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RAMAN SPECTRA OF SODIUM ALUMINATE SOLUTIONS WITH HIGH-CAUSTIC RATIO AND HIGH CONCENTRATION

LIU Miaoxiu CAO Yilin CHEN Nianyi Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , ChinaZHUANG Zhicheng Shanghai Jiaotong University , Shanghai , China Professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

The constitution of high-caustic ratio and highly concentrated sodium aluminate solutions has been investigated by Raman spectra method.By comparison with the Raman spectra of crystalline solids of Ca_3[Al(OH)_6]_2 and Ba_2[Al_2(OH)_(10)],it can be concluded that AI(OH)_6~(3-)ion and perhaps its polymers may be formed in these solutions.

关键词: high caustic ratio , null , null

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