,共聚合增长活化能Ep=13.4 kJ/mol,比一般的正常<span style=\"color:red\">乙烯</span>基单体Ep值小.","authors":[{"authorName":"艾娇艳","id":"5cbc1f45-587d-4d9b-9abe-39c5d87b3475","originalAuthorName":"艾娇艳"},{"authorName":"刘朋生","id":"f1c7d848-56f4-419d-a0f2-0b0ec70ec1fd","originalAuthorName":"刘朋生"},{"authorName":"周述璋","id":"50ed3260-9e67-4643-aac5-a2993297e81b","originalAuthorName":"周述璋"}],"doi":"","fpage":"196","id":"19d4e784-21f5-4b0e-9acd-71b5e00bb053","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"41089f60-90a2-4bce-8629-3710b34e78b4","keyword":"N-(α-甲基-<span style=\"color:red\">丁</span>酯基)-马来<span style=\"color:red\">酰</span>亚胺","originalKeyword":"N-(α-甲基-丁酯基)-马来酰亚胺"},{"id":"7acc52af-47fc-4204-978e-85255762c276","keyword":"耐热型聚<span style=\"color:red\">苯乙烯</span>","originalKeyword":"耐热型聚苯乙烯"},{"id":"8dce5c23-4f8d-4423-9bb1-5efd241789d9","keyword":"自由基共聚","originalKeyword":"自由基共聚"}],"language":"zh","publisherId":"gfzclkxygc200203050","title":"N-(α-甲基-<span style=\"color:red\">丁</span>酯基)-马来<span style=\"color:red\">酰</span>亚胺/<span style=\"color:red\">苯乙烯</span>共聚合研究","volume":"18","year":"2002"},{"abstractinfo":"通过原位本体聚合制备三种不同链长的烷<span style=\"color:red\">氧基</span>(异丙<span style=\"color:red\">氧基</span>、异<span style=\"color:red\">丁</span><span style=\"color:red\">氧基</span>、异辛<span style=\"color:red\">氧基</span>)混合稀土掺杂的改性聚<span style=\"color:red\">苯乙烯</span>.研究了烷<span style=\"color:red\">氧</span>稀土改性聚<span style=\"color:red\">苯乙烯</span>的动态力学性能,并测定其冲击强度.结果表明,三种烷<span style=\"color:red\">氧</span>稀土掺杂的改性聚<span style=\"color:red\">苯乙烯</span>均在低温-80 ℃左右出现一个大的β转变峰,且低温损耗模量峰的模量均比PS高一个数量级,表明改性聚<span style=\"color:red\">苯乙烯</span>具有较好的抗冲性能,其中三异<span style=\"color:red\">丁</span><span style=\"color:red\">氧基</span>稀土掺杂的聚<span style=\"color:red\">苯乙烯</span>的冲击强度最高.","authors":[{"authorName":"章文贡","id":"9b7b261b-a02e-4306-a88f-6f329253120c","originalAuthorName":"章文贡"},{"authorName":"林美娟","id":"13c0c44d-748d-4e63-a52e-2befd592aa4e","originalAuthorName":"林美娟"},{"authorName":"王文","id":"19167068-b995-40af-b154-db406013d9d3","originalAuthorName":"王文"}],"doi":"","fpage":"220","id":"d29097b1-7f85-4bee-abbb-6074fddf7147","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"73d082e3-0505-4463-a54c-2378ef2b275b","keyword":"烷<span style=\"color:red\">氧</span>混合稀土","originalKeyword":"烷氧混合稀土"},{"id":"3a420e0d-4dae-4c78-a988-62ffd2302b8d","keyword":"掺杂改性","originalKeyword":"掺杂改性"},{"id":"46c240c2-e039-4803-a95b-2bc076809d62","keyword":"聚<span style=\"color:red\">苯乙烯</span>","originalKeyword":"聚苯乙烯"},{"id":"2f27feba-0bd8-4414-9e71-959ff81b9e22","keyword":"抗冲性能","originalKeyword":"抗冲性能"}],"language":"zh","publisherId":"gfzclkxygc200303056","title":"烷<span style=\"color:red\">氧</span>混合稀土掺杂改性<span style=\"color:red\">对</span>聚<span style=\"color:red\">苯乙烯</span>抗冲性能的影响","volume":"19","year":"2003"},{"abstractinfo":"以十二烷基硫酸钠/十二烷基苯磺酸钠为乳化剂,过氧化苯甲<span style=\"color:red\">酰</span>为引发剂进行了<span style=\"color:red\">苯乙烯</span>/丙烯酸<span style=\"color:red\">丁</span>酯微乳液共聚合反应.