Jia ZHANG
,
Wensheng SUN
,
Mingxiu QUAN
,
Zhuangqi HU
材料科学技术（英）
Microstructure and subsequent phase transformations on heating of the melt-spun Nd85Al15 alloy have been studied by X-ray diffraction, transmission electron microscopy and differential scanning calorimetry. The melt-spun Nd85Al15 alloy shows two-stage transformation processes as follows: amorphous+72 nm supersaturated bcc-Nd(Al) solid solution→7 nm omega-like phase→AlNd3+hexagonal Nd. The activation energies for the first and second transformation were found to be 100 kJ/mol and 188 kJ/mol, respectively. The formation mechanism of nanoscale omega-like phase is discussed.
关键词:
Melt-spun Nd85Al15 alloy
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,
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Jia ZHANG
,
Keqiang QIU
,
Aimin WANG
,
Haifeng ZHANG
,
Mingxiu QUAN
,
Zhuangqi HU
材料科学技术（英）
The Mg65Cu25Y10 melts were quenched at a temperature of 973 K under various pressures in the range of 2～5 GPa and ambient pressure. The microstructure of the solidified specimens has been investigated by X-ray diffraction, transmission electron microscope and electron probe microanalysis. Experimental results show that the pressure has a great influence on the solidification microstructure of the Mg65Cu25Y10. At ambient pressure, the solidification products are Mg2(Cu,Y) and a very small amount of Y2O3 inclusion. As the pressure is above 2 GPa, a new Cu2(Y,Mg) phase appears, while Y2O3 is not observed at the pressure of 3, 4 and 5 GPa. When the pressure increases from 2 GPa to 5 GPa, the grain sizes of Mg2(Cu,Y) and Cu2(Y,Mg) decrease from 125, 96 nm to 80, 7 nm, respectively. The mechanisms for the effects of the pressure on the phase evolution and microstructure during solidification process of Mg65Cu25Y10 alloy have been discussed.
关键词:
Mg65Cu25Y10 alloy
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