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Effects of temperature and [S] on the kinetics of nitrogen removal from liquid steel

Jie FU , Shixiang ZHOU , Ping WANG , Lin DI , Jian ZHU

材料科学技术(英文)

The kinetics of denitrogenation from liquid steel was studied by using an oxygen-nitrogen analysis system(LECO TC-436) under 1600℃ similar to 2813℃ conditions. The results show that when [S]=0.005%, nitrogen removal was controlled by nitrogen transfer in liquid diffusion layer, when [S]=0.012% and 0.140%, it was controlled by both nitrogen transfer in liquid diffusion layer and the chemical reaction at the liquid-gas interface below 2250℃, and by nitrogen transfer in liquid diffusion layer under 2250℃ similar to 2813 degreesC conditions. The activation energy E-a was 57 kJ/mol for 0.0050%[S], 95 kJ/mol for 0.012%[S], 165 kJ/mol for 0.140%[S]. The resistance of sulphur on nitrogen removal decreased with the temperature rose, and disappeared at 2630℃. Based on the results obtained, it has been answered why the nitrogen in liquid steel can be decreased rapidly by carbon-oxygen reaction under very high oxygen and sulphur content conditions during the BOF, EAF, VOD and AOD steelmaking processes.

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Fatigue crack initiation for Al-Zn-Mg alloy welded joint

Liang ZHANG , Xuesong LIU , Linsen WANG , Ping WANG , Hongyuan FANG

金属学报(英文版)

To investigate fatigue crack initiation characteristics of Al-Zn-Mg alloy welded joint, notched specimens were used in fatigue test for the base metal, welding bead and heat affected zone (HAZ). The fatigue fracture surface near the fatigue crack initiation site was observed by scanning electron microscope (SEM). The results show that the differences of fatigue crack initiation life among base metal, welding bead and HAZ are not obvious. Inhomogeneity in microstructure and mechanical performance of HAZ influences the fatigue crack initiation life. The ratio of fatigue crack initiation life (Ni) to fatigue failure life (N f)Al-Zn-Mg alloy|Welded joint|Fatigue crack initiation|Life prediction for the base metal, welding bead and HAZ of A7N01 aluminium alloy welded joint are 26.32%, 40.21% and 60.67%, respectively. Fatigue crack initiation life can be predicted using a uniform model. Observation of fatigue fracture surfaces shows that for the welding bead a fatigue crack initiates from the smooth surface due to the welding process, the blowhole in HAZ causes fatigue crack and the crushed second phase particles play an important role in fatigue crack initiation for the base metal.

关键词: Al-Zn-Mg alloy , null , null , null

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