研究了引发剂浓度[I]、单体总浓度[M]、乳化剂含量CE和聚合温度T<span style=\"color:red\">对</span>微乳液共聚合的最大聚合速率Rmax和共聚物粘均分子量η的影响,测定了共聚单体的竞聚率,结果得到Rmax∝[I]0.90[M]1.49C 0.73E exp(-6116/T),η∝[I]-1.60[M]-1.22C -1.43E exp(3496/T);r St= 0.55,r BA= 0.23.","authors":[{"authorName":"李雪艳","id":"35089f11-3ad9-4e3a-bbd9-63969766e7f4","originalAuthorName":"李雪艳"},{"authorName":"王德松","id":"96f7375a-48ac-4b48-a089-1e184f3b7c21","originalAuthorName":"王德松"},{"authorName":"安静","id":"b3a683b9-4761-48b3-8991-301cbdc8e90b","originalAuthorName":"安静"},{"authorName":"朱学旺","id":"a3cf646e-def7-400c-a630-8cd48b68451b","originalAuthorName":"朱学旺"},{"authorName":"殷蓉","id":"9e87d5fc-0e79-48d1-bd30-ca3bc3d32c0a","originalAuthorName":"殷蓉"},{"authorName":"罗青枝","id":"c87fd0f8-23a2-40e9-8a6f-61e46309f0ab","originalAuthorName":"罗青枝"},{"authorName":"李发堂","id":"facbd225-0817-43f1-9aa9-4d6e98d0a6b3","originalAuthorName":"李发堂"}],"doi":"","fpage":"100","id":"0f1bf0bb-568d-49c6-ae99-382d4e83174e","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"1928b2c4-dc7f-44ac-8d80-e63c96f651a9","keyword":"<span style=\"color:red\">苯乙烯</span>","originalKeyword":"苯乙烯"},{"id":"92cf7c3f-8cb8-41cc-a4ee-30f29ea83161","keyword":"丙烯酸<span style=\"color:red\">丁</span>酯","originalKeyword":"丙烯酸丁酯"},{"id":"bbac9ee9-30ed-4bad-8e1b-7db5a1cade1c","keyword":"微乳液共聚","originalKeyword":"微乳液共聚"},{"id":"87347992-3683-4da1-aa30-fbdc694a2745","keyword":"竞聚率","originalKeyword":"竞聚率"}],"language":"zh","publisherId":"gfzclkxygc200306025","title":"过氧化苯甲<span style=\"color:red\">酰</span>引发<span style=\"color:red\">苯乙烯</span>/丙烯酸<span style=\"color:red\">丁</span>酯微乳液共聚合","volume":"19","year":"2003"},{"abstractinfo":"以偶氮二异<span style=\"color:red\">丁</span>腈作引发剂,N-(1-萘基)马来<span style=\"color:red\">酰</span>亚胺和<span style=\"color:red\">苯乙烯</span>为原料,采用溶液聚合法合成了N-(1-萘基)马来<span style=\"color:red\">酰</span>亚胺/<span style=\"color:red\">苯乙烯</span>共聚物,分析了原料配比、不同溶剂、引发剂用量、反应时间等工艺条件<span style=\"color:red\">对</span>聚合反应体系的影响.采用傅立叶红外FT-IR、热失重分析法(TG)等<span style=\"color:red\">对</span>聚合物的结构和性质进行了表征.