Z. Bian
,
G. He and G.L. Chen (State Key Laboratory for Advanced Metals and Materials
,
University of Science and Technology Beijing
,
Beijing 100083
,
China) J. Lu
,
D.J. Chen
,
G.C. Tu
,
G.J. Chen and X.J. Hu (Shougang Metallurgical Research Institute
,
Beijing 100085
,
China)
金属学报(英文版)
Al80Ni6 Y8 Co4 Cu2 amorphous ribbons were isothermally annealed and a mixed structure consisting of α-Al particle with a size of less than 15nm and Al3Ni compound with a size of about 30nm was obtained. The crystallization kinetics of Al80Ni6 Y8 Co4 Cu2 amorphous alloy shows that the precipitation of α-Al particles is the growth process controlled by diffusion of the solute elements rejected from the growing crystals. By quenching at different cooling rates, a mixed structure consisting of nanoscale α-Al particles and the remaining glass matrix or structure consisting of nanoscale particle (Al phase or Al3Ni compound) with a size of about 100nm was formed. The addition of Co elements and Cu elements to Al-Ni-Y alloy systems increases the glass formation ability of the alloy and the thermal stability of the supercooled liquid region against crystallization, which results from significant difference of atomic size, strong bonding nature among constituent elements and the low diffisivity of the solute elements due to the concentration gradient in the growing front of crystals.
关键词:
a mixed structure
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Z. Bian
,
G. He and G.L. Chen (State Key Laboratory of Advanced Metals and Materials
,
University of Science and Technology Beijing
,
Beijing 100083
,
China)
金属学报(英文版)
The compressive mechanical behavior and fracture process of Zr_52.5 Cu_17.9Ni_14.6 Al10 Ti5 bulky amorphous alloy were investigated in detail at a strain rate of 10-4s-1. The compressive fracture strength, elastic deformation and elastic modulus of the alloy are 1770MPa, 2.1% and 82GPa, respectively. From SEM observation of fracture surface, the fracture process of bulky amorphous alloy can be described as a tearing process along shear bands. The increase of temperature in the local region was calculated roughly.
关键词:
bulky amorphous alloy
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