Shanling WANG
,
Baoluo SHEN Shengji GAO
,
Da LI
,
Mingjing TU
,
Weicheng YU
,
Ge YAO
材料科学技术（英）
The creep behavior of Al2O3. SiO2 fiber reinforced ZL109 composites has been investigated at four temperatures ranging from 553 to 623 K. The results show high stress exponent and high apparent creep activation energy. A good correlation between the normalized creep rate and normalized effective stress means that the true stress exponent of minimum creep strain rate of the composite is very close to 5, and the minimum creep strain rate is matrix lattice diffusion controlled. The threshold stress decreases with increasing temperature linearly and disappears at a temperature close to 623 K. It is assumed that the long range internal back stresses generated in creep reduce the load transfer to fibers and the interaction between dislocations and strengthening precipitates decreases at high temperature. At a high temperature where the long range internal back stresses is very close to the applied stress, the threshold stress disappears.
关键词:
Quan'an LI
,
Yungui CHEN
,
Mingjing TU
材料科学技术（英）
Effect of stoichiometry on microstructures, electrochemical properties and PCT characteristics of the alloys Ml(Ni0.71Co0.15-Al0.06Mn0.08)x (Ml=Lanthanum-rich Michmetal, x=4.6-5.2) have been investigated. The lattice constants a, c and cell volumes of non-stoichiometric alloys are bigger than those of the stoichiometric alloy. With the increasing stoichiometry x, the value of a decreases, and the value of c and cell volume increases except for those of the stoichiometric alloy; the plateau pressure of PCT curve, discharge capacity and cycling stability all increase. The alloy with x=5.2 shows the highest discharge capacity and the best cycling stability among the studied alloys.
关键词:
Hydrogen storage alloy
,
null
,
null
,
null
,
null
Yuhua WEN
,
Ning LI
,
Mingjing TU
材料科学技术（英）
The effects of prestrain and annealing temperature on phase transformation temperatures in Fel4Mn5Si8Cr4Ni shape memory alloy have been studied. The results showed that when the annealing temperature was 673 K, both the A(f) and the M-s temperatures increased appreciably as the prestrain increased, the A, temperature increased slightly with increasing prestrain, the resistivity difference at 303 K between the heating and cooling curve also increased with increasing prestrain, which agreed with the recovery strain. The shape memory effect in Fe-Mn-Si-Cr-Ni shape memory alloy is caused by the stress-induced gamma --> epsilon martensite transformation and its reverse transformation. When the prestrain was 10%, the M-s temperature decreased remarkably as the annealing temperature increased.
关键词:
Yuhua WEN
,
Ning LI
,
Mingjing TU
材料科学技术（英）
The effects of aging temperature on shape memory effect, mechanical properties and microstructure of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles rich in chromium, manganese and silicon precipitate during aging, and thereby increase the hardness and strength of the alloy. The shape recovery ratio can be remarkably improved by aging and a maximum value can be obtained at 1223 K, which is 68% higher than that of the specimen in solid solution state. When the aging temperature is below 1223 K, the amount of second phase particles increases as the aging temperature increases. The size of austenite grain increases with increasing aging temperature. When the temperature is over 1223 K, the second phase particles can not precipitate. The lack of second phase particles and the increase of grain size make the hardness and shape recovery ratio drastically decrease, when the temperature is over 1223 K.
关键词:
