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PROPERTIES OF ELECTRODEPOSITED AMORPHOUS Ni-W-P-SiC COMPOSITE COATINGS

GUO Zhongcheng , LIU Hongkang , WANG Zhiyin , WANG Min(Department of Metallurgy , Kunming institute of Technology , Kunming 650093 , China) Manuscript received 8 May 1995

金属学报(英文版)

The Effects of heat treatment temperature on the hardness,wear resistance and structure of the amorphous Ni-W-P-SiC composite coatings have been investigated.The results show that Ni-W-P-SiC composite coatings are amorphous under 300℃, partially crystalline at 300-400℃,and crystalline when heat treatment temperature reaches 400℃,the crystals being fine Ni3P phase particles.The hardness,wear resistance and the crystallization temperature of the composite coatings increase when an additive is added into the bath.The hardness and wear resistance of the coatings increase with increasing heat treatment temperature,and they will reach their peak values when the heat treatment temperature reaches 400℃.Corrosion experiment indicates that the corrosion resistance of amorphous Ni-W-P-SiC composite coatings in various kinds of corrosive media except nitric acid is better than that of stainless steel 1Cr18Ni9Ti.Scanning electron microscopy observation shows that the additive has no effect on the surface appearance of the coatings,but the current density and the pH value have considerable effects on the surface appearance.

关键词: :electrodeposition , null , null

PREDICTION OF THERMODYNAMIC PROPERTIES OF THE FeO-CaO-SiO_2 MELTS FROM WILSON EQUATION

D.P.Tao and X.W. Yang(Department of Metallurgy , Kunming University of Science and Technology , Kunming 650093 , China)

金属学报(英文版)

An attempt was made to use the Wilson equation to predict the thermodynamic properties of the FeO-CaO-SiO2 melts at 1673 and 1873K. The activities of component FeO in the ternary melts at a given temperature were found to be conveniently calculated from the equation only with related binary parameters at different temperatures.The predicted values are in agreement with the ternary experimental data.

关键词: thermodynamic property , null , null

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