{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"将新制备的厚朴酚键合硅胶固定相( MSP)用于嘌呤、嘧啶、蝶呤及<span style=\"color:red\">黄酮</span>类化合物的液相色谱分离分析.选取了4种嘌呤、8种嘧啶、4种蝶呤及5种<span style=\"color:red\">黄酮</span>类药物作为极性化合物的代表,以商品反相碳十八烷基键合硅胶柱(ODS)作参照,研究了新固定相对碱性化合物的选择性和相关分离机理.实验发现,在简单流动相条件下,厚朴酚键合硅胶固定相对上述药物表现出较高的选择性及分离效果.,尽管MSP没有进行封尾处理,但含氮类极性化合物(嘌呤、嘧啶、蝶呤)仍表现出基本对称的色谱峰形.多数药物在两柱上的洗脱顺序大致相同,说明疏水作用始终存在,这说明新固定相具有反相色谱性能.比较研究还发现,MSP在分离上述极性药物时能够提供除疏水性作用之外的其他作用位点.例如,在分离嘌呤、嘧啶及蝶呤时,氢键和偶极作用明显存在;同时MSP与溶质结构中的芳环(硫唑嘌呤、紫花牡荆素)之间有较强的π-π电子相互作用等,使得含氮类极性化合物和<span style=\"color:red\">黄酮</span>的保留一般比ODS强,分离度也有一定的改善.多种作用可以合理地解释MSP柱对极性溶质有更强的分离能力,厚朴酚键合硅胶固定相可在一定程度上弥补ODS单一疏水作用的不足,有利于分类碱性化合物.","authors":[{"authorName":"陈红","id":"246364c9-b176-492d-8fcd-5e0277408923","originalAuthorName":"陈红"},{"authorName":"李来生","id":"d7e243fd-4d2c-4b63-b8d8-ebc5a02b6600","originalAuthorName":"李来生"},{"authorName":"张杨","id":"3105f529-1ba6-4349-8224-8dc73a4ec837","originalAuthorName":"张杨"},{"authorName":"周仁丹","id":"888dfc23-683a-4498-8a53-3f2a409ff113","originalAuthorName":"周仁丹"}],"doi":"10.3724/SP.J.1123.2012.06028","fpage":"1062","id":"c3779213-e6f4-4ca6-b2fd-10441ba469cb","issue":"10","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"2b292148-871b-4b77-83f4-3ee9b22d5183","keyword":"厚朴酚键合硅胶固定相","originalKeyword":"厚朴酚键合硅胶固定相"},{"id":"118c5ec5-99b3-43c5-baca-2acafe2bb522","keyword":"反相高效液相色谱","originalKeyword":"反相高效液相色谱"},{"id":"6a1ec366-0b35-4d1a-8970-2f2522d74e82","keyword":"嘌呤","originalKeyword":"嘌呤"},{"id":"df8b00d4-a2a6-4755-8e1d-f12e4dc95cbb","keyword":"嘧啶","originalKeyword":"嘧啶"},{"id":"6df5cbae-d567-4942-9ae7-9060b75bc13b","keyword":"蝶呤","originalKeyword":"蝶呤"},{"id":"93d55474-eb8e-44a0-a148-5c885620654a","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"38351595-32f7-48d5-91cf-6d26f81ab31c","keyword":"色谱保留机理","originalKeyword":"色谱保留机理"}],"language":"zh","publisherId":"sp201210015","title":"厚朴酚键合硅胶高效液相色谱固定相分离嘌呤、嘧啶、蝶呤及<span style=\"color:red\">黄酮</span>","volume":"30","year":"2012"},{"abstractinfo":"在高效液相色谱-质谱分析指导下,针对性地分离制备了黄芩药材中系列<span style=\"color:red\">黄酮</span>成分对照品.首先对黄芩药材乙醇提取物进行液相色谱-质谱分析,获得各色谱峰的保留时间、紫外光谱和质谱特征.经波谱数据解析结合文献对比,鉴定了黄芩药材中的19种<span style=\"color:red\">黄酮</span>类成分.然后根据液相色谱-质谱分析结果和文献,设计了目标成分对照品的制备流程,采用低压制备柱色谱法依次制备了黄芩苷、汉黄芩苷、黄芩素、汉黄芩素和千层纸素A共5种<span style=\"color:red\">黄酮</span>类成分的对照品.结果表明这5种<span style=\"color:red\">黄酮</span>类成分对照品的纯度均大于98％.