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Amino-Tris-(Methylenephosphonic Acid) Layers Adsorption On Aa6061 Aluminum Alloy

S.H. Wang , C.S. Liu , F.J.Shan , G.C. Qi

金属学报(英文版)

The amino-tri-(methylenephosphonic acid) layers were adsorbed on the surface of AA6061 aluminum alloy for improving the lacquer adhesion and corrosion inhibition as a substitute for chromate coatings. The surface structure and characteristic of the amino-tri-(methylenephosphonic acid) layers on AA6061 aluminum alloy were investigated by means of XPS and ATR-FTIR analysis. The analyzed results showed that the amino-tri-(methylenephosphonic acid) adsorption layers adsorb on the surface of aluminium alloy $via$ acid-base interaction in a bi-dentate conformation. After the amino-tri-(methylenephosphonic acid) layers were coated with epoxy resin, the layers showed good adhesive strength and favorable corrosion resistance in contrast to chromate coatings.

关键词: Amino-tri-(methylenephosphonic acid)Layer , null , null , null

CORROSION BEHAVIOR OF A ZIRCONIUM-TITANIUM BASED PHOSPHONIC ACID CONVERSION COATING ON AA6061 ALUMINIUM ALLOY

S.H. Wang

金属学报(英文版)

The conversion coating was formed by dipping AA6061 in a fluorotitanate/zirconate acid and amino trimethylene phosphonic acid (ATMP) solution at room temperature. The formation process and the anti-corrosion performance of the conversion coating were investigated using electrochemical test and salt spray test (SST), respectively. The electrochemical test shows that the Zr/Ti and ATMP coating improves the corrosion resistance of AA6061 as good as the chromate (VI) coating. But the results of SST show that the corrosion resistance of Zr/Ti and ATMP coating is not as good as the chromate (VI) coating. The corrosion area is less than 2% after 72h.

关键词: Corrosion resistance , null , null

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