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Thermodynamics of Bainitic Formation in Carbon-depleted Region in Fe-C Alloys

Xiaolei WU , Xiangkang MENG , Xiyan ZHANG , Yanqing YANG and Mokuang KANG(Dept. of Materials Science and Technology , 401 , Northwestern Polytech. University , Xi'an , 710072 , China)

材料科学技术(英)

Thermodynamic analysis for the formation of bainitic ferrite in carbon -depleted region has been conducted. The results show that the driving force of bainitic formation increases with depleting of carbon in parent austenite and with decreasing the transformation temperature. The critical driving force (absolute value) at the Bs temperature is 600-1 200 J / mol, which increases as the mean carbon content of Fe-C alloys increases. The freshly-formed bainitic ferrite has partial supersaturation of carbon, which increases smoothly with decreasing the transformation temperature Therefore, the displacive formation of bainitic ferrite in carbon-depleted region is thermodynamically feasible in the whole temperature range of bainitic reaction.

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Study of Carbon-poor Regions of Austenite during Bainitic Incubation Period by SAM

Xiaolei WU , Husheng JIA , Xiyan ZHANG and Mokuang KANG(Dept. of Materials Science & Engineering , Northwestern Polytechnical University , Xi'an , 710072 , China)(To whom correspondence should be addressed)

材料科学技术(英)

The variation of carbon composition in undercooled austenite during bainitic incubation period has been investigated in 40CrMnSiMoVA by scanning auger microprobe (SAM). The results show that the outstanding diffusion and redistribution of carbon occur in isothermally reacted specimens. This leads to the formation of carbon-poor regions (CPR) near austenite grain boundaries and in austenite grains. The carbon content in CPR exceeds the equilibrium carbon composition of ferrite. Furthermore, it is indicated that the existence of CPR is thermodynamically possible.

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Nonequilibrium Microstructures and Phase Evolutions of an Iron-based Laser Clad Coating

Xiaolei WU , Guangnan CHEN

材料科学技术(英)

The microstructural and compositional features of the laser-solidified microstructures and phase evolutions occurring during high temperature tempering were investigated by using analytical electron microscopy with energy dispersive X-ray analysis. The cladded alloy, a powder mixture of Fe, Cr, W, Ni and C with a weight ratio of 10:5:1:1:1, was processed with a 3 kW continuous wave CO2 laser. The cladded coating possessed the hypoeutectic microstructure of the primary dendritic γ-austenite and interdendritic eutectic consisting of (γ+M7C3). Theγ-austenite is a nonequilibrium phase with extended solid solution of alloying elements. And, a great deal of fine structures, i.e., a high density of dislocations, twins, and stacking faults existed in austenite phase. During high temperature aging, the precipitation of M23C6, MC and M2C in austenite and in situ transformation of M7C3(+γ)→ M23C6 and M7C3+γ→M6C occurred. The laser clad coating revealed an evident secondary hardening and superior impact wear resistance.

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Microstructure and Wear Resistance of In situ TiCp Composite Coating by Laser Cladding

Xiaolei WU , Guangnan CHEN

材料科学技术(英)

A new in situ method was realized by one step laser cladding to produce Ni-base alloy composite coating reinforced by in situ reacted and gradiently distributed TiCp particles. The submicron TiCp particles were formed and uniformly distributed because of the in situ reaction and trapping effect under the rapid solidification condition. And, TiCp particles were of gradient distribution on a macro scale and their volume fraction increased from 1.86% at the layer/substrate interface to a maximum 38.4% at the surface of the layer. Furthermore, the in situ generated TiCp/g-Ni interfaces were free from deleterious surface reactions. Additionally, the clad coating also revealed a high microhardness of gradient variation with the layer depth and the superior abrasive wear resistance.

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