该方法可用于针对性地快速分离制备中药中的化学成分.","authors":[{"authorName":"郭鹤男","id":"ce182eae-5215-464d-b51f-b2c2f4eab927","originalAuthorName":"郭鹤男"},{"authorName":"杨学东","id":"8dee4792-2461-4002-af0f-8dda7d01a963","originalAuthorName":"杨学东"},{"authorName":"刘军","id":"525ed13a-2d23-4219-a2cb-34a8c9052a0f","originalAuthorName":"刘军"},{"authorName":"郑文凤","id":"2ef98e8a-1e49-492b-af7f-a3b72f1db43f","originalAuthorName":"郑文凤"}],"doi":"10.3724/SP.J.1123.2012.02030","fpage":"690","id":"cb3ac60b-ea64-4432-832f-d73338289aa4","issue":"7","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"9cac12e6-e43d-4b8b-a308-3bffcea81afd","keyword":"高效液相色谱-质谱联用","originalKeyword":"高效液相色谱-质谱联用"},{"id":"40d4bd51-7506-4cee-8da1-bcfe713d731d","keyword":"黄芩","originalKeyword":"黄芩"},{"id":"a1c9e4fe-8192-43d6-a591-ee5ac9828daa","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"8af05eb0-ec64-4b73-9f9c-68c8421b1b53","keyword":"对照品","originalKeyword":"对照品"}],"language":"zh","publisherId":"sp201207008","title":"高效液相色谱-质谱分析指导下制备黄芩中系列<span style=\"color:red\">黄酮</span>成分对照品","volume":"30","year":"2012"},{"abstractinfo":"对千里光(Senecio scandens Buch.-Ham.)全草的乙酸乙酯提取部位进一步分离,得到4个<span style=\"color:red\">黄酮</span>类化合物和2个酚酸类化合物,经理化性质和NMR及MS谱学数据鉴定分别为槲皮素-3-O-β-D-葡萄糖苷(Ⅰ)、金丝桃苷(Ⅱ)、槲皮素(Ⅴ)、异鼠李素(Ⅵ)、绿原酸(Ⅲ)和咖啡酸(Ⅳ). 化合物Ⅰ～Ⅵ均为首次从千里光属植物中分离鉴定.","authors":[{"authorName":"何忠梅","id":"5c8239a0-b1d5-46d7-8051-674388123040","originalAuthorName":"何忠梅"},{"authorName":"宗颖","id":"d8682033-dffd-4c8b-bcfb-184dca59d71f","originalAuthorName":"宗颖"},{"authorName":"孙佳明","id":"d90a14c6-e687-40a8-95dc-ed0f153619a1","originalAuthorName":"孙佳明"},{"authorName":"肖凤艳","id":"77ca7400-fbff-4193-a249-e4dfc4631a3e","originalAuthorName":"肖凤艳"}],"doi":"10.3724/SP.J.1095.2010.00061","fpage":"1486","id":"fc447156-7fb0-403c-8090-fe8dcd70df7a","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"61804e88-635a-471e-b0df-be001132b628","keyword":"千里光","originalKeyword":"千里光"},{"id":"99bdfe61-968d-4ebe-a768-201e379578ae","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"0ddd789e-79b4-46ad-a659-b4c6fe831bcf","keyword":"酚酸","originalKeyword":"酚酸"},{"id":"5fe08cdc-e980-46b0-9508-727f5ff1f417","keyword":"分离","originalKeyword":"分离"},{"id":"585fca48-55f8-4e27-aebb-ac5a00680273","keyword":"鉴定","originalKeyword":"鉴定"}],"language":"zh","publisherId":"yyhx201012026","title":"千里光中几种<span style=\"color:red\">黄酮</span>和酚酸类成分的分离与鉴定","volume":"27","year":"2010"},{"abstractinfo":"采用均匀实验设计和信息理论评价方法,建立了鱼腥草中<span style=\"color:red\">黄酮</span>类成分的高效液相色谱(HPLC)指纹图谱的分析方法.采用建立的方法和本研究室提出的指纹图谱评价软件,对同样种植条件下10个批次的鱼腥草指纹图谱进行了相似性评价,相似度均大于0.90;同时测定了芦丁、槲皮甙和槲皮素3个成分在10批鱼腥草药材中的含量分别为0.25% ～0.34% 、0.27% ～0.37% 、0.012% ～0.016% .另外对不同采收季节和不同部位的鱼腥草药材中的<span style=\"color:red\">黄酮</span>类成分进行了指纹图谱的测定、主成分分析以及成分含量测定,结果表明,不同季节、不同部位的鱼腥草中<span style=\"color:red\">黄酮</span>类化合物的指纹图谱及成分含量存在较大的差异,且药用部位的差异大于采收季节的差异.