LI Cheng Beijing Central Design and Research Institute for Non-Ferrous Metallurgical Industry
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Beijing
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ChinaLIU Chunpeng
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Kunming Institute of Technology
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Kunming
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China LI Cheng
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Metallurgical Dept.No.l
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Beijing Central Design and Research Institute for Non-Ferrous Metallurgical Industry
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Beijing 100038
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China
金属学报(英文版)
The rate equation of reaction between PbS and PbO is dα/dt=kx_(PbS)~3 x_(PbO)~(-2).A transition product, PbSO_4·2PbO,is found by X-ray diffraction analysis.The reaction mechanism was dis- cussed on the basis of electron transfer.
关键词:
kinetics
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LIU Rixin NING Baolin ** Dept.of Metallurgy
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Kunming Institute of Technology
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Kunming
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650093
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China*** Dept.of Thermal Energy
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Northeast University of Technology
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Shenyang
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110006
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China+ To whom correspondence should be addressed
材料科学技术（英文）
This paper provides a mathematical model for the billet reheating process in furnace.A new optimum method is brought up that the objective function is the integral value of enthalpy increasing process of a billet.Different delays are simulated and calculated,some proper delay strategies are ob- tained.The on-line computer control model is de- veloped.The real production conditions simulated, the temperature deviation of drop out billet from the target temperature is kept within±15℃.
关键词:
reheating furnace
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By LIU Zhonghua LIU Chunpeng Department of Metallurgy
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Kunming Institute of Technology
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Kunming
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650093
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China.To whom correspondence should be addressed.
材料科学技术（英文）
Reduction kinetics of Ni_3S_2 was experimen-tally studied by following the time required forcompletion of the hydrogen reduction reaction inthe presence of calcium oxide.A simple empiricalintegration equation,derived for describing the ef-fect of CaO/S molar ratio,temperature,hydrogenconcentration and the average diameter ofNi_3S_2 grains,may be shown as following:t_(X=1)=2.317×10~(-6)d_(Ni_3S_2) C_(H_2)~(-1)β~(-2.29)e~(13710/T),minThe reduction reaction is of first order with respectto hydrogen concentration,and the apparent reac-tion activation energy is 114.0 kJ/mol.A great ma-jority of metallic Ni reduced from Ni_3S_2 is distrib-uted in the products evenly.
关键词:
kinetics
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TAO Dongping LIU Chunpeng ** Dept.of Metallurgy
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Kunming Institute of Technology
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Kunming
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650093
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China+ To whom correspondence should be addressed
材料科学技术（英文）
The rate processes of oxidative dearsenication of niccolite ore in microwave oven and in conventional furnace were measured with thermogravimetric technique.The results show that the dearsenication rate of niccolite ore with microwave heating becomes faster than that with conventional heating. Under the conditions of an approximate linear heating and a definite air flow,the oxidative dearsenication process of niccolite ore is mainly controlled by interfacial chemical reaction.The ex- perimental data are in agreement with the kinetic model of linear heating as follows: In{[1-(1-α)~(1/3)]/T}= In (PAM)/(r_oρφE)(1-(RT)/E)-E/(RT) Thus the apparent activation energies of oxidative dearsenication of the niccolite ore containing differ- ent additions have been obtained from the model.
关键词:
kinetics
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