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FREE ENERGIES OF FORMATION FOR ELECTROCHEMICALLOY ALLOYED Y-Cu SYSTEM

YANG Qiqin LIU Guankun LIU Zejin Zhongshan University , Guangzhou , China YANG Qiqin , Associate Professor , Department of Chemistry , Zhongshan University , Guangzhou , China

金属学报(英文版)

The electrochemical alloying of Y-Cu system in molten NaCl-KCl-YCl_3 has been investi- gated.The free energy changes of the formation reactions of the intermetallic compounds,in- cluding YCu_6 ,YCu_4 YCu_2 ,Yfu(973—103 K),were determined by means of electrode potential-time curves of the working electrode after potentiostatic electrolysis.The results in- dicate that the potential-time method is simple and reliable.

关键词: Y-Cu system , null , null

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