该方法为规范鱼腥草中<span style=\"color:red\">黄酮</span>类成分在制药和用药的实际应用提供了一些可靠的基础信息.","authors":[{"authorName":"卢红梅","id":"cc267da6-3268-4253-b133-c9082bc2ea8c","originalAuthorName":"卢红梅"},{"authorName":"彭丽华","id":"a67601bd-3c08-4128-882a-a4850b1dc37c","originalAuthorName":"彭丽华"},{"authorName":"郭方遒","id":"cbdfdc82-2acb-4d72-9a28-e5d3505a5860","originalAuthorName":"郭方遒"},{"authorName":"伍贤进","id":"b9b69813-24da-40b4-a3c9-0cfa539c6f11","originalAuthorName":"伍贤进"},{"authorName":"梁逸曾","id":"6bf13e06-b6eb-42e2-8943-f434ee7b19c1","originalAuthorName":"梁逸曾"}],"doi":"10.3724/SP.J.1123.2010.00965","fpage":"965","id":"3be50db4-caf0-49ca-a2bb-4c4b78b63078","issue":"10","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"bcc5b50a-d980-4983-b5ee-96874ffad0f7","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"614279bc-5236-4b34-9945-881cb33669d9","keyword":"指纹图谱","originalKeyword":"指纹图谱"},{"id":"3cedce27-1151-4f1a-a65d-9376e1a2b49a","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"49cd69dd-87fa-4a6d-a204-9b491ffa29ed","keyword":"鱼腥草","originalKeyword":"鱼腥草"}],"language":"zh","publisherId":"sp201010011","title":"鱼腥草中<span style=\"color:red\">黄酮</span>类成分的高效液相色谱指纹图谱分析","volume":"28","year":"2010"},{"abstractinfo":"7-溴乙氧基<span style=\"color:red\">黄酮</span>与水杨醛固相反应得到7-邻甲醛基苯氧乙氧基<span style=\"color:red\">黄酮</span>,该化合物分别与N4-取代苯氨基脲类、N4-取代氨基硫脲类及取代苯亚氨基乙酰肼类化合物固相研磨反应得到3种类型共14个含水杨醛席夫碱结构的<span style=\"color:red\">黄酮</span>衍生物.用红外(IR)、核磁共振氢谱(1H NMR)、质谱(ESI-MS)及元素分析(EA)或高分辨质谱(HR-MS)等技术手段对化合物的结构进行了确证.比较测定了这些新化合物清除超氧自由基(O2-·)、羟自由基(·OH)和2,2-二苯基-1-苦味酰基自由基(DPPH·)的活性及总还原能力,并对化合物进行了抗菌活性测定,结果表明,在0.5 g/L浓度时,多数化合物具有抗氧化活性,表现出较好的抑菌活性,其中尤以化合物3b表现出与氯霉素相当的抗菌活性.","authors":[{"authorName":"段志芳","id":"9485f617-22df-474e-904f-add2e6355934","originalAuthorName":"段志芳"},{"authorName":"邵玲","id":"23f1a18b-4e2e-4493-be1a-4b3fcfffe6d1","originalAuthorName":"邵玲"}],"doi":"10.11944/j.issn.1000-0518.2015.09.150032","fpage":"1005","id":"910030cd-65f9-4ea8-ab9e-cee1169e1c41","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b62ff750-5ccb-4748-88ef-7535809d6644","keyword":"水杨醛席夫碱","originalKeyword":"水杨醛席夫碱"},{"id":"8189eba9-1899-482a-a4dd-a439879713a3","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"7ab15936-1a3c-472a-9a51-9fc83d43a2c6","keyword":"固相合成","originalKeyword":"固相合成"},{"id":"934ea332-6221-4c37-a01c-1c482c12babd","keyword":"抗氧化","originalKeyword":"抗氧化"},{"id":"40e2cae3-76ae-4a66-909c-3baaa2920fcf","keyword":"抗菌","originalKeyword":"抗菌"}],"language":"zh","publisherId":"yyhx201509005","title":"含水杨醛席夫碱结构的<span style=\"color:red\">黄酮</span>衍生物的固相合成与抗氧化及抗菌活性","volume":"32","year":"2015"},{"abstractinfo":"应用高效液相色谱法/二极管阵列检测器同时测定了飞机草中木犀草素、槲皮素和山柰酚的含量.