结果表明,随着共聚物中N-(1-萘基)马来<span style=\"color:red\">酰</span>亚胺含量的增加,共聚物的耐热性也获得提高.","authors":[{"authorName":"王国祥","id":"e2a622d2-de41-4998-8469-a57c69d57a6e","originalAuthorName":"王国祥"},{"authorName":"陈钱","id":"2960cc53-0dc1-446c-ba25-0dc4e41abfbd","originalAuthorName":"陈钱"},{"authorName":"何斌鸿","id":"37385c12-1806-4a65-84ce-a8566ae85ca7","originalAuthorName":"何斌鸿"}],"doi":"10.3969/j.issn.1009-9239.2008.05.004","fpage":"15","id":"3550d287-223e-4b8e-8e68-52b44a3a0d59","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"58def633-c7d0-4d0a-a3f9-a60305c1f4e6","keyword":"N-(1-萘基)马来<span style=\"color:red\">酰</span>亚胺","originalKeyword":"N-(1-萘基)马来酰亚胺"},{"id":"f4f7a20f-879f-4030-acb0-a3dd6b70b999","keyword":"合成","originalKeyword":"合成"},{"id":"69dbcc81-34a8-4b98-9bbc-19e7d21ed619","keyword":"表征","originalKeyword":"表征"},{"id":"0670324f-3757-420b-b21b-280fb3e01dfd","keyword":"工艺条件","originalKeyword":"工艺条件"}],"language":"zh","publisherId":"jycltx200805004","title":"N-(1-萘基)马来<span style=\"color:red\">酰</span>亚胺/<span style=\"color:red\">苯乙烯</span>共聚合研究","volume":"41","year":"2008"},{"abstractinfo":"研究了1,1,2-三取代烯类单体N-环己基糠柠<span style=\"color:red\">酰</span>亚胺(ChCⅠ) 与<span style=\"color:red\">苯乙烯</span>共聚物的合成及其耐热性.当投料中<span style=\"color:red\">苯乙烯</span>为主时,共聚物最高转化率组成糠柠<span style=\"color:red\">酰</span>亚胺单元含量高于其投料组成,而当投料<span style=\"color:red\">苯乙烯</span>组成较低时,糠柠<span style=\"color:red\">酰</span>亚胺单元含量变成低于其投料组成,可归结为单体ChCⅠ的电子效应或空阻效应的影响.共聚物玻璃化温度明显高于聚<span style=\"color:red\">苯乙烯</span>,随共聚单体ChCⅠ组成增加而提高,热降解温度也明显提高.还讨论了依糠酸酐在环己胺作用下形成N-环己基糠柠<span style=\"color:red\">酰</span>亚胺的异构化反应.","authors":[{"authorName":"董建华","id":"ac04ec4f-5ac8-40a0-964d-2baf1a1d8a71","originalAuthorName":"董建华"},{"authorName":"陈倩","id":"bd583356-d278-447a-b803-1b3453f058e0","originalAuthorName":"陈倩"}],"doi":"","fpage":"75","id":"05d9ad1c-d087-406e-af89-4fad87f982bb","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"06c97a5a-67bf-4eec-a407-371f555be5c4","keyword":"N-环己基糠柠<span style=\"color:red\">酰</span>亚胺","originalKeyword":"N-环己基糠柠酰亚胺"},{"id":"7d8a835c-b7c1-40d5-85c3-283f480cc82e","keyword":"耐热聚<span style=\"color:red\">苯乙烯</span>","originalKeyword":"耐热聚苯乙烯"},{"id":"c70e1e6c-273f-4e46-b7d4-4c3b5757ca38","keyword":"自由基共聚合","originalKeyword":"自由基共聚合"}],"language":"zh","publisherId":"gfzclkxygc199903022","title":"新型耐热聚<span style=\"color:red\">苯乙烯</span>--N-环己基糠柠<span style=\"color:red\">酰</span>亚胺/<span style=\"color:red\">苯乙烯</span>共聚物","volume":"15","year":"1999"},{"abstractinfo":"以<span style=\"color:red\">苯乙烯</span>和丙烯酸<span style=\"color:red\">丁</span>酯为反应单体,聚<span style=\"color:red\">乙烯</span>吡咯烷酮为分散剂,偶氮二异<span style=\"color:red\">丁</span>腈为引发剂,乙醇/水为分散介质,采用分散聚合法制备了微米级<span style=\"color:red\">苯乙烯</span>/丙烯酸<span style=\"color:red\">丁</span>酯共聚微球,通过红外光谱、核磁共振氢谱和扫描电镜<span style=\"color:red\">对</span>产物进行了表征,并且<span style=\"color:red\">对</span>不同聚合条件下,产物微球的粒径和粒径分布进行了研究.