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M(?)ssbauer Spectra for Ultrafine Particles Fe_3O_4

Haibo LI Weitao ZHENG Yudong LIU Ruilin ZHANG Department of Materials Science , Jilin University , Changchun , 130023 , China

材料科学技术(英文)

The procedure of preparing specimens of ultrafine particles (UFP) Fe_3O_4 was studied and the measurement and analysis of the Mssbauer spectra at room temperature was made.After the hyperfine field due to iron was analyzed carefully,it is shown that the interaction of the interfaces be- tween grains of UFP Fe_3O_4 has stronger effects (enlarging the quadrupole splitting in Mssbauer spectrum) and it is found that superparamagnetic effects appear,which means that the magnetic property of UFP Fe_3O_4 is different from that of bulk Fe_3O_4.

关键词: UFP , null , null

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