色谱柱HiQ sil C18W柱(4.6 mm×25 cm,5μm),流动相V(甲醇)∶V(水)∶V(磷酸)=50∶49.8∶0.2,检测波长槲皮素254 nm,木犀草素和山柰酚360 nm,温度30℃,流速1 mL/min,进样量10μL.确定了以超声波提取法制备飞机草分析样品的方法:溶剂为体积分数85%的乙醇,液固比为10∶1(mL/g),提取时间为1 h.结果表明,3种<span style=\"color:red\">黄酮</span>在0.01×10-3～0.10×10-3 g/mL范围内呈现良好线性关系(R2＞0.999 0),平均加样回收率分别为99.601 7%、99.032 6%和99.450 8%,RSD＜2%.该方法操作简便、准确度高,可快速测定飞机草中木犀草素、槲皮素和山柰酚3种物质的含量.","authors":[{"authorName":"付玉杰","id":"b0497401-c807-4214-ace4-f8f39078d6be","originalAuthorName":"付玉杰"},{"authorName":"刘威","id":"b110b585-6d7c-43b1-9a84-5f768316f3f4","originalAuthorName":"刘威"},{"authorName":"侯春莲","id":"0642fba0-2ea8-465a-af1c-cc1203cf692d","originalAuthorName":"侯春莲"},{"authorName":"刘晓娜","id":"5157cfcf-22c0-4946-8af8-05e6367b6df5","originalAuthorName":"刘晓娜"},{"authorName":"李双明","id":"63739576-2d4f-48a6-9f4c-1eeff686ee39","originalAuthorName":"李双明"},{"authorName":"祖元刚","id":"cc7044ac-8bc7-4e77-b0c4-ad9458af2626","originalAuthorName":"祖元刚"}],"doi":"10.3969/j.issn.1000-0518.2007.12.023","fpage":"1452","id":"d7cae677-28f5-4a10-907e-d155d3573ae1","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"517b4812-193d-4bb3-86ca-e8bfbdcf9aa2","keyword":"飞机草","originalKeyword":"飞机草"},{"id":"2d7083b9-d855-48ca-a01b-93d9cee004ad","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"f88dad75-edae-4e62-bdd5-8e17c28ec1dd","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"a16d573c-b200-40a2-a588-cb50c2766437","keyword":"超声提取法","originalKeyword":"超声提取法"}],"language":"zh","publisherId":"yyhx200712023","title":"RP-HPLC/二极管阵列检测器同时测定飞机草中3种<span style=\"color:red\">黄酮</span>","volume":"24","year":"2007"},{"abstractinfo":"建立了银杏保健茶中16种<span style=\"color:red\">黄酮</span>类物质的液相色谱-串联质谱（ LC-MS／MS）测定方法。16种<span style=\"color:red\">黄酮</span>成分分别为儿茶素、牡荆素、葛根素、大豆苷元、水飞蓟宾、槲皮素、木犀草素、芹菜素、柚皮素、橙皮素二氢查尔酮、山柰酚、橙皮素、异鼠李素、黄芩素、川陈皮素、桔皮素。实验优化了液相色谱条件和质谱参数。采用 C 18柱分离，流动相为乙腈-水（含0.1％甲酸）梯度洗脱，流速0.25 mL／min，以电喷雾离子源正离子多反应监测（ MRM）模式进行 MS／MS 检测。16种<span style=\"color:red\">黄酮</span>类物质在各自的线性范围内具有良好的线性关系，相关系数大于0.996，低、中、高3个添加水平的平均回收率在70.9％~100.0％之间，相对标准偏差小于10％。通过检测发现实际样品中9种<span style=\"color:red\">黄酮</span>物质含量较高，分别是：山柰酚、槲皮素、橙皮素、牡荆素、木犀草素、儿茶素、芹菜素、柚皮素、异鼠李素，占总量的99.6％，此9种物质可作为银杏保健茶的质量控制指标。本法简便、快速、准确可靠，可用于控制银杏保健茶的质量。","authors":[{"authorName":"蒋娅兰","id":"fede9d1d-45ba-4a6d-aa7e-997f25b36085","originalAuthorName":"蒋娅兰"},{"authorName":"黄芳","id":"b78ce7e4-300f-4a18-b2ea-c894beb28689","originalAuthorName":"黄芳"},{"authorName":"毋福海","id":"2a05ea06-bb1e-46ee-bc20-44fd3603fb54","originalAuthorName":"毋福海"},{"authorName":"吴惠勤","id":"b97558b6-4b69-4cc6-9f60-5cf1c045e93a","originalAuthorName":"吴惠勤"},