结果表明,随着<span style=\"color:red\">苯乙烯</span>/丙烯酸<span style=\"color:red\">丁</span>酯比值增大,粒子平均粒径和分布都减小;分散剂用量增加,粒子平均粒径减小,分布变窄;增加引发剂用量或提高温度,粒子平均粒径增大,分布变宽;随着乙醇/水比值增大,粒子平均粒径增大,分布有个极小值.","authors":[{"authorName":"郑玉婴","id":"78670577-e019-4e7b-8f83-17f07a3a2062","originalAuthorName":"郑玉婴"},{"authorName":"玄泽亮","id":"e1d63f92-5a23-4893-b501-5fa8244d265b","originalAuthorName":"玄泽亮"},{"authorName":"张星","id":"02ae8c4c-2e34-4d26-9268-b85792bf7bd8","originalAuthorName":"张星"},{"authorName":"程雷","id":"6057b237-0aad-4035-9789-609d8a33dcc9","originalAuthorName":"程雷"}],"doi":"","fpage":"43","id":"e125e0f9-035e-461f-b415-50983d3eeca6","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7daff00c-1ac6-4ff7-8265-48089fb19355","keyword":"<span style=\"color:red\">苯乙烯</span>","originalKeyword":"苯乙烯"},{"id":"a96f3a47-35f7-4fae-928d-3076d162f296","keyword":"丙烯酸正<span style=\"color:red\">丁</span>酯","originalKeyword":"丙烯酸正丁酯"},{"id":"9a7968fc-8226-43b9-bf05-c6dd77e67ea2","keyword":"分散共聚合","originalKeyword":"分散共聚合"},{"id":"c7e893e1-dd6c-4b0a-889c-2f1028b8d25e","keyword":"单分散","originalKeyword":"单分散"}],"language":"zh","publisherId":"gfzclkxygc201101012","title":"单分散<span style=\"color:red\">苯乙烯</span>/丙烯酸<span style=\"color:red\">丁</span>酯共聚微球的制备","volume":"27","year":"2011"},{"abstractinfo":"以偶氮二异<span style=\"color:red\">丁</span>腈( AIBN)为引发剂,在 N,N 二甲基甲酰胺( DMF)中进行了 N 甘胺<span style=\"color:red\">酰</span>马来<span style=\"color:red\">酰</span>亚胺( M1)与<span style=\"color:red\">苯乙烯</span>( M2)的共聚合反应,采用元素分析仪<span style=\"color:red\">对</span>共聚合产物的组份进行分析,通过 Mayo Lewis方程、 Kelen Tudos方程、 Ezrielev Brokhina Roskin方程计算了共聚合反应竞聚率,得到 r1=0 066、 r2=0 093,同时计算了平均序列长度 L1 、 L2及序列分布,计算结果表明:( 1)随着 [M1]/[M2]的增加, L1增加, L2 减小;( 2) N 甘胺<span style=\"color:red\">酰</span>马来<span style=\"color:red\">酰</span>亚胺链段分布比<span style=\"color:red\">苯乙烯</span>链段分布更趋于短链.","authors":[{"authorName":"王国祥","id":"17262b41-e819-4143-bf78-bb772fe31f82","originalAuthorName":"王国祥"},{"authorName":"刘朋生","id":"d7b3a1f1-87bc-498f-9199-5a5f90a7d4d5","originalAuthorName":"刘朋生"}],"doi":"10.3969/j.issn.1009-9239.2004.01.011","fpage":"33","id":"fe3859d4-84d3-45fc-ab05-f379cac50428","issue":"1","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"49a26a77-426c-4f16-b29f-412b034cd147","keyword":"N 甘胺<span style=\"color:red\">酰</span>马来<span style=\"color:red\">酰</span>亚胺","originalKeyword":"N 甘胺酰马来酰亚胺"},{"id":"2a65a643-4f88-42f3-b938-e5cbcc0fee0e","keyword":"<span style=\"color:red\">苯乙烯</span>","originalKeyword":"苯乙烯"},{"id":"cfb81e55-8c2f-4b12-94e3-4569aa4cbd2d","keyword":"共聚合","originalKeyword":"共聚合"},{"id":"bb433557-6816-4ddd-be8b-f518479c8a68","keyword":"竞聚率","originalKeyword":"竞聚率"}],"language":"zh","publisherId":"jycltx200401011","title":"N-甘胺<span style=\"color:red\">酰</span>马来<span style=\"color:red\">酰</span>亚胺与<span style=\"color:red\">苯乙烯</span>反应动力学参数的研究","volume":"37","year":"2004"}],"totalpage":14515,"totalrecord":145148}