FENG Di
,
YE Wujun
,
HAN Guangwei
,
LUO Heli(Central Iron Steel Research Institute
,
Beijing 10008 1
,
China)
金属学报(英文版)
Research work and recent progress made toward the industrial applications of the Ni_3Al in CISRI are discussed in present paper. The development of a Ni_3Al base alloy named MX-246 hardened by carbides and fine dispersion of disordered γ is summaried. This alloy,with higher peak temperature of yield strength and higher strain hardening rate than alloyIC-218,has been successfully used as the material of rolling guider at elevated temperatures and in wear conditions. The Ni3Al base alloy of GH264 has been made into welding electrodes by horizontal continuous casting process, and recently successfully surfacing welded on hydraulic blades as cavitation erosion resistance material. The process of remelting Ni3Al base alloy in air was also developed. The processes of producing welding electrodes and remelting in air set the base of industrial applications of Ni3Al in welding, repairing and casting in mass production and into components of large size. Another application of the compound, manufacturing the jet engine rivets used at about 1300℃ , can be attributed to its excellent oxidation resistance and still keeping high strength up to the melting point.
关键词:
: Ni_3Al
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null
,
null
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null
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叶长江
,
李铁藩
,
周龙江
金属学报
研究了Ｎｉ－１１，８２Ａｌ－１．０３Ｚｒ－０．１Ｂ（ｗｔ－％）合金晶粒尺寸为３０和１８０μｍ两种组织结构试样，在９００和１１００℃静态空气中的等温氧化行为．发现，当氧化温度为９００℃时，氧化速率随晶粒尺寸减小而减小，而在１１００℃，二者氧化速率几乎没有区别．利用ＥＰＭＡ，ＸＲＤ分析了氧化产物，证明两种试样的氧化膜相成分与结构，均由ＮｉＯ外层和Ａｌ_２Ｏ_３，ＮｉＡｌ_２Ｏ_４内层组成．但氧化膜／合金界面形貌显著不同．９００℃氧化膜与合金界面呈平滑的波浪型，而１１００℃界面出现树根状突出氧化物伸入到合金表层内部．对上述实验结果作了理论分析，认为前一结果为合金晶界快速短路扩散传质所致、而后一现象与合金晶粒尺寸关系较小，起决定作用的为活性元素Ｚｒ的“反应元素效应（ＲＥＥ）”．
关键词:
Ｎｉ_３Ａｌ
,
oxidation behaviour
,
grain size
,
reactive element effect
郭建亭
,
谷月峰
,
林栋梁
金属学报
对不同Ｚｒ含量Ｎｉ３Ａｌ的力学性能及晶界的研究结果表明：随Ｚｒ含量的增加，合金的屈服强度和抗张强度不断提高；当Ｚｒ≤０．７ａｔ．－％时，塑性随Ｚｒ含量的增加而提高；但Ｚｒ含量达１．２ａｔ．－％时，Ｚｒ的增塑效果下降．Ａｕｇｅｒ能谱分析表明：Ｚｒ在晶界有偏聚，偏聚因子约为３．断口观察显示：不含Ｚｒ或Ｚｒ含量为１．２ａｔ．－％的Ｎｉ－２４．０Ａｌ合金均为沿晶断裂，其余含Ｚｒ合金的断裂方式为穿晶、沿晶混合断裂．这表明：含Ｚｒ的Ｎｉ３Ａｌ塑性和Ｚｒ在晶界的偏聚有密切关系．
关键词:
Ｎｉ_３Ａｌ
,
Zr
,
mechanical property
,
grain boundary