{"authorName":"黄晓兰","id":"3b93f123-0a01-4de7-b6e8-8e1df586f919","originalAuthorName":"黄晓兰"},{"authorName":"邓欣","id":"787a33fa-e99b-40ba-b76a-3f8b2ba10418","originalAuthorName":"邓欣"}],"doi":"10.3724/SP.J.1123.2015.06013","fpage":"1032","id":"546ac7c3-e53e-44ad-a191-0dcd77d18677","issue":"10","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"c852a1f8-817c-4f33-9bd3-a58c1d298cdb","keyword":"液相色谱-串联质谱","originalKeyword":"液相色谱-串联质谱"},{"id":"71d67abb-359d-4261-b851-3435e231b27a","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"0e1c2e1f-3213-44ca-a32e-064556f8d431","keyword":"银杏保健茶","originalKeyword":"银杏保健茶"}],"language":"zh","publisherId":"sp201510005","title":"高效液相色谱-串联质谱法同时测定银杏保健茶中的16种<span style=\"color:red\">黄酮</span>类功效成分","volume":"","year":"2015"},{"abstractinfo":"在分离介质中添加配位剂可提高分离效率.利用MVD2007软件中的Grid计算程序包,应用分子力场的计算模型模拟了Cu2+与处于最低能量构象的山萘酚、槲皮素等<span style=\"color:red\">黄酮</span>类化合物的配位相互作用,得到了Cu2+与山萘酚、槲皮素等分子间的作用力场势能曲面和相对结合能.通过对山萘酚、槲皮素与Cu2+相对结合能的比较,并与高效液相色谱实验结果进行对照分析,得到的研究结果为Cu2+与山萘酚的配位结合要优于其与槲皮素的配位结合.模拟计算与实验结果具有很好的相关性.","authors":[{"authorName":"潘见","id":"9ffca4b4-ab05-4dd5-bcff-cf3ac7fc6199","originalAuthorName":"潘见"},{"authorName":"王佳","id":"fdea652c-a1f0-4abc-b0d5-556d07fe6a41","originalAuthorName":"王佳"},{"authorName":"甘昌胜","id":"87ec8d5e-cd35-477f-a877-7d721c277498","originalAuthorName":"甘昌胜"},{"authorName":"张晨光","id":"056c3d68-024c-4b81-9da9-c4bd7f6cb832","originalAuthorName":"张晨光"}],"doi":"10.3321/j.issn:1000-8713.2008.03.026","fpage":"388","id":"a629232b-6d96-49b9-beda-931e9ec9aa6e","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"8110f01e-50f0-481b-b69f-4eb3f7ba5671","keyword":"计算化学","originalKeyword":"计算化学"},{"id":"da7e3bd8-6d31-4b6a-b68c-4dd1d67f3874","keyword":"配位化合物","originalKeyword":"配位化合物"},{"id":"71137457-4a07-4331-abec-f9521c37a7af","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"fa0b6d89-3c02-47e4-9e30-0dd169942b57","keyword":"山萘酚","originalKeyword":"山萘酚"},{"id":"960f6e1b-50f2-4679-8e76-ef51a7248d10","keyword":"槲皮素","originalKeyword":"槲皮素"},{"id":"df234268-d198-493e-b920-a9dc4c62c414","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"}],"language":"zh","publisherId":"sp200803026","title":"槲皮素、山萘酚与Cu2+配位特性的计算化学解析","volume":"26","year":"2008"},{"abstractinfo":"利用高速逆流色谱分离纯化中草药木蝴蝶乙酸乙酯粗提物中的<span style=\"color:red\">黄酮</span>类活性成分,并将分离规模从分析型线性放大到制备型,以获得大量的活性成分,为进一步的药物筛选提供物质基础.实验在分析型高速逆流色谱上对分离参数进行了系统优化,并将优化条件放大到制备型高速逆流色谱上对911.6 mg木蝴蝶乙酸乙酯粗提物进行分离,得到5种化合物,经高效液相色谱、电喷雾电离质谱和核磁共振氢谱、碳谱分析鉴定,分别为白杨素(160.9 mg,纯度为97.3% )、黄芩素(130.4 mg,纯度为97.6% )、黄芩素-7-O-葡萄糖苷(314.0 mg,纯度为98.3% )、黄芩素-7-O-双葡萄糖苷(179.1 mg,纯度为99.2% )和一种新的白杨素双葡萄糖苷(21.7 mg,纯度为98.8% ).