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Effect of Sn on the Color and Tarnishing of Cu-Mn-Zn Alloys

Yuping ZHANG , Jinxu ZHANG , Jiansheng WU

材料科学技术(英)

parameters such as L*, a* and b* are selected to describe the surface color of alloys while the color difference (ΔE*) is used to evaluate the color stability. The results show that with the increase of Sn, the color change of Cu-Mn-Zn alloys is greatly reduced and the corrosion resistance in the synthetic sweat is improved dramatically. However, up to 4.4wt pct Sn does not change the color of Cu-Mn-Zn alloys much. XPS and AES are employed to analyze the tarnished surface. It is proved that a Sn enriched film is formed and Sn takes the form of Sn oxide. This thin and protective oxide film can prevent alloy from further tarnishing

关键词: Sn , null , null , null

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