Y.Z. Yang
,
Y.H Luo
,
Q.S. Li
,
Y.L. Zhu
,
X.M. Ma
,
Y.D. Dong and Y.Z. Chuang(Department of Materials Science and Engineering
,
Guangdong University of Technology
,
Guangzhou510090
,
China)(Guangdong Educational College
,
Guangzhou 510084
,
China)(Department of Materials Science and Engineering
,
Shanghai University
,
Shanghai 200072
,
China)(Institute of Metal Research
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
The structural transformation in Fe-Cu powder induced by mechanically driven alloying has been monitored by the lattice constant measurements and Mossbauer spectroscopy. For the samples with Cu higher than 75at.% Mossbauer the spectra show a broad paramagnetic doublet; for samples with 50 and 60at.%Cu a new broad ferromagnetic sextet; for those with less than 30at.%Cu similar to those of α-Fe. The main peaks of the hyperfine field distribution significantly broaden and shift to a lower position with increasing Cu content due to the complex environments of iron atoms in the solid solutions and the reduction in the nearest neighbor Fe of a cental Fe atom, respectively. The saturation magnetization of Fe-Cu alloys monotonously decreases with Cu content. The complex composition dependence of coercive field for the milled samples is discussed with respect to the solid dissolution, grain size, interfacial state etc.. The increase of lattice constants with the solute content in the two terminal solid solutions has been explained by the volume-size factor theory or magnetovolume effect.
关键词:
mechanical alloying
,
null
,
null
,
null
Y.Z. Yang
,
Y.L. Zhu
,
Q.S. Li
,
X.M. Ma
,
Y.D. Dong and Y.Z. Chuang (Department of Materials Science and Engineering
,
Guangdong University of Technologyt Guangzhou 510090
,
China)(Depotment of Materials Science and Engineering
,
Shanghai University
,
Shanghai 200072
,
China)(Institute of Metal Research
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
Nanocrystalline supersaturated solid solutions (Sa in Fe) with Sn content less than 50 at. %,and FeSn2 and Fe1.3Sn intermetallic compounds have been prepared by mechanical alloying of Fe and Sn mixture powders with composition of Fe1-xSnx (x≤0.5).The atomic alloying the formation and microstructure, especially the coordination environments, of the resultant alloys have been studied by X-ray diffraction, 57Fe and 119Sn Mossbauer Spectroscopy and diffrrential scanning calorimetry. The Fe and Sn coordination environments and the composition dependence of the hyperfine parameters on the Fe and Sn content have been fully discussed with respect to the solid dissolution alloying, grain refinement, and distortion caused or induced by mechanical alloying.
关键词:
mechanical alloying
,
null
,
null
Y.Z. Yang
,
X.J. Bai
,
T.C. Kuang
金属学报(英文版)
The structure of bcc-Fe80 Cu2o solid solution produced by mechanical alloying of theelemental bcc-Fe and fcc-Cu powders has been studied using X-ray diffraction and theextended X-ray absorption fine structure (EXAFS) techniques. The disappearance ofelemental Fe and Cu X-ray diffraction (XRD) peaks and the presence of bcc structuralXRD peaks illustrate the formation of a nanocrystalline single-phase bcc-Fe80 Gu20solid solution. From the EXAFS results, the clear observation of Cu atoms taking onbcc coordination in the solid solution and Fe atoms remaining bcc structure furtherverifies the reality of atomic alloying between Fe and Cu atoms and the lattice changeof Cu from fcc to bcc. However, the supersaturated bcc solid solution is not chemicallyuniform, i.e., some regions are rich in Fe atoms and other regions rich in Cu atoms.
关键词:
mechanical alloying
,
null
,
null
,
null