该放大过程不仅将处理量提高了53倍,还保持了在分析型设备上的分离度和分离时间.该工作为天然产物的研究提供了一个高效的分离纯化方法.","authors":[{"authorName":"袁媛","id":"a70512e3-ca20-4d74-9707-364935b5635e","originalAuthorName":"袁媛"},{"authorName":"骆厚鼎","id":"a820348e-3ef0-4265-8003-1a87bf0d9292","originalAuthorName":"骆厚鼎"},{"authorName":"陈俐娟","id":"9dc13498-2058-4895-bca0-2bbb6cf7e056","originalAuthorName":"陈俐娟"}],"doi":"","fpage":"489","id":"2cb6a620-d296-4d3e-9247-7d1d4924e71d","issue":"4","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"f04a2254-c826-4bc3-bbdc-ce3a8f1b5a97","keyword":"高速逆流色谱","originalKeyword":"高速逆流色谱"},{"id":"dee7c78d-8d7d-44ac-b300-0634520f74d4","keyword":"线性放大","originalKeyword":"线性放大"},{"id":"51d6eed7-3614-419d-b803-5259d1057a6d","keyword":"<span style=\"color:red\">黄酮</span>","originalKeyword":"黄酮"},{"id":"658a04e2-a822-44e8-9213-05f2c6b4de41","keyword":"木蝴蝶","originalKeyword":"木蝴蝶"},{"id":"2cc92457-2013-40e5-8057-ce4daccd2fd0","keyword":"中草药","originalKeyword":"中草药"}],"language":"zh","publisherId":"sp200804018","title":"高速逆流色谱在分离纯化木蝴蝶活性成分中的线性放大","volume":"26","year":"2008"},{"abstractinfo":"利用羟丙基-β-环糊精(HP-β-CD)水溶液对中药射干(Belamcanda chinensis)中功能性成分异<span style=\"color:red\">黄酮</span>类物质富集提取.考察了时间、温度等对提取效果的影响,确定了优化的工艺条件；结合紫外光谱、高效液相色谱和液相色谱-质谱联用等检测手段,测定提取源总异<span style=\"color:red\">黄酮</span>含量及<span style=\"color:red\">黄酮</span>种类.在此条件下,对异<span style=\"color:red\">黄酮</span>类物质的提取总量较纯水浸取提高1倍,鸢尾苷提取量可提高2倍.","authors":[{"authorName":"李美慧","id":"6a01cb62-0bc7-4dd3-ba6f-167deaeda43f","originalAuthorName":"李美慧"},{"authorName":"张宇","id":"261bdd31-ec59-4422-8b68-f2785b2ad535","originalAuthorName":"张宇"},{"authorName":"张森","id":"37277229-d5b0-40cc-a5e3-26fe7dd98e86","originalAuthorName":"张森"},{"authorName":"夏婷婷","id":"ac8e67d0-bcdb-4cd7-a819-3f687787bc75","originalAuthorName":"夏婷婷"},{"authorName":"郝爱友","id":"b318dec5-622a-43ef-98f7-019cd2515b1e","originalAuthorName":"郝爱友"}],"doi":"10.3724/SP.J.1095.2012.00307","fpage":"730","id":"cc223072-97bd-4914-9a02-4caf13ef056c","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"75adfba7-988f-4733-8838-f60af45a3547","keyword":"羟丙基-β-环糊精","originalKeyword":"羟丙基-β-环糊精"},{"id":"b3e16f78-4ded-4d2e-b1b6-cbe408032e9f","keyword":"射干","originalKeyword":"射干"},{"id":"7f9de03b-6f62-46ce-a8a2-71ba97644178","keyword":"异<span style=\"color:red\">黄酮</span>","originalKeyword":"异黄酮"},{"id":"32fdb5ad-dc23-4f52-983e-6b8d8f6cbf7a","keyword":"鸢尾苷","originalKeyword":"鸢尾苷"}],"language":"zh","publisherId":"yyhx201206022","title":"羟丙基-β-环糊精富集提取射干中异<span style=\"color:red\">黄酮</span>","volume":"29","year":"2012"}],"totalpage":9,"totalrecord":86}