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Effect of Hydrogen on Cryogenic Mechanical Properties of Cr-Ni-Mn-N Austenitic Steels

Luming MA , Guojun LIANG , Jun TAN , Lijian RONG , Yiyi LI

材料科学技术(英文)

The method of high-pressure hydrogen charging was used to investigate the internal hydrogen effects on cryogenic mechanical properties of two Cr-Ni-Mn-N austenitic steels, 22-13-5 and 21-6-9. Specimens saturated with hydrogen up to 65×10-6~68×10-6were tested in air at temperatures ranging from 77 to 293 K. Hydrogen caused the increase in cryogenic strength, both yield strength and ultimate tensile strength. Hydrogen decreased cryogenic ductility, and the maximum hydrogen embrittlement (HE) tendency was found at a certain low temperature. Cr-Ni-Mn-N austenitic steels showed the feature: δL>ΨL at low temperatures, here, δL andΨL are the hydrogen induced loss rates of elongation and reduction of area, respectively. Hydrogen had less effect on cryogenic Charpy impact toughness and notched tensile strength, however, hydrogen decreased cryogenic fracture toughness of the steels. At temperature below Md, the fracture toughness was obviously decreased due to the formation of strain-induced martensites, whether hydrogen was charged or not.

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Effect of carbon and phosphorous on the solidification microstructure in a Cr-Ni-Mn-N austenitic hydrogen-resistant steel

Jun TAN , Luming MA , Shouxin LI , Lijian RONG , Jincai YUAN , Yiyi LI

材料科学技术(英文)

The influence of carbon and phosphorus on the solidification microstructure of a Cr-Ni-Mn-N austenitic steel was studied. The button specimens were prepared by vacuum induction melting and magnetic convection. The experimental results show that the increase of C or P concentration in the steel can change the solidification modes of Cr-Ni-Mn-N austenitic steels and has a significant effect on the morphology of the dendrites. The content of delta -ferrite in the microstructure reduces with increasing the concentration of C or P in the steel, there is a gradient of the content of delta -ferrite formed from surface through the center of the specimens.

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