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Apparent Active Adsorption Force at a Solid-Liquid Interface with Active Adsorption

XIAN Aiping SI Zhongyao Institute of Metal Research , Academia Sinica 72 , Wenhua Road , Shenyang , 110015 , China.

材料科学技术(英文)

The paper presents a new relationship between the three surface tensions on the solid-liquid-vapor interface, γ_(sl)-γ_(sv)+γ_(lv)cosθ=βin order to understand the wetting on the liquid-solid interface in the case of active adsorption.The authors suggest a new force“apparent active adsorption force”βto take part in the balance at the three interface lines of contact in the solid-liquid-vapor phases,its dimen- sion isβ=Σα_iRT(Γ_i~(sl)-Γ_i~(sv)+Γ_i~(lv)cosθ),and its direction is dependent on the sign of β,whenβis a positive, the direction is agree with surface tension of the sol- id-vapor interface γ and vice versa.

关键词: solid-liquid interface , null , null , null , null

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