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Electrochemical Behavior of Dissolved Fe2O3 in Molten CaCl2KF

WANG Shulan , Geir Martin Haarberg , Eirin Kvalheim

钢铁研究学报(英文版)

he electrochemical behavior of dissolved Fe2O3 in 825CaCl2175KF (mole percent, %) was studied using cyclic voltammetry, chronoamperometry, and galvanostatic electrolysis at 827 ℃, and the deposits were characterized by XRD and SEM. Pure iron was deposited on a rotating cylinder (210 r/min) with a cell voltage less than -10 V. Deposition rate was controlled by diffusion on a molybdenum electrode. The diffusion coefficient of iron species Fe(Ⅲ) in the melt at 827 ℃ was found to be 97×10-5 cm2/s.

关键词: iron;electrolysis;electrochemistry;molten salt

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