Mingfen WEN
,
Lian CHEN
,
Min TONG
,
Demin CHEN
,
Huiming CHENG
,
Yuchun ZHAI
,
Yanwen TIAN
材料科学技术（英文）
Zr0.9Ti0.1(Ni,Co,Mn,V)(2.1) as-cast alloy was prepared by melting under Ar atmosphere; and then, four composite alloys were prepared by ball-milling after hydrogen absorbing agent was added. The initial discharge capacity was as high as 430 mAh .g(-1) for composite alloy electrode c discharged at 60 mA .g(-1) current density and its maximum capacity reached 505 mAh .g(-1). All composite alloy electrodes have good activation behavior, being fully activated in one or two cycles. At 300 mA .g(-1) current density, the composite alloy electrode c was found to have good cycle stability.
关键词:
Mingfen WEN
,
Bo YU
,
Qiuping WANG
,
Chongli SONG
,
Jing CHEN
材料科学技术（英文）
Different nanometer CeO2-ZrO2 mixed oxides doped with lanthanum or ~praseodymium were prepared by coprecipi-tation. The characteristics of all mixed oxides were tested by XRD, SEM, TEM, and XPS. XRD results showed that all oxides were formed solid solution with CaF2 structure at low temperature and had good thermal stability. More Ce4+ ions were rich on the surface by XPS, which were beneficial to oxygen storage. The particle mediun sizes (d50) of all oxides powders were approximately 10~20 nm by small angle scattering goniometer. When doped Zr4+ in CeO2, the specific surface areas were improved at low or high temperature. The area of Ce0.6Zr0.3La0.04Pr0.06O2 powder had excess 110 m2/g after calcining at 923 K for 4h, even calcined at 1273 K for 4 h, the area was up to 65 m2/g.
关键词:
Ceria-zirconia
,
null
,